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https://www.readbyqxmd.com/read/28435967/thermal-mismatch-strain-induced-disorder-of-y2mo3o12-and-its-effect-on-thermal-expansion-of-y2mo3o12-al-composites
#1
Chang Zhou, Qiang Zhang, Saiyue Liu, Bingcheng Luo, Eongyu Yi, Enke Tian, Guowu Li, Longtu Li, Gaohui Wu
Fully dense Y2Mo3O12/Al composites were prepared by squeeze-casting. Relatively mild conditions of 750 °C/20 min/50 MPa were used in order to avoid reaction of the components. SEM, Raman spectroscopy, XRD and dilatometry were used to characterize the microstructures and morphologies of the composites. Zero thermal expansion was achieved in the temperature range where the thermal mismatch strain was zero. We show that the CTE mismatch of Al and Y2Mo3O12 results in compressive and tensile strains that distort the Y2Mo3O12 lattice...
April 24, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28435874/toward-garnet-electrolyte-based-li-metal-batteries-an-ultrathin-highly-effective-artificial-solid-state-electrolyte-metallic-li-interface
#2
Kun Kelvin Fu, Yunhui Gong, Boyang Liu, Yizhou Zhu, Shaomao Xu, Yonggang Yao, Wei Luo, Chengwei Wang, Steven D Lacey, Jiaqi Dai, Yanan Chen, Yifei Mo, Eric Wachsman, Liangbing Hu
Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet-type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10(-3) to 10(-4) S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface...
April 2017: Science Advances
https://www.readbyqxmd.com/read/28435697/calcium-phosphates-and-silicon-exploring-methods-of-incorporation
#3
Ana I Rodrigues, Rui L Reis, Clemens A van Blitterswijk, Isabel B Leonor, Pamela Habibović
BACKGROUND: Bioinorganics have been explored as additives to ceramic bone graft substitutes with the aim to improve their performance in repair and regeneration of large bone defects. Silicon (Si), an essential trace element involved in the processes related to bone formation and remodeling, was shown not only to enhance osteoblasts proliferation but also to stimulate the differentiation of mesenchymal stem cells (MSCs) and preosteoblasts into the osteogenic lineage. In this study, the added value of Si to calcium phosphate (CaP) coatings was evaluated...
2017: Biomaterials Research
https://www.readbyqxmd.com/read/28435623/influence-of-nano-structured-alumina-coating-on-shear-bond-strength-between-y-tzp-ceramic-and-various-dual-cured-resin-cements
#4
Jung-Jin Lee, Jung-Yun Choi, Jae-Min Seo
PURPOSE: The purpose of this study was to evaluate the effect of nano-structured alumina surface coating on shear bond strength between Y-TZP ceramic and various dual-cured resin cements. MATERIALS AND METHODS: A total of 90 disk-shaped zirconia specimens (HASS CO., Gangneung, Korea) were divided into three groups by surface treatment method: (1) airborne particle abrasion, (2) tribochemicalsilica coating, and (3) nano-structured alumina coating. Each group was categorized into three subgroups of ten specimens and bonded with three different types of dual-cured resin cements...
April 2017: Journal of Advanced Prosthodontics
https://www.readbyqxmd.com/read/28435367/-ormocer-an-innovative-technology-a-replacement-for-conventional-cements-and-veneer-a-comparative-in-vitro-analysis
#5
Vini Rajeev, Rajeev Arunachalam, Sanjna Nayar, P R Arunima, Sivadas Ganapathy, Vaishnavi Vedam
OBJECTIVE: This in vitro study was designed to assess shear bond strength (SBS) of ormocer flowable (OF) resin as a luting agent, ormocer as an indirect veneer material with portrayal of modes of failures using scanning electron microscope (SEM). MATERIALS AND METHODS: Sixty maxillary central incisors were divided into Group I, II, and III with 20 samples each based on luting cement used. They were OF, self-adhesive (SA) cement, and total etch (TE) cement. These groups were subdivided into "a" and "b" of ten each based on the type of veneering materials used...
