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https://www.readbyqxmd.com/read/28217797/poly-vinyl-alcohol-as-a-water-protecting-agent-for-silver-nanoparticles-the-role-of-polymer-size-and-structure
#1
Alexander Kyrychenko, Dmitry A Pasko, Oleg N Kalugin
Chemical modification of silver nanoparticles (AgNPs) with a stabilizing agent, such as poly(vinyl alcohol) (PVA), plays an important role in shape-controlled seeded-growth and colloidal stability. However, theoretical aspects of the stabilizing mechanism of PVA are still poorly understood. To gain a better understanding of the role of PVA in water protecting effects for silver nanoparticles, we developed an atomistic model of a AgNP grafted with single-chain PVA of various lengths. Our model, designed for classical molecular dynamics (MD) simulations, approximates the AgNP as a quasi-spherical silver nanocrystal with 3...
February 20, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/28214621/interaction-of-non-aqueous-dispersions-of-silver-nanoparticles-with-cellular-membrane-models
#2
Gustavo Bonomi Soriano, Roselaine da Silva Oliveira, Fernanda Ferraz Camilo, Luciano Caseli
In this work, silver nanoparticles (AgNPs) dispersed in non-aqueous media and stabilized with polyether block polymers amide (PEBA) were incorporated in Langmuir monolayers of dipalmitoylphosphatidylcholine (DPPC), which served as a cell membrane model. The AgNPs presented surface activity, disturbing the viscoelastic properties of the floating film. They expanded the monolayers decreasing their surface elasticity as observed with surface pressure-area isotherms. Polarization modulation reflection-absorption spectroscopy showed that the permanence of AgNPs at the air-water interface is favored by PEBA, affecting both the hydrophilic and the hydrophobic groups of the phospholipid...
February 13, 2017: Journal of Colloid and Interface Science
https://www.readbyqxmd.com/read/28214609/evaluation-of-vascular-tone-and-cardiac-contractility-in-response-to-silver-nanoparticles-using-langendorff-rat-heart-preparation
#3
Ramirez-Lee Manuel Alejandro, Martinez-Cuevas Pedro Pablo, Rosas-Hernandez Hector, Oros-Ovalle Cuauhtémoc, Bravo-Sanchez Mariela, Martinez-Castañon Gabriel Alejandro, Gonzalez Carmen
Silver nanoparticles (AgNPs) have been widely used because of their antimicrobial properties. However, several reports suggest that AgNPs exposure promote cardiac effects that involve nitric oxide (NO) and oxidative stress (OS). Nevertheless, there are no studies related to AgNPs-induced effects in cardiac physiology. The aim of this study was to evaluate the AgNPs direct actions on coronary vascular tone and cardiac contractility using Langendorff rat heart preparation. Low concentrations of AgNPs (0.1 and 1μg/mL) increased NO derived from inducible NO-synthase (iNOS), without modifying cardiac parameters...
February 15, 2017: Nanomedicine: Nanotechnology, Biology, and Medicine
https://www.readbyqxmd.com/read/28214590/green-engineered-biomolecule-capped-silver-and-copper-nanohybrids-using-prosopis-cineraria-leaf-extract-enhanced-antibacterial-activity-against-microbial-pathogens-of-public-health-relevance-and-cytotoxicity-on-human-breast-cancer-cells-mcf-7
#4
U Jinu, M Gomathi, I Saiqa, N Geetha, G Benelli, P Venkatachalam
This research focused on green engineering and characterization of silver (PcAgNPs) and copper nanoparticles (PcCuNPs) using Prosopis cineraria (Pc) leaf extract prepared by using microwave irradiation. We studied their enhanced antimicrobial activity on human pathogens as well as cytotoxicity on breast cancer cells (MCF-7). Biofabricated silver and copper nanoparticles exhibited UV-Visible absorbance peaks at 420 nm and 575 nm, confirming the bioreduction and stabilization of nanoparticles. Nanoparticles were characterized by FTIR, XRD, FESEM, and EDX analysis...
February 15, 2017: Microbial Pathogenesis
https://www.readbyqxmd.com/read/28213297/retention-of-silver-nano-particles-and-silver-ions-in-calcareous-soils-influence-of-soil-properties
#5
Samaneh Rahmatpour, Mehran Shirvani, Mohammad R Mosaddeghi, Mehdi Bazarganipour
The rapid production and application of silver nanoparticles (AgNPs) have led to significant release of AgNPs into the terrestrial environments. Once released into the soil, AgNPs could enter into different interactions with soil particles which play key roles in controlling the fate and transport of these nanoparticles. In spite of that, experimental studies on the retention of AgNPs in soils are very scarce. Hence, the key objective of this research was to find out the retention behavior of AgNPs and Ag(I) ions in a range of calcareous soils...
