keyword
https://read.qxmd.com/read/38608574/high-performance-electrosorption-of-lanthanum-ion-by-mn-3-o-4-loaded-phosphorus-doped-porous-carbon-electrodes-via-capacitive-deionization
#1
JOURNAL ARTICLE
Guanfeng Lin, Guilong Wang, Yongzhi Xiong, Simin Li, Rongyuan Jiang, Beili Lu, Biao Huang, Haijiao Xie
Transition-metal-oxide@heteroatom doped porous carbon composites have attracted considerable research interest because of their large theoretical adsorption capacity, excellent electrical conductivity and well-developed pore structure. Herein, Mn3 O4 -loaded phosphorus-doped porous carbon composites (Mn3 O4 @PC-900) were designed and fabricated for the electrosorption of La3+ in aqueous solutions. Due to the synergistic effect between Mn3 O4 and PC-900, and the active sites provided by Mn-O-Mn, C/PO, C-P-O and Mn-OH, Mn3 O4 @PC-900 exhibits high electrosorption performance...
April 11, 2024: Journal of Environmental Management
https://read.qxmd.com/read/38602862/long-term-safety-of-lanthanum-carbonate-in-the-real-word-a-19-year-disproportionality-analysis-from-the-fda-adverse-event-reporting-system
#2
JOURNAL ARTICLE
Mengjia Ying, Jian Shi, Yahao Ling, Tao Shi, Lele Liao, Linhui Cao
BACKGROUND: Lanthanum carbonate is widely used to manage serum phosphate and calcium levels in end-stage kidney disease (ESKD) patients, yet comprehensive long-term safety data are lacking. This study leverages the FDA Adverse Event Reporting System (FAERS) to assess the extended safety profile of lanthanum carbonate. RESEARCH DESIGN AND METHODS: We analyzed FAERS data (2004-2022) to study the association between lanthanum carbonate and adverse events (AEs). Using MedDRA v25...
April 11, 2024: Expert Opinion on Drug Safety
https://read.qxmd.com/read/38601863/safety-and-efficacy-of-a-feed-additive-consisting-of-lanthanum-carbonate-octahydrate-for-dogs-porus-gmbh
#3
JOURNAL ARTICLE
Vasileios Bampidis, Giovanna Azimonti, Maria de Lourdes Bastos, Henrik Christensen, Mojca Durjava, Birgit Dusemund, Maryline Kouba, Marta López-Alonso, Secundino López Puente, Francesca Marcon, Baltasar Mayo, Alena Pechová, Mariana Petkova, Fernando Ramos, Roberto Edoardo Villa, Ruud Woutersen, Orsolya Holczknecht, Fabiola Pizzo, Maria Vittoria Vettori, Jaume Galobart
Following a request from the European Commission, EFSA was asked to deliver a scientific opinion on the safety and efficacy of lanthanum carbonate octahydrate as a zootechnical feed additive for dogs. The additive is already authorised for use in feed for cats. The FEEDAP Panel concluded that the additive lanthanum carbonate octahydrate is safe for adult dogs at the maximum recommended level of 7500 mg/kg complete feed. The additive is not irritant to skin or eyes, is not a skin sensitiser and exposure by inhalation is considered to be unlikely...
April 2024: EFSA journal
https://read.qxmd.com/read/38570905/associations-of-kidney-functional-magnetic-resonance-imaging-biomarkers-with-markers-of-inflammation-in-individuals-with-chronic-kidney-disease
#4
JOURNAL ARTICLE
Jacquelyn Trujillo, Manal Alotaibi, Nay Seif, Xuan Cai, Brett Larive, Jennifer Gassman, Kalani L Raphael, Alfred K Cheung, Dominic S Raj, Linda F Fried, Stuart Sprague, Geoffrey Block, Michel Chonchol, John Paul Middleton, Myles Wolf, Joachim H Ix, Pottumarthi Prasad, Tamara Isakova, Anand Srivastava
BACKGROUND: Greater fibrosis and decreased oxygenation may amplify systemic inflammation, but data on the associations of kidney functional magnetic resonance imaging (fMRI) measurements of fibrosis (apparent diffusion coefficient [ADC]) and oxygenation (relaxation rate [R2*]) with systemic markers of inflammation are limited. METHODS: We evaluated associations of baseline kidney fMRI-derived ADC and R2* with baseline and follow-up serum interleukin-6 (IL-6) and C-reactive protein (CRP) in 127 participants from the COMBINE trial, a randomized, 12-month trial of nicotinamide and lanthanum carbonate vs...