January 2017: European Journal of Dentistry
https://www.readbyqxmd.com/read/28435358/effect-of-cleaning-agent-primer-application-and-their-combination-on-the-bond-strength-of-a-resin-cement-to-two-yttrium-tetragonal-zirconia-polycrystal-zirconia-ceramics
#6
William Matthew Negreiros, Glaucia Maria Bovi Ambrosano, Marcelo Giannini
OBJECTIVE: The objective of this study is to evaluate the effect of a cleaning agent and priming on the bond strength (BS) of a resin cement (RC) to zirconia ceramics after 24 h and 1 year of water-storage. MATERIALS AND METHODS: Fifty-six Katana and 56 ZirCAD zirconia ceramic plates were prepared and each zirconia brand was divided into four groups (n = 14): (1) untreated; (2) treated with Ivoclean cleaning agent; (3) treated with Monobond Plus coupling agent; (4) treated with Ivoclean + Monobond Plus...
January 2017: European Journal of Dentistry
https://www.readbyqxmd.com/read/28434679/effect-of-fabrication-stages-and-cementation-on-the-marginal-fit-of-cad-cam-monolithic-zirconia-crowns
#7
Ediz Kale, Burak Yilmaz, Emre Seker, Tuncer Burak Özcelik
STATEMENT OF PROBLEM: Monolithic zirconia crowns fabricated using computer-aided design and computer-aided manufacturing (CAD-CAM) technology have recently become an alternative dental prosthetic treatment. The marginal fit of monolithic zirconia crown may be affected by different stages of the fabrication procedures in the laboratory and cementation. Information regarding the accuracy of fit of monolithic zirconia crowns at different stages of fabrication and cementation is limited. PURPOSE: The purpose of this in vitro study was to evaluate the effect of different stages of fabrication and cementation on the vertical marginal discrepancy (VMD) of CAD-CAM fabricated monolithic zirconia crowns...
April 20, 2017: Journal of Prosthetic Dentistry
https://www.readbyqxmd.com/read/28434556/cad-cam-techniques-help-in-the-rebuilding-of-ideal-marginal-gingiva-contours-of-anterior-maxillary-teeth-a-case-report
#8
Jiayue Yin, Dan Liu, Yuehua Huang, Lin Wu, Xiaolin Tang
BACKGROUND AND OVERVIEW: "Pink esthetics," which are considered to be as important as "white esthetics," have attracted increasing attention. To date, clinicians rarely have applied computer-aided design and computer-aided manufacturing (CAD/CAM) techniques in the rebuilding of the contour of the marginal gingiva in the esthetic zone. CASE DESCRIPTION: In this case report, the authors describe a female patient who had gingival inflammation and an asymmetrical contour of the marginal gingiva of the anterior maxillary teeth because previously placed ceramic crowns violated the biological width...
April 20, 2017: Journal of the American Dental Association
https://www.readbyqxmd.com/read/28434434/local-structural-damage-evaluation-of-a-c-c-sic-ceramic-matrix-composite
#9
Benedicta D Arhatari, Matthew Zonneveldt, John Thornton, Brian Abbey
Ceramic matrix composites (CMCs) are structural materials, which have useful properties that combine high strength at high temperatures with moderate toughness. Carbon fibers within a matrix of carbon and silicon carbide, called C/C-SiC, are a particular class of CMC noted for their high oxidation resistance. Here we use a combination of four-point bending and X-ray radiography, to study the mechanical failure of C/C-SiC CMCs. Correlating X-ray radiographic and load/displacement curve data reveals that the fiber bundles act to slow down crack propagation during four-point bending tests...
April 24, 2017: Microscopy and Microanalysis
https://www.readbyqxmd.com/read/28432999/effect-of-intra-oral-aging-on-t%C3%A2-m-phase-transformation-microstructure-and-mechanical-properties-of-y-tzp-dental-ceramics
#10
Luciana Meireles Miragaya, Renato Bastos Guimarães, Rodrigo Othávio de Assunção E Souza, Glauco Dos Santos Botelho, José Guilherme Antunes Guimarães, Eduardo Moreira da Silva
The aim of the present study was to evaluate the influence of intra-oral aging on the tetragonal-to-monoclinic (t→m) phase transformation of two Y-TZP dental ceramics - Lava Frame (Frame) and Lava Plus (Plus) - and determine the impact of this response on their microstructures and mechanical properties: flexural strength, Young's modulus, microhardness and fracture toughness. Standardized ceramic specimens were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM)...