February 14, 2017: Journal of Environmental Management
https://www.readbyqxmd.com/read/28208089/low-dose-toxicity-of-biogenic-silver-nanoparticles-fabricated-by-swertia-chirata-on-root-tips-and-flower-buds-of-allium-cepa
#6
Nirlipta Saha, S Dutta Gupta
Chemically synthesized silver nanoparticles (chem-AgNPs) have been assessed extensively to show adverse effects on plant cells but the role of biologically synthesized nanoparticles (bio-AgNPs) at lower concentrations and their toxicological impact on plant cells have not been sufficiently studied. In this study, bio-AgNPs were prepared using aqueous leaf extracts of Swertia chirata. This AgNPs showed absorption peak at 440nm of the visible spectrum. TEM analysis revealed that the average size of AgNPs were 20nm and mainly spherical in shape...
February 9, 2017: Journal of Hazardous Materials
https://www.readbyqxmd.com/read/28202922/removal-of-silver-nanoparticles-by-mussel-inspired-fe3o4-polydopamine-core-shell-microspheres-and-its-use-as-efficient-catalyst-for-methylene-blue-reduction
#7
Maoling Wu, Yinying Li, Rui Yue, Xiaodan Zhang, Yuming Huang
The removal of silver nanoparticles (AgNPs) from water is highly needed because of their increasing use and potential risk to the environment due to their toxic effects. Catalysis over AgNPs has received significant attention because of their highly catalytic performance. However, their use in practical applications is limited due to high cost and limited resources. Here, we present for the first time that the mussel-inspired Fe3O4@polydopamine (Fe3O4@PDA) nanocomposite can be used for efficient removal and recovery of AgNPs...
February 16, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28197855/soil-microbial-community-responses-to-contamination-with-silver-aluminium-oxide-and-silicon-dioxide-nanoparticles
#8
C F McGee, S Storey, N Clipson, E Doyle
Soil microorganisms are key contributors to nutrient cycling and are essential for the maintenance of healthy soils and sustainable agriculture. Although the antimicrobial effects of a broad range of nanoparticulate substances have been characterised in vitro, little is known about the impact of these compounds on microbial communities in environments such as soil. In this study, the effect of three widely used nanoparticulates (silver, silicon dioxide and aluminium oxide) on bacterial and fungal communities in an agricultural pastureland soil was examined in a microcosm-based experiment using a combination of enzyme analysis, molecular fingerprinting and amplicon sequencing...
February 14, 2017: Ecotoxicology
https://www.readbyqxmd.com/read/28196456/toxicity-of-internalized-laser-generated-pure-silver-nanoparticles-to-the-isolated-rat-hippocampus-cells
#9
Canan Kursungoz, Sadık Taşkın Taş, Mustafa F Sargon, Yıldırım Sara, Bülend Ortaç
Silver nanoparticles (AgNPs) are the most commonly used nanoparticles (NPs) in medicine, industry and cosmetics. They are generally considered as biocompatible. However, contradictory reports on their biosafety render them difficult to accept as 'safe'. In this study, we evaluated the neurotoxicity of direct AgNP treatment in rat hippocampal slices. We produced pure uncoated AgNPs by a pulsed laser ablation method. NP characterization was performed by Ultraviolet (UV) visible spectrophotometer, scanning electron microscope, transmission electron microscope (TEM) and energy-dispersive X-ray spectroscopy...
January 1, 2017: Toxicology and Industrial Health
https://www.readbyqxmd.com/read/28192905/extracting-metallic-nanoparticles-from-soils-for-quantitative-analysis-method-development-using-engineered-silver-nanoparticles-and-sp-icp-ms
#10
D M Schwertfeger, Jessica R Velicogna, Alexander H Jesmer, Selin Saatcioglu, Heather McShane, Richard P Scroggins, Juliska I Princz
The lack of an efficient and standardized method to disperse soil particles and quantitatively subsample the nanoparticulate fraction for characterization analyses is hindering progress in assessing the fate and toxicity of metallic engineered nanomaterials in the soil environment. This study investigates various soil extraction and extract preparation techniques for their ability to remove nanoparticulate Ag from a field soil amended with biosolids contaminated with engineered silver nanoparticles (AgNPs), while presenting a suitable suspension for quantitative single-particle inductively coupled plasma mass spectroscopy (SP-ICP-MS) analysis...
