Thomas M Kirse, Iván Maisuls, María Victoria Cappellari, Erik Niehaves, Jutta Kösters, Alexander Hepp, Uwe Karst, Ezequiel Wolcan, Cristian A Strassert
In this work, we have explored Re(I) complexes featuring triphenylpnictogen ( PnPh 3 , Pn = P , As , or Sb )-based coligands and bidentate (neutral or monoanionic) luminophores derived from 1,10-phenantroline ( phen ), as well as from 2-(3-( tert -butyl)-1 H -1,2,4-triazol-5-yl)pyridine ( H(N- t Bu) ). The effect of the increasingly heavy elements on the structural parameters, photoexcited-state properties, and electrochemical behavior as well as the hybridization defects and polarization of the Pn atoms was related to the charges of the main luminophores (i...
February 21, 2024: Inorganic Chemistry