April 13, 2017: Journal of the Mechanical Behavior of Biomedical Materials
https://www.readbyqxmd.com/read/28431686/adm-guidance-ceramics-all-ceramic-multilayer-interfaces-in-dentistry
#11
Ulrich Lohbauer, Susanne S Scherrer, Alvaro Della Bona, Michael Tholey, Richard van Noort, Alessandro Vichi, J Robert Kelly, Paulo F Cesar
This guidance document describes the specific issues involved in dental multilayer ceramic systems. The material interactions with regard to specific thermal and mechanical properties are reviewed and the characteristics of dental tooth-shaped processing parameters (sintering, geometry, thickness ratio, etc.) are discussed. Several techniques for the measurement of bond quality and residual stresses are presented with a detailed discussion of advantages and disadvantages. In essence no single technique is able to describe adequately the all-ceramic interface...
April 18, 2017: Dental Materials: Official Publication of the Academy of Dental Materials
https://www.readbyqxmd.com/read/28427632/ultrasonic-treatment-of-cofe2o4-b2o3-sio2-as-a-new-hybrid-magnetic-composite-nanostructure-and-catalytic-application-in-the-synthesis-of-dihydroquinazolinones
#12
Ali Maleki, Morteza Aghaei, Hamid Reza Hafizi-Atabak, Mohammad Ferdowsi
New hybrid magnetic composite nanostructure are prepared via ultrasonic treatment by glass-ceramic method, characterized by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), energy-dispersive X-ray (EDX), element distribution image (EDX mapping), thermal gravimetric analysis (TGA)/differential thermal analysis (DTA) and N2 adsorption-desorption by Brunauer-Emmett-Teller (BET) analyses. Then, the catalytic activity of the prepared CoFe2O4@B2O3-SiO2 nanoparticles was tested in the synthesis of 2-substituted-3-(phenylamino)-dihydroquinazolin-4(1H)-ones in deep eutectic solvent (DES) based on choline chloride as an eco-friendly and recyclable media...
July 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28426904/in-vitro-study-of-the-proliferation-and-growth-of-human-fetal-osteoblasts-on-mg-and-si-co-substituted-tricalcium-phosphate-ceramics
#13
Juan Parra, Ismael H García Páez, Antonio H De Aza, Carmen Baudin, M Rocío Martín, Pilar Pena
The objective of this work was to study the feasibility of the solid state sintering, a conventional ceramic processing method, to obtain Mg and Si co-substituted tricalcium phosphate bioceramics and composites containing diopside. A series of new Ca3 (PO4 )2 based ceramics has been prepared from attrition milled mixtures of synthetic Ca3 (PO4 )2 and CaMg(SiO3 )2 powders, isostatically pressed and sintered at 1250-1300°C. Materials containing 0, 1 and 5 wt.% of CaMg(SiO3 )2 were constituted by β + α - Ca3 (PO4 )2 solid solutions while the material containing 60 wt...
April 20, 2017: Journal of Biomedical Materials Research. Part A
https://www.readbyqxmd.com/read/28426434/neutron-scattering-by-dirac-multipoles
#14
S W Lovesey, D D Khalyavin
Scattering by magnetic charge formed by Dirac multipoles that are magnetic and polar is examined in the context of materials with properties that challenge conventional concepts. An order parameter composed of Dirac quadrupoles has been revealed in the pseudo-gap phase of ceramic, high-T c superconductors on the basis of Kerr effect and magnetic neutron Bragg diffraction measurements. Construction of Dirac quadrupoles that emerge from centrosymmetric sites used by Cu ions in the ceramic superconductor Hg1201 is illustrated, together with selection rules for excitations that will feature in neutron inelastic scattering, and RIXS experiments...
April 20, 2017: Journal of Physics. Condensed Matter: An Institute of Physics Journal
https://www.readbyqxmd.com/read/28426196/chiral-inorganic-nanostructures
#15
Wei Ma, Liguang Xu, André F de Moura, Xiaoling Wu, Hua Kuang, Chuanlai Xu, Nicholas A Kotov
The field of chiral inorganic nanostructures is rapidly expanding. It started from the observation of strong circular dichroism during the synthesis of simple nanoparticles (NPs) and their assemblies mediated by biomolecules and expanded to sophisticated synthetic protocols involving nanostructures from metals, semiconductors, ceramics, and nanocarbons. Besides the well-established chirality transfer from bioorganic molecules, other methods to impart handedness to nanoscale matter specific to inorganic materials were discovered, including three-dimentional lithography, multiphoton chirality transfer, polarization effects in nanoscale assemblies, and others...