April 4, 2024: Kidney360
https://read.qxmd.com/read/38475249/flexible-composite-electrolyte-membranes-with-fast-ion-transport-channels-for-solid-state-lithium-batteries
#5
JOURNAL ARTICLE
Xiaojun Ma, Dongxu Mao, Wenkai Xin, Shangyun Yang, Hao Zhang, Yanzhu Zhang, Xundao Liu, Dehua Dong, Zhengmao Ye, Jiajie Li
Numerous endeavors have been dedicated to the development of composite polymer electrolyte (CPE) membranes for all-solid-state batteries (SSBs). However, insufficient ionic conductivity and mechanical properties still pose great challenges in practical applications. In this study, a flexible composite electrolyte membrane (FCPE) with fast ion transport channels was prepared using a phase conversion process combined with in situ polymerization. The polyvinylidene fluoride-hexafluoro propylene (PVDF-HFP) polymer matrix incorporated with lithium lanthanum zirconate (LLZTO) formed a 3D net-like structure, and the in situ polymerized polyvinyl ethylene carbonate (PVEC) enhanced the interface connection...
February 20, 2024: Polymers
https://read.qxmd.com/read/38417141/ion-electron-co-conductive-triple-phase-interface-enabling-fast-redox-reaction-kinetics-in-lithium-sulfur-batteries
#6
JOURNAL ARTICLE
Huan Wang, Boyu Li, Yanlei Shen, Ziyao Zhang, Yinzhao Sun, Weitao Zhou, Shuaitong Liang, Weitao Li, Jianxin He
Lithium-sulfur batteries (LSBs) are promising next-generation energy storage systems because of their high energy densities and high theoretical specific capacities. However, most catalysts in the LSBs are based on carbon materials, which can only improve the conductivity and are unable to accelerate lithium-ion transport. Therefore, it would be worthwhile to develop a catalytic electrode exhibiting both ion and electron conductivity. Herein, a triple-phase interface using lithium lanthanum titanate/carbon (LLTO/C) nanofibers to construct ion/electron co-conductive materials was used to afford enhanced adsorption of lithium polysulfides (LiPSs), high conductivity, and fast ion transport in working LSBs...
February 28, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38387026/zero-strain-sodium-lanthanum-titanate-perovskite-embedded-in-flexible-carbon-fibers-as-a-long-span-anode-for-lithium-ion-batteries
#7
JOURNAL ARTICLE
Kuo Cao, Yiran Zhu, Haiyan He, Jingchao Xiao, Naiqing Ren, Juntao Si, Chunhua Chen
"High-capacity" graphite and "zero-strain" spinel Li4 Ti5 O12 (LTO) occupy the majority market of anode materials for Li+ storage in commercial applications. Nevertheless, their intrinsic drawbacks including the unsafe potential of graphite and unsatisfactory capacity of LTO limit the further development of lithium-ion batteries (LIBs), which is unable to satisfy the ever-increasing demands. Here, a novel Na0.35 La0.55 TiO3 perovskite embedded in multichannel carbon fibers (NLTO-NF) is rationally designed and synthesized through an electrospinning method...
February 22, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38334118/copper-enhanced-co-2-electroreduction-in-soecs
#8
JOURNAL ARTICLE
Umer Draz, Elisabetta Di Bartolomeo, Anna Paola Panunzi, Umberto Pasqual Laverdura, Nicola Lisi, Rosa Chierchia, Leonardo Duranti
The development of a Co-free and Ni-free electrocatalyst for carbon dioxide electrolysis would be a turning point for the large-scale commercialization of solid-oxide electrolysis cells (CO2 -SOECs). Indeed, the demand for cobalt and nickel is expected to become critical by 2050 due to automotive electrification. Currently, the reference materials for CO2 -SOEC electrodes are perovskite oxides containing Mn or Co (anodes) and Ni-YSZ cermets (cathodes). However, issues need to be addressed, such as structural degradation and/or carbon deposition at the cathode side, especially at high overpotentials...
