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Functional infra red spectroscopy

Andreas Iskra, Alexander S Gentleman, Aras Kartouzian, Michael J Kent, Alastair P Sharp, Stuart R Mackenzie
The structures of gas-phase M(+)(CO2)n (M = Co, Rh, Ir; n = 2-15) ion-molecule complexes have been investigated using a combination of infrared resonance-enhanced photodissociation (IR-REPD) spectroscopy and density functional theory. The results provide insight into fundamental metal ion-CO2 interactions, highlighting the trends with increasing ligand number and with different group 9 ions. Spectra have been recorded in the region of the CO2 asymmetric stretch around 2350 cm(-1) using the inert messenger technique and their interpretation has been aided by comparison with simulated infrared spectra of calculated low-energy isomeric structures...
January 3, 2017: Journal of Physical Chemistry. A
C S Pundir, V Aggarwal
The nanoparticles (NPs) aggregates of lipase from porcine pancreas, glycerol kinase (GK) from Cellulomonas sp. and glycerol-3-phosphate oxidase (GPO) from Aerococcus viridanss were prepared by desolvation and glutaraldehyde crosslinking and functionalized by cysteamine. These enzyme nanoparticles (ENPs) were characterized by transmission electron microscopy (TEM) and Fourier transform infra red (FTIR) spectroscopy. The functionalzed ENPs aggregates were co-immobilized covalently onto polycrystalline Au electrode through thiolated bond...
January 15, 2017: Analytical Biochemistry
S Anandhakumar, G Krishnamoorthy, K M Ramkumar, A M Raichur
In recent years, nanoparticles (NPs) based on biopolymers or peptides are gaining popularity for the encapsulation and release of drug molecules, especially for cancer therapy, due to their ability for targeted and controlled release. The use of collagen peptide (CP) for the preparation of chitosan (CN) NPs is especially interesting as it results in NPs that are stable under physiological conditions. In this work, mono-dispersed pH responsive CPCN NPs of about 100nm were prepared via ionic gelation method by simple and mild co-precipitation of CN and CP...
January 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
Anne-Laure Chateigner-Boutin, José J Ordaz-Ortiz, Camille Alvarado, Brigitte Bouchet, Sylvie Durand, Yves Verhertbruggen, Yves Barrière, Luc Saulnier
Cell walls are comprised of networks of entangled polymers that differ considerably between species, tissues and developmental stages. The cell walls of grasses, a family that encompasses major crops, contain specific polysaccharide structures such as xylans substituted with feruloylated arabinose residues. Ferulic acid is involved in the grass cell wall assembly by mediating linkages between xylan chains and between xylans and lignins. Ferulic acid contributes to the physical properties of cell walls, it is a hindrance to cell wall degradability (thus biomass conversion and silage digestibility) and may contribute to pest resistance...
2016: Frontiers in Plant Science
Atef Thamri, Hamdi Baccar, Claudia Struzzi, Carla Bittencourt, Adnane Abdelghani, Eduard Llobet
The chemical modification of multiwalled carbon nanotubes (MWCNTs) with a long chain mercapto acid is reported as a way to improve sensitivity and response time of gas sensors for detecting alcohols, acetone and toxic gases such as DMMP. We have developed sensors employing MWCNTs decorated with gold nanoparticles and modified with a 16-mercaptohexadecanoic acid (MHDA) monolayer. Morphological and compositional analysis by Transmission Electron Microscopy (TEM), Fourier Transform Infra-red Spectroscopy (FTIR) and X-ray photoelectron spectroscopy were performed to characterize the gold nanoparticles and to check the bonding of the thiol monolayer...
October 10, 2016: Scientific Reports
Saravanan Krishnan, Shoba Narayan, Anju Chadha
The cell free extracts of Candida parapsilosis ATCC 7330 are more efficient than the whole resting cells of the yeast in the synthesis of directly usable gold nanoparticles as revealed by this systematic study. Cell free extracts yielded gold nanoparticles of hydrodynamic diameter (50-200 nm). In this study, the total protein concentration influences the nanofabrication and not only the reductase enzymes as originally thought. Powder X-ray diffraction studies confirm the crystalline nature of the gold nanoparticles...
December 2016: AMB Express
Suresh K Kalangi, A Dayakar, D Gangappa, R Sathyavathi, R S Maurya, D Narayana Rao
Despite the existence of chemotherapy, there is no effective cure for leishmaniasis. In the light of recommended therapeutic regimen is attributed for toxicity and development of clinical resistance, exploration of an efficient method of drug delivery could be one of the option in reducing the dosage and toxicity of drugs. This work is aimed in such fashion to study the enhanced antileishmanial activity of miltefosine with silver-nanoparticles (AgNPs) synthesized by using Anethum graveolens (dill) leaf extract as reducing agent...
