Samir Vučelj, Rušid Hasić, Darko Ašanin, Biljana Šmit, Angelina Caković, Jovana Bogojeski, Marina Ćendić Serafinović, Bojana Simović Marković, Bojan Stojanović, Sladjana Pavlović, Isidora Stanisavljević, Irfan Ćorović, Milica Dimitrijević Stojanović, Ivan Jovanović, Tanja V Soldatović, Bojana Stojanović
A series of mono- and heteronuclear platinum(II) and zinc(II) complexes with 4,4',4″-tri- tert -butyl-2,2':6',2″-terpyridine ligand were synthesized and characterized. The DNA and protein binding properties of [ZnCl2 (terpy t Bu )] ( C1 ), [{ cis -PtCl(NH3 )2 ( μ -pyrazine)ZnCl(terpy t Bu )}](ClO4 )2 ( C2 ), [{ trans -PtCl(NH3 )2 ( μ -pyrazine)ZnCl(terpy t Bu )}](ClO4 )2 ( C3 ), [{ cis -PtCl(NH3 )2 ( μ -4,4'-bipyridyl)ZnCl(terpy t Bu )}](CIO4 )2 ( C4 ) and [{ trans -PtCl(NH3 )2 ( μ -4,4'-bipyridyl)ZnCl(terpy t Bu )}](CIO4 )2 ( C5 ) (where terpy t Bu = 4,4',4″-tri- tert -butyl-2,2':6',2″-terpyridine), were investigated by electronic absorption, fluorescence spectroscopic, and molecular docking methods...
March 6, 2024: International Journal of Molecular Sciences