February 9, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38325506/structural-design-of-la-2-co-3-3-loaded-magnetic-biochar-for-selective-removal-of-phosphorus-from-wastewater
#9
JOURNAL ARTICLE
Erming Ouyang, Hanrui Xiang, Rui Zhao, Hongwei Yang, Wanyuan He, Ruiyue Zhang
High levels of phosphorus released into the environment can cause eutrophication issues in wastewater, therefore discharge concentrations of such element are regulated in many countries. This study addresses the pressing need for effective phosphorus removal methods by developing a novel La2 (CO3 )3 and MnFe2 O4 loaded biochar composite (LMB). A remarkable adsorption capacity towards the three forms of phosphorus from wastewater, including phosphate, phosphite, and etidronic acid monohydrate (as a representative of organic phosphorus), was exhibited by LMB (88...
February 5, 2024: Environmental Pollution
https://read.qxmd.com/read/38296091/one-step-synthesis-of-phytic-acid-assisted-hydrochar-boost-selective-sorption-and-in-situ-passivation-of-lanthanum
#10
JOURNAL ARTICLE
Xiaodong Pei, Hailong Gao, Cenyao Shang, Junxia Huang, Mengting Ge, Huifang Xie, Yanfang Feng, Bingyu Wang
The rare earth metal element lanthanum (La) possesses carcinogenic, genotoxic, and accumulative properties, necessitating urgent development of an efficient and cost-effective method to remove La. However, current sorbents still encounter challenges such as poor selectivity, low sorption capacity, and high production costs. This study therefore proposes a promising solution: the creation of phytic acid-assisted sludge hydrochars (P-SHCs) to eliminate La from water and soil environments. This method harnesses phytic acid's exceptional binding ability and the economical hydrothermal carbonization process...
January 29, 2024: Science of the Total Environment
https://read.qxmd.com/read/38296068/contrasting-effects-of-a-traditional-material-of-polyaluminum-chloride-and-an-emerging-material-of-lanthanum-carbonate-capping-on-sediment-internal-phosphorus-immobilization
#11
JOURNAL ARTICLE
Qi Li, Wenming Yan, Minjuan Li, Xiang Chen, Tingfeng Wu, Xiangyu He, Qi Yao, Yulin Yan, Gaoxiang Li
Polyaluminum chloride (PAC) is a traditional material used for immobilizing sediment internal phosphorus (P) in field-scale experiment. Lanthanum carbonate (LC) is an emerging material which have been used in immobilizing sediment internal P in laboratory. To promote LC in practice, the premise is that it does have advantages over traditional material when used. Herein, a 90-day incubation experiment was conducted comparing the effectiveness and mechanism of LC and PAC capping in controlling sediment internal P...
January 29, 2024: Science of the Total Environment
https://read.qxmd.com/read/38250543/impact-of-rare-earth-elements-on-caco-3-crystallization-insights-into-kinetics-mechanisms-and-crystal-morphology
#12
JOURNAL ARTICLE
Luca Terribili, Remi Rateau, Adrienn M Szucs, Melanie Maddin, Juan Diego Rodriguez-Blanco
This study investigated the crystallization kinetics and mechanisms of calcium carbonate (CaCO3 ) in the presence of rare earth elements (REEs) including lanthanum (La), neodymium (Nd), and dysprosium (Dy). Through a comprehensive approach utilizing UV-vis spectrophotometry, powder X-ray diffraction, and high-resolution electron microscopy, we examined the effects of REEs on CaCO3 growth from solution at varying concentrations and combinations of REEs. Our findings highlight that even trace amounts of REEs significantly decelerate the rate of CaCO3 crystallization, also leading to alterations in crystal morphology and mechanisms of growth...