January 30, 2017: Analytical Chemistry
https://www.readbyqxmd.com/read/28189097/thermo-responsive-nanoarrays-of-silver-nanoparticle-silicate-nanoplatelet-and-pnipaam-for-the-antimicrobial-applications
#11
Hsiao-Chu Lin, Yu-An Su, Ting-Yu Liu, Yu-Jane Sheng, Jiang-Jen Lin
The ternary nanohybrids of silver nanoparticles (AgNPs) in combination with silicate nanoplatelets (NSP) and thermally sensitive poly(N-isopropylacrylamide) (PNiPAAm) were fabricated for antibacterial applications. PNiPAAm were chemically grafted on the NSP by atom-transfer radical polymerization (ATRP) via polymerizing N-isopropylacrylamide monomers with sol-gel linkers (BBTES). The nanoparticles of AgNPs then were adsorbed on NSP-PNiPAAm nanosheets through in situ reduction reaction of AgNO3 in aqueous dispersion...
January 27, 2017: Colloids and Surfaces. B, Biointerfaces
https://www.readbyqxmd.com/read/28187403/green-synthesis-of-silver-nanoparticle-for-the-selective-and-sensitive-colorimetric-detection-of-mercury-ii-ion
#12
Vijay Kumar, Devendra K Singh, Sweta Mohan, Daraksha Bano, Ravi Kumar Gundampati, Syed Hadi Hasan
An ecofriendly and zero cost approach has been developed for the photoinduced synthesis of more stable AgNPs using an aqueous extract of Murraya koenigii (AEM) as a reducing and stabilizing agent. The exposed reaction mixture of AEM and AgNO3 to sunlight turned dark brown which primarily confirmed the biosynthesis of AgNPs. The biosynthesis was monitored by UV-vis spectroscopy which exhibited a sharp SPR band at 430nm after 30min of sunlight exposure. The optimum conditions for biosynthesis of AgNPs were 30min of sunlight exposure, 2...
January 31, 2017: Journal of Photochemistry and Photobiology. B, Biology
https://www.readbyqxmd.com/read/28184215/uptake-accumulation-and-toxicity-of-silver-nanoparticle-in-autotrophic-plants-and-heterotrophic-microbes-a-concentric-review
#13
REVIEW
Durgesh K Tripathi, Ashutosh Tripathi, Shweta, Swati Singh, Yashwant Singh, Kanchan Vishwakarma, Gaurav Yadav, Shivesh Sharma, Vivek K Singh, Rohit K Mishra, R G Upadhyay, Nawal K Dubey, Yonghoon Lee, Devendra K Chauhan
Nanotechnology is a cutting-edge field of science with the potential to revolutionize today's technological advances including industrial applications. It is being utilized for the welfare of mankind; but at the same time, the unprecedented use and uncontrolled release of nanomaterials into the environment poses enormous threat to living organisms. Silver nanoparticles (AgNPs) are used in several industries and its continuous release may hamper many physiological and biochemical processes in the living organisms including autotrophs and heterotrophs...
2017: Frontiers in Microbiology
https://www.readbyqxmd.com/read/28184158/biological-activity-of-green-synthesized-silver-nanoparticles-depends-on-the-applied-natural-extracts-a-comprehensive-study
#14
Andrea Rónavári, Dávid Kovács, Nóra Igaz, Csaba Vágvölgyi, Imre Miklós Boros, Zoltán Kónya, Ilona Pfeiffer, Mónika Kiricsi
Due to obvious disadvantages of the classical chemical methods, green synthesis of metallic nanoparticles has attracted tremendous attention in recent years. Numerous environmentally benign synthesis methods have been developed yielding nanoparticles via low-cost, eco-friendly, and simple approaches. In this study, our aim was to determine the suitability of coffee and green tea extracts in green synthesis of silver nanoparticles as well as to compare the performance of the obtained materials in different biological systems...
2017: International Journal of Nanomedicine
https://www.readbyqxmd.com/read/28183660/anticancer-activity-of-biologically-synthesized-silver-and-gold-nanoparticles-on-mouse-myoblast-cancer-cells-and-their-toxicity-against-embryonic-zebrafish
#15
Rajan Ramachandran, Chandran Krishnaraj, Allur Subramaniyan Sivakumar, Palaniappan Prasannakumar, V K Abhay Kumar, Kwan Seob Shim, Chul-Gyu Song, Soon-Il Yun
The aim of this study was to evaluate the anticancer activity of bioinspired silver nanoparticles (AgNPs) and gold nanoparticles (AuNPs) against mouse myoblast cancer cells (C2C12). Both AgNPs and AuNPs were biologically synthesized using Spinacia oleracea Linn., aqueous leaves extract. UV-Vis. spectrophotometer, high resolution-transmission electron microscopy (HR-TEM), field emission-scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD) studies supported the successful synthesis of AgNPs and AuNPs...