November 2016: Experimental Parasitology
Joanna Depciuch, Magdalena Sowa-Kućma, Gabriel Nowak, Dominika Dudek, Marcin Siwek, Krzysztof Styczeń, Magdalena Parlińska-Wojtan
Raman and FTIR (Fourier Transform Infra Red) spectroscopies provide information on the chemical structure of compounds through identification and analysis of functional groups. In the present study, both spectroscopic techniques were used for investigating the phospholipid - protein balance in blood serum of depressed subjects (major depressive disorder and bipolar disorder type I or II) taking also into account their age and gender. The obtained results were compared with those of healthy subjects. The Raman and FTIR (using ATR (Attenuated Total Reflectance) technique), spectra show that a correlation between the level of phospholipids and proteins exists...
November 30, 2016: Journal of Pharmaceutical and Biomedical Analysis
Opeyemi A Oyewo, Maurice S Onyango, Christian Wolkersdorfer
Transformation of agricultural waste such as banana peels into a valuable sorbent material has been proven effective and efficient in wastewater treatment. Further, transformation into nanosorbent to enhance the removal capacity of actinides (uranium and thorium) from synthetic and real mine water is extensively investigated in this study. The nanosorbent samples before and after adsorption were characterised by X-ray diffraction (XRD), Fourier transform infra-red (FTIR), zetasizer nanoseries and scanning electron microscopy (SEM) while the amount of radioactive substances adsorbed was determined by inductively coupled plasma optical emission spectroscopy...
November 2016: Journal of Environmental Radioactivity
Fabien Bibi, Maud Villain, Carole Guillaume, Brice Sorli, Nathalie Gontard
Polymers can be classified as synthetic polymers and natural polymers, and are often characterized by their most typical functions namely their high mechanical resistivity, electrical conductivity and dielectric properties. This bibliography report consists in: (i) Defining the origins of the dielectric properties of natural polymers by reviewing proteins. Despite their complex molecular chains, proteins present several points of interest, particularly, their charge content conferring their electrical and dielectric properties; (ii) Identifying factors influencing the dielectric properties of protein films...
2016: Sensors
Vaida Arcisauskaite, Domagoj Fijan, Mariano Spivak, Coen de Graaf, John E McGrady
Both density functional theory and multi-configurational ab initio (CASPT2) calculations are used to explore the potential energy surface of the hexagonal prismatic cluster [Mn@Si12](+). Unlike isoelectronic Cr@Si12, the ground state is a biradical, with triplet and open-shell singlet states lying very close in energy. The results are discussed in the context of recent experimental studies using infra-red multiple photon dissociation spectroscopy and X-ray MCD spectroscopy.
September 14, 2016: Physical Chemistry Chemical Physics: PCCP
R Karthikeyani, A Divya, T Mathavan, R Mohamed Asath, A Milton Franklin Benial, K Muthuchelian
This study investigates the structural and optical properties in the cribellate silk of the sheet web spider Stegodyphus sarasinorum Karsch (Eresidae) and the combined dragline, viscid silk of the orb-web spiders Argiope pulchella Thorell (Araneidae) and Nephila pilipes Fabricius (Nephilidae). X-ray diffraction (XRD), Fourier transform infra-red (FTIR), Ultraviolet-visible (UV-Vis) and fluorescence spectroscopic techniques were used to study these three spider silk species. X-ray diffraction data are consistent with the amorphous polymer network which is arising from the interaction of larger side chain amino acid contributions due to the poly-glycine rich sequences known to be present in the proteins of cribellate silk...
January 5, 2017: Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
Mahshid Chekini, Laure Guénée, Valentina Marchionni, Manish Sharma, Thomas Bürgi
Organic molecules imprinting can be used for introducing specific properties and functionalities such as chirality to mesoporous materials. Particularly organic self-assemblies can work as a scaffold for templating inorganic materials such as silica. During recent years chiral imprinting of anionic surfactant for fabrication of twisted rod-like silica structures assisted by co-structuring directing agent were thoroughly investigated. The organic self-assemblies of anionic surfactants can also be used for introducing other shapes in rod-like silica structures...