January 17, 2024: Crystal Growth & Design
https://read.qxmd.com/read/38224332/super-hydrophilic-lacoo-3-g-c-3-n-4-nanocomposite-coated-beauty-sponge-for-solar-driven-seawater-desalination-with-simultaneous-volatile-organic-compound-removal
#13
JOURNAL ARTICLE
Lokesh Kumar Rathore, Parul Garg, Piyush Kumar, Ashok Bera
Interfacial solar steam generation (ISSG) is emerging as a promising, environment-friendly solution for fulfilling freshwater and energy demands. However, a critical challenge for ISSG lies in the presence of harmful volatile organic compounds (VOCs) in the feedwater which are co-evaporated with water, leading to more enriched concentration in condensed water. Herein, lanthanum cobaltate-graphitic carbon nitride (LaCoO3 /g-C3 N4 , LCO/g-CN) nanocomposite decorated beauty sponge (LCO/g-CN@BS) is proposed as an efficient photothermal/photocatalytic material for solar-driven seawater desalination and simultaneous VOC degradation...
January 15, 2024: Nanoscale
https://read.qxmd.com/read/38203834/targeted-radium-alpha-therapy-in-the-era-of-nanomedicine-in-vivo-results
#14
REVIEW
György Trencsényi, Csaba Csikos, Zita Képes
Targeted alpha-particle therapy using radionuclides with alpha emission is a rapidly developing area in modern cancer treatment. To selectively deliver alpha-emitting isotopes to tumors, targeting vectors, including monoclonal antibodies, peptides, small molecule inhibitors, or other biomolecules, are attached to them, which ensures specific binding to tumor-related antigens and cell surface receptors. Although earlier studies have already demonstrated the anti-tumor potential of alpha-emitting radium (Ra) isotopes-Radium-223 and Radium-224 (223/224 Ra)-in the treatment of skeletal metastases, their inability to complex with target-specific moieties hindered application beyond bone targeting...
January 4, 2024: International Journal of Molecular Sciences
https://read.qxmd.com/read/38157572/long-term-evaluation-of-palm-oil-mill-effluent-pome-steam-reforming-over-lanthanum-based-perovskite-oxides
#15
JOURNAL ARTICLE
Yoke Wang Cheng, Chi Cheng Chong, Chin Kui Cheng, Chi-Hwa Wang, Kim Hoong Ng, Thongthai Witoon, Man Kee Lam, Jun Wei Lim
To replace the obsolete ponding system, palm oil mill effluent (POME) steam reforming (SR) over net-acidic LaNiO3 and net-basic LaCoO3 were proposed as the POME primary treatments, with promising H2 -rich syngas production. Herein, the long-term evaluation of POME SR was scrutinized with both catalysts under the optimal conditions (600 °C, 0.09 mL POME/min, 0.3 g catalyst, & 74-105 μm catalyst particle size) to examine the catalyst microstructure changes, transient process stability, and final effluent evaluation...
December 28, 2023: Journal of Environmental Management
https://read.qxmd.com/read/38151558/environmental-risk-of-ion-absorbed-rare-earth-ores-concentration-of-leaching-agent-and-fractionation-of-pb
#16
JOURNAL ARTICLE
Ying Gang Jia, Zhenli Yan, Liannan Shang, Jian Chen
Rare earth (RE) is an important strategic resource; however, there has been a growing concern about the environmental problems caused by RE mining, such as ammonia nitrogen pollution and heavy metal pollution. There is a limited research about the behavior of leaching agents and the fractionation of RE and heavy metal during the mining process for ion adsorption of rare earth ore (IRE-ore) in the previously available papers. In this study, (NH4 )2 SO4 solution, which commonly used in the production of mining IRE-ore, was used as a leaching agent...