April 20, 2017: Chemical Reviews
https://www.readbyqxmd.com/read/28425155/effect-of-platinum-on-sintering-morphology-of-porous-ysz-ceramics
#16
Pan Fang, Junmei Wang, Xian Li, Shijie Wu, Wenlei Zhang, Sufang Li
Platinum/yttria-stabilized zirconia (Pt/YSZ) porous ceramics were prepared by sintering of the Pt/PMMA/YSZ stripe-like membrane with a porogen of spherical polymethyl methacrylate (PMMA) and a precursor of platinum (Pt) of chloroplatinic acid. The microstructure of raw and processed material and Pt/ZrO2 calcination process at different sintering temperatures were investigated. The results showed that the spherically porous structure of Pt/YSZ was observed at a sintering temperature below 400 °C due to the thermal decomposition of PMMA...
April 19, 2017: Microscopy Research and Technique
https://www.readbyqxmd.com/read/28424734/influence-of-teeth-preparation-finishing-on-the-adaptation-of-lithium-disilicate-crowns
#17
Bruna Salamoni Sinhori, Mauro Amaral Caldeira de Andrada, Guilherme Carpena Lopes, Sylvio Monteiro Junior, Luiz Narciso Baratieri
The polishing step of teeth preparations for crowns is a step often performed, so that there is an increased time during the clinical procedure. The aim of this study is to evaluate the marginal and internal adaptation of all-ceramic CAD/CAM lithium disilicate crowns in polished preparations for crown and nonpolished preparations for crowns. For this purpose, 20 first molars were selected, which were divided into two groups (n = 10) G1, teeth that received surface roughening similar to preparation without polishing, and G2 (control), polished preparations...
2017: International Journal of Biomaterials
https://www.readbyqxmd.com/read/28422367/microtensile-bond-strength-of-a-resin-cement-to-silica-based-and-y-tzp-ceramics-using-different-surface-treatments
#18
Alireza Keshvad, Seyed Mohammad Reza Hakimaneh
PURPOSE: To evaluate the effects of different surface treatments on the microtensile bond strength (μTBS) of bonding between resin cement and lithia or zirconia-based ceramics using an in vitro study. MATERIALS AND METHODS: Three zirconia ceramic blocks (IPS e.max ZirCAD) and three lithium disilicate ceramic blocks (IPS e.max CAD) were sintered and duplicated in resin composite. The zirconia specimens underwent various treatments (n = 1): (i) Sandblast + primer (ZiSa); (ii) sandblast + laser irradiation + primer (ZiSaLa); or (iii) laser irradiation + primer (ZiLa)...
April 19, 2017: Journal of Prosthodontics: Official Journal of the American College of Prosthodontists
https://www.readbyqxmd.com/read/28421736/enhancing-the-bioactivity-of-yttria-stabilized-tetragonal-zirconia-ceramics-via-grain-boundary-activation
#19
Jinhuan Ke, Jiandong Ye, Fupo He
Yttria-stabilized tetragonal zirconia (Y-TZP) has been proposed as a potential dental implant due to its good biocompatibility, excellent mechanical properties, and distinctive aesthetic effect. However, Y-TZP cannot form chemical bonds with bone tissue because of its biological inertness, which affects the reliability and long-term efficacy of Y-TZP implants. In this study, to improve the bioactivity of Y-TZP ceramics while maintaining their good mechanical performance, Y-TZP was modified by grain boundary activation via the infiltration of a bioactive glass (BG) sol into the surface layer of Y-TZP ceramics under different negative pressures (atmospheric pressure, -0...
April 19, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28420832/effect-of-air-particle-pressures-on-the-surface-topography-and-bond-strengths-of-resin-cement-to-the-hybrid-ceramics
#20
Jong-Eun Kim, Jee-Hwan Kim, June-Sung Shim, Byoung-Duck Roh, Yooseok Shin
This study aimed to determine the appropriate pressure for airborne-abrasion by comparing the shear bond strength values for different hybrid ceramic surfaces. Two materials were used to produce hybrid ceramic specimens: Lava Ultimate and MAZIC Duro. The group of specimens whose surfaces were not subjected to airborne-abrasion was set as the control group. In the experimental group, airborne-abrasion was performed at pressures of 0.1, 0.2, and 0.3 MPa. After the adhesive and resin cement was applied, an SBS test was performed...
April 18, 2017: Dental Materials Journal
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