September 1, 2016: Journal of Colloid and Interface Science
Renato M Ribeiro-Viana, Paula C S Faria-Tischer, Cesar A Tischer
The anhydroglucose chains of cellulose possess hydroxyls that facilitate different chemical modification strategies to expand on, or provide new applications for membranes produced by the bacteria Gluconacetobacter xylinus. Conjugation with biomolecules such as proteins, especially by the amine groups, is of great value and interest for the production of biomaterial derivatives from bacterial cellulose. To assist in these modifications, cellulose was succinylated in order to prevent steric hindrance and to create an attachment point for conjugation...
September 5, 2016: Carbohydrate Polymers
Sadiya Anjum, Abha Arora, M S Alam, Bhuvanesh Gupta
Antimicrobial and scar preventive wound dressings were developed by coating a blend of chitosan (CS), polyethylene glycol (PEG) and polyvinyl pyrolidone (PVP) on the cotton fabric and subsequent freeze drying. The miscibility of blend systems and functional group interaction were investigated by attenuated total reflectance-infra red spectroscopy. The scanning electron microscopy of the coated fabric revealed porous structure. The porosity of the material was 54-70% and the pore size was in the range of 75-120μm depending on the blend composition...
July 11, 2016: International Journal of Pharmaceutics
Colette M McKay, Adnan Shah, Abd-Krim Seghouane, Xin Zhou, William Cross, Ruth Litovsky
Many studies, using a variety of imaging techniques, have shown that deafness induces functional plasticity in the brain of adults with late-onset deafness, and in children changes the way the auditory brain develops. Cross modal plasticity refers to evidence that stimuli of one modality (e.g. vision) activate neural regions devoted to a different modality (e.g. hearing) that are not normally activated by those stimuli. Other studies have shown that multimodal brain networks (such as those involved in language comprehension, and the default mode network) are altered by deafness, as evidenced by changes in patterns of activation or connectivity within the networks...
2016: Advances in Experimental Medicine and Biology
Aleksandra Biedrzycka, Romuald Lango
Conventional monitoring during surgery and intensive care is not sufficiently sensitive to detect acute changes in vital organs perfusion, while its good quality is critical for maintaining their function. Disturbed vital organ perfusion may lead to the development of postoperative complications, including neurological sequel and renal failure. Near-infra-red spectroscopy (NIRS) represents one of up-to-date techniques of patient monitoring which is commonly used for the assessment of brain oximetry in thoracic aorta surgery, and - increasingly more often -in open-heart surgery...
2016: Anaesthesiology Intensive Therapy
Joanna Depciuch, Magdalena Sowa-Kućma, Paulina Misztak, Bernadeta Szewczyk, Gabriel Nowak, Piotr Pankiewicz, Magdalena Parlińska-Wojtan
BACKGROUND: Dysfunctions in neuronal proteins can lead to development of depression. Lipids determine the localization and function of proteins in the cell membrane and thereby regulate synaptic throughput in neurons. The aim of study was to examine changes in the phospholipid-protein balance in the olfactory bulbectomy (OB) model of depression in rats using a Fourier transform infra-red (FTIR) spectroscopy. METHODS: Sprague Dawley rats were subjected to the OB procedure and treated with amitriptyline (AMI, 10mg/kg)...
June 2016: Pharmacological Reports: PR
A De Luca, S Santra, R Ghosh, S Z Ali, J W Gardner, P K Guha, F Udrea
In this paper we present a temperature-modulated graphene oxide (GO) resistive humidity sensor that employs complementary-metal-oxide-semiconductor (CMOS) micro-electro-mechanical-system (MEMS) micro-hotplate technology for the monitoring and control of indoor air quality (IAQ). GO powder is obtained by chemical exfoliation, dispersed in water and deposited via ink-jet printing onto a low power micro-hotplate. Atomic force microscopy (AFM) and transmission electron microscopy (TEM) show the typical layered and wrinkled morphology of the GO...
February 28, 2016: Nanoscale
Olivier Tsiakaka, Mehdi Terosiet, Olivier Romain, Aymeric Histace, Habib Benali, Pierre-Franois Pradat, Farouk Vallette, Michael Feher, Sylvain Feruglio
Little is known about the processes occurring after Spinal Cord damage. Whether permanent or recoverable, those processes have not been precisely characterized because their mechanism is complex and information on the functioning of this organ are partial. This study demonstrates the feasibility of Spinal Cord activity monitoring using Near Infra-Red Spectroscopy in a pig animal model. This animal has been chosen because of its comparable size and its similarities with humans. In the first step, optical characterization of the Spinal Cord tissues was performed in different conditions using a spectrophotometer...
August 2015: Conference Proceedings: Annual International Conference of the IEEE Engineering in Medicine and Biology Society
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