December 27, 2023: Environmental Science and Pollution Research International
https://read.qxmd.com/read/38148422/the-deposition-of-lanthanum-carbonate-may-activate-macrophages-to-induce-gastrointestinal-mucosal-injury-in-patients-with-chronic-kidney-disease-an-in-vitro-caco-2-thp-1-macrophage-coculture-model-study
#17
JOURNAL ARTICLE
Ya-Ju Song, Hui-Xue Liu, Xiao-Gai Yang
The aim of this study was to investigate the effect and possible underlying mechanism of La2 (CO3 )3 deposition on GI mucosal inflammation. Our results showed that La2 (CO3 )3 can dissolve in artificial gastric fluids and form lanthanum phosphate (LaPO4 ) precipitates with an average size of about 1 μm. To mimic the intestinal mucosa and epithelial barrier, we established a Caco-2/THP-1 macrophage coculture model and a Caco-2 monoculture model, respectively. Our findings demonstrated that the medium of THP-1 macrophages stimulated by LaPO4 particles can damage the Caco-2 monolayer integrity in the coculture model, while the particles themselves had no direct impact on the Caco-2 monolayer integrity in the monoculture model...
December 26, 2023: Journal of Biological Inorganic Chemistry: JBIC
https://read.qxmd.com/read/38138843/la-2-o-3-ceo-2-supported-bimetallic-cu-ni-drm-catalysts
#18
JOURNAL ARTICLE
Pavel K Putanenko, Natalia V Dorofeeva, Tamara S Kharlamova, Maria V Grabchenko, Sergei A Kulinich, Olga V Vodyankina
The present work is focused on nickel catalysts supported on La2 O3 -CeO2 binary oxides without and with the addition of Cu to the active component for the dry reforming of methane (DRM). The catalysts are characterized using XRD, XRF, TPD-CO2 , TPR-H2 , and low-temperature N2 adsorption-desorption methods. This work shows the effect of different La:Ce ratios (1:1 and 9:1) and the Cu addition on the structural, acid base, and catalytic properties of Ni-containing systems. The binary LaCeOx oxide at a ratio of La:Ce = 1:1 is characterized by the formation of a solid solution with a fluorite structure, which is preserved upon the introduction of mono- or bimetallic particles...
December 18, 2023: Materials
https://read.qxmd.com/read/38138131/state-of-the-art-constraint-based-modeling-of-microbial-metabolism-from-basics-to-context-specific-models-with-a-focus-on-methanotrophs
#19
REVIEW
Mikhail A Kulyashov, Semyon K Kolmykov, Tamara M Khlebodarova, Ilya R Akberdin
Methanotrophy is the ability of an organism to capture and utilize the greenhouse gas, methane, as a source of energy-rich carbon. Over the years, significant progress has been made in understanding of mechanisms for methane utilization, mostly in bacterial systems, including the key metabolic pathways, regulation and the impact of various factors (iron, copper, calcium, lanthanum, and tungsten) on cell growth and methane bioconversion. The implementation of -omics approaches provided vast amount of heterogeneous data that require the adaptation or development of computational tools for a system-wide interrogative analysis of methanotrophy...
December 14, 2023: Microorganisms
https://read.qxmd.com/read/38098407/-preparation-of-bamboo-based-n-p-co-doped-activated-carbon-and-its-lanthanum-ion-adsorption-performance
#20
JOURNAL ARTICLE
Gui-Long Wang, Yan-Yan Liu, Rong-Yuan Jiang, Si-Min Li, Guan-Feng Lin, Bei-Li Lu, Biao Huang, Yan-Dan Chen
Using diammonium hydrogen phosphate as an activator and N and P source and and bamboo chips as the carbon source, N, P co-doped activated carbon was prepared by one-step pyrolysis and used to efficiently remove La3+ in aqueous solutions. The effects of activation temperature and pH value on the adsorption performance of La3+ were analyzed, and the activation and adsorption mechanisms were explored using TG-IR, SEM-EDX, pore structure, XPS, and hydrophilicity. The results showed that diammonium hydrogen phosphate easily decomposed at a high temperature to produce ammonia and phosphoric acid, which activated the material and promoted the increase in the specific surface area and pore volume of the activated carbon...
December 8, 2023: Huan Jing Ke Xue= Huanjing Kexue
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