April 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/28183643/silver-deposited-carboxymethyl-chitosan-grafted-magnetic-nanoparticles-as-dual-action-deliverable-antimicrobial-materials
#16
Duc-Thang Vo, Sabrina Sabrina, Cheng-Kang Lee
Carboxymethyl chitosan (CMCS) was known to have a much better antimicrobial activity than chitosan due to the increased cationic -NH3(+) groups resulted from the intra- and intermolecular interactions between the carboxyl and amino groups. CMCS was grafted onto the surface of silica coated magnetic nanoparticles (MNPs) to obtain magnetically retrievable and deliverable antimicrobial nanoparticles (MNPs@CMCS). The presence of carboxylate groups in CMCS not only enhanced antimicrobial activity but also enabled Ag ions chelating ability to induce the in situ formation of Ag nanoparticles (AgNPs)...
April 1, 2017: Materials Science & Engineering. C, Materials for Biological Applications
https://www.readbyqxmd.com/read/28181394/effects-of-silver-nanoparticles-on-the-interactions-of-neuron-and-glia-like-cells-toxicity-uptake-mechanisms-and-lysosomal-tracking
#17
I-Lun Hsiao, Yi-Kong Hsieh, Chun-Yu Chuang, Chu-Fang Wang, Yuh-Jeen Huang
Silver nanoparticles (AgNPs) are commonly used nanomaterials in consumer products. Previous studies focused on its effects on neurons; however, little is known about their effects and uptake mechanisms on glial cells under normal or activated states. Here, ALT astrocyte-like, BV-2 microglia and differentiated N2a neuroblastoma cells were directly or indirectly exposed to 10 nm AgNPs using mono- and co-culture system. A lipopolysaccharide (LPS) was pretreated to activate glial cells before AgNP treatment for mimicking NP exposure under brain inflammation...
February 9, 2017: Environmental Toxicology
https://www.readbyqxmd.com/read/28177254/experimental-and-numerical-investigations-of-silver-nanoparticle-transport-under-variable-flow-and-ionic-strength-in-soil
#18
Joanna Makselon, Dan Zhou, Irina Engelhardt, Diederik Jacques, Erwin Klumpp
Unsaturated column experiments were conducted with an undisturbed loamy sand soil to investigate the influence of flow interruption (FI) and ionic strength (IS) on the transport and retention of surfactant-stabilized silver nanoparticles (AgNP) and the results were compared to those obtained under continuous flow conditions. AgNP concentrations for breakthrough curves (BTCs) and retention profiles (RPs) were analyzed by ICP-MS. Experimental results were simulated by the numerical code HP1 (Hydrus-PhreeqC) with the DLVO theory, extended colloid filtration theory and colloid release model...
February 8, 2017: Environmental Science & Technology
https://www.readbyqxmd.com/read/28176951/in-vitro-and-in-vivo-evaluation-of-biologically-synthesized-silver-nanoparticles-for-topical-applications-effect-of-surface-coating-and-loading-into-hydrogels
#19
Aml I Mekkawy, Mohamed A El-Mokhtar, Nivien A Nafady, Naeima Yousef, Mostafa A Hamad, Sohair M El-Shanawany, Ehsan H Ibrahim, Mahmoud Elsabahy
In the present study, silver nanoparticles (AgNPs) were synthesized via biological reduction of silver nitrate using extract of the fungus Fusarium verticillioides (green chemistry principle). The synthesized nanoparticles were spherical and homogenous in size. AgNPs were coated with polyethylene glycol (PEG) 6000, sodium dodecyl sulfate (SDS), and β-cyclodextrin (β-CD). The averaged diameters of AgNPs were 19.2±3.6, 13±4, 14±4.4, and 15.7±4.8 nm, for PEG-, SDS-, and β-CD-coated and uncoated AgNPs, respectively...
2017: International Journal of Nanomedicine
https://www.readbyqxmd.com/read/28176261/sampling-for-silver-nanoparticles-in-aqueous-media-using-a-rotating-disk-electrode-evidence-for-selective-sampling-of-silver-nanoparticles-in-the-presence-of-ionic-silver
#20
Spencer Steinberg, Vernon Hodge, Brian Schumacher, Wayne Sovocool
Amendment of a carbon paste electrode consisting of graphite and Nujol®, with a variety of organic and inorganic materials, allows direct adsorption of silver nanoparticles (AgNPs) from aqueous solution in either open or close circuit modes. The adsorbed AgNPs are detected by stripping voltammetry. Detection limits of less than 1 ppb Ag are achievable with a rotating disk system. More than one silver peak was apparent in many of the stripping voltammograms. The appearance of multiple peaks could be due to different species of silver formed upon stripping or variation in the state of aggregation or size of nanoparticles...
March 2017: Environmental Monitoring and Assessment
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