Polyaniline nanofibers

A novel MoS2 /polyaniline (PANI)/polyacrylonitrile (PAN)@BiFeO3 bilayer hollow nanofiber membrane (PPBM-H) was successfully synthesized by coaxial electrospinning technique. In the nanofiber, BiFeO3 nanoparticles (NPs) and MoS2 nanosheets (NSs) were loaded in the middle and outer layers of the PANI/PAN composites, respectively, which constructs a type II heterojunction with spatially separated microtopography, thus significantly improving the charge separation in photocatalysis. Moreover, the hollow structure and the vast number of exposed groups on the surface of PPBM-H help to improve the mass transfer efficiency and pollutant adsorption performance in wastewater treatment...

The coaxial electrospinning method for preparation of g-C3 N4 /polyacrylonitrile (PAN)/polyaniline (PANI)@LaFeO3 cable fiber membrane (PC@PL) was designed for adsorption-filtration-photodegradation of pollutants. A series of characterization results show that LaFeO3 and g-C3 N4 nanoparticles (NPs) are respectively loaded in the inner and outer layers of PAN/PANI composite fibers to construct the site-specific Z-type heterojunction system with spatially separated morphologies. The PANI in cable not only possesses abundant exposed amino/imino functional groups for adsorption of contaminant molecules but also due to the excellent electrical conductivity works as a redox medium for collecting and consuming the electrons and holes from LaFeO3 and g-C3 N4 , which can efficiently promote photo-generated charge carriers separation and improve the catalytic performance...

We developed an integrated gas diffusion layer (GDL) for proton exchange membrane (PEM) fuel cells by growing carbon nanofibers (CNFs) in situ on carbon paper via the electro-polymerization of polyaniline (PANI) on carbon paper followed by a subsequent carbonization treatment process. The CNF/carbon paper showed a microporous structure and a significantly increased pore volume compared to commercial carbon paper. By utilizing this CNF/carbon paper in a PEM fuel cell, it was found that the cell with CNF/carbon paper had superior performance compared to the commercial GDL at both high and low humidity conditions, and its power density was as high as 1...

Developing highly efficient and stable precious metal electrocatalysts toward hydrogen evolution reaction (HER) is crucial for energy application, while it is still challenging to achieve highly dispersed ultrafine metal nanoparticles on some promising supports to synergistically promote their electrocatalytic performance. Herein, we propose a feasible chelating adsorption-engaged strategy by introducing de-doped polyaniline with abundant amino groups to immobilize ultrafine iridium (Ir) nanoparticles on their derived N-doped carbon nanofibers (Ir-NCNFs)...

Simple and green strategy was described for the development of multifunctional polyester nanofibers (PNFs). Solution blow spinning (SBS) technology was applied to in situ immobilize nanocomposites of polyaniline (PANi) and silver nanoparticles (AgNPs) into plasma-treated polyester nanoscaled fibers prepared. The polyester nanofibers were prepared from recycled polyethylene terephthalate waste, which was exposed plasma-curing and a REDOX reaction in the presence of AgNO3 , aniline, and CH3 COONH4 . Plasma-catalyzed oxidative polymerization of aniline to polyaniline together with a reductive process of Ag+ to silver nanoparticles led to their enduring insoluble dispersion into the surface of polyester nanofibers...

With the development of convergence technology, the Internet of Things (IoT), and artificial intelligence (AI), there has been increasing interest in the materials industry. In recent years, numerous studies have attempted to identify and explore multi-functional cutting-edge hybrid materials. In this paper, the international literature on the materials used in hybrid fibers and manufacturing technologies were investigated and their future utilization in the industry is predicted. Furthermore, a systematic review is also conducted...

Nanofeatured polyaniline (PANI) electrodes have demonstrated impressive sensing performance due to the enhanced electrolyte diffusion and ion transport. However, the retaining of these nanostructures on substrates via electrophoretic deposition (EPD) faces an insurmountable challenge from the involved dedoping process. Here, camphorsulfonic acid is utilized with high steric effects to dope PANI (PANI-CSA) that can be directly used EPD without involving a dedoping process. Five different nanofeatures (sea cucumber-like, nanofiber, amorphous, nanotube, and nanorod) are synthesized, and they have been all successfully transferred onto indium tin oxide substrate in a formic acid/acetonitrile system, namely a morphology memory effect...

Polyaniline (PANI), due to the various and controllable shapes, the environmental stability, the excellent physical and chemical property, has gained significant attention. PANI with abundant morphologies were successfully prepared through adjusting and controlling the state of the initial micelle-like in the micelle-like system composed by aniline and organic acids with relatively weak intermolecular interaction. Although the influence of the inorganic salts on their morphology, including the surface and the diameter, was investigated, the influence of salt on the nucleation of PANI was still unclear...

In recent years, supercapacitors based on cellulose nanofiber (CNF) films have received considerable attention for their excellent flexibility, lightweight, and unique structure. In this study, MXene (Ti3 C2 Tx ) /CNF/polyaniline (PANI) hybrid films with good conductivity and flexibility were prepared by a convenient vacuum filtration method. Combined with PANI, MXene creates an open structure with high conductivity, which facilitates ion and electron transport among the materials and provides the composite with high electrochemical activity...

Composite biopolymer/conducting polymer scaffolds, such as polylactic acid (PLA)/ polyaniline (PAni) nanofibers, have emerged as popular alternative scaffolds in the electrical-sensitive nerve tissue engineering (TE). Although mimicking the extracellular matrix geometry, such scaffolds are highly hydrophobic and usually present an inhomogeneous morphology with massive beads that impede nerve cell-material interactions. Therefore, the present study launches an exclusive combinatorial strategy merging successive pre- and post-electrospinning plasma treatments to cope with these issues...

In the development of energy supply systems for smart wearable devices, supercapacitors stand out owing to their ability of quick and efficient energy supply. However, their application is limited due to their low energy density and poor mechanical energy. Herein, a strategy for the preparation of flexible supercapacitors is reported, which is based on the fabrication of aerogel films by simultaneously utilising cellulose nanofiber (CNFs) as an MXene intercalation material and polyaniline (PANI) as a template material...

The potential of application of an electrospun nanofiber sheet as new polymeric support for immobilizing the liquid membrane, instead of a common commercial polypropylene sheet, in on-chip electromembrane extraction (EME) of some acidic polar drugs followed by HPLC with ultraviolet detection is presented. The nanofiber sheet was prepared by electrospinning a mixture of polycaprolactone and polyaniline. The successful synthesis of the electrospun nanofiber sheet was confirmed by field emission-scanning electron microscopy, energy-dispersive X-ray spectroscopy, elemental mapping, and atomic force microscopy...

Recent trends in tissue engineering technology have switched to electrical potentials generated through bioactive scaffolds regarding their appropriate effects on cell behaviors. Preparing a piezo-electrical stimuli scaffold with high electrical conductivity for bone and cartilage tissue regeneration is the ultimate goal of the present study. Here, Barium Titanate nanoparticles (BaTiO3 NPs) were used as piezoelectric material and highly conductive binary doped Polyaniline nanoparticles (PANI NPs) were synthesized by oxidative polymerization...

Use of the nanocomposite of chloride-doped polyaniline nanofibers and multiwalled carbon nanotubes (PANINFs-Cl:MWCNTs) for construction of ion-selective electrodes with solid-contact sensitive to chloride ions has been described. Many types of electrodes were tested, differing in the quantitative and qualitative composition of the layer placed between the electrode material and the ion-selective membrane. Initial tests were carried out, including tests of electrical properties of intermediate solid-contact layers...

Polyaniline (PANi) hydrogels often exhibit highly mechanical and electrochemical properties, which have received extensive attention in the fields of batteries, supercapacitors, and sensors. However, the shortcomings such as hydrophobicity and easy aggregation of PANi frequently result in deterioration of mechanical and electrochemical performance of PANi hydrogels. Here, a bifunctional natural product, glycyrrhizic acid (GL), is utilized to prepare the homogeneous conductive PANi hydrogel, because GL not only can assemble into supramolecular hydrogel as the biocompatible matrix but also can salinize aniline monomers to facilitate the polymerization in situ to form uniformly dispersed PANi within GL matrix...

In recent decades, studies have focused on inorganic nanozymes to overcome the intrinsic drawbacks of bioenzymes due to the demands of improving the reaction conditions and lack of robustness to harsh environmental factors. Many biochemical reactions catalyzed by enzymes require light activation. Light-activated nanozymes have distinct advantages, including being regulated by light stimuli, activating the molecular oxygen to produce reactive oxygen species (ROS) without interfering supplementary oxidants, and often showing a synergistic effect to catalyze some challenging reactions...

A novel potentiometric solid contact (SC) sensor was developed to determine the anticancer drug gefitinib by employing a polyaniline nanofibers/carboxylated multi-walled carbon nanotube (PANI-NFs/c-MWCNT) nano-composite as an ion to electron transducer. The FDA approved gefitinib as the first line treatment of non-small cell lung cancer (NSCLC) that represents 90% of lung carcinomas. The PANI-NFs/C-MWCNT nano-composite was synthesized and characterized using Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM)...

Designing novel efficient electrode materials with controlled hierarchical structure and composition for advanced supercapacitors remains a great challenge. Herein, a core-triple-shelled hierarchical GCNF/PANI/NCO nanostructure has been designed and fabricated by sequential growth of the conductive polyaniline (PANI) layers and nickel carbonate hydroxide (Ni2 (CO3 )(OH)2 ) nanosheets on the graphene-coated electrospun carbon nanofibers (GCNF) via a facile wet-chemical strategy. Taking full advantage of the free-standing architecture of graphene-coated electrospun carbon nanofibers, high conductivity and flexibility of the PANI layers, and abundant active sites of Ni2 (CO3 )(OH)2 nanosheets, the optimal GCNF/PANI/NCO (2 h) electrode exhibits a high specific capacitance of 1565F g-1 at 1 A/g and enhanced rate capability, which are higher than those of the GCNF, GCNF/PANI, and GCNF/NCO (2 h) electrodes at the same situation, and also exceeds most of the reported nickel carbonate hydroxide-based electrodes in literature...

Immobilized enzymes are better suited for industrial applications than free enzymes due to their favorable properties such as ease of separation and reuse, and enhanced stability and storage life. β-Galactosidases are an important class of glycosidases with hydrolysis and transglycosylation activities, which are applied in industries for lactose hydrolysis and prebiotics synthesis worldwide. The recent innovations in immobilized β-galactosidases have improved the performance of the immobilized enzymes and broadened their applications in the fields of food, energy, and medicine...

The complicated preparation process and low energy density of polyaniline (PANI)-based electrodes limit their wide applications in flexible energy storage devices. In this work, a reduced graphene (rGO)-wrapped polyaniline nanofiber network (PANI-NFN)/oxidized carbon cloth (OCC) (rGO@PANI-NFN/OCC) composite was prepared by a facile impregnation method using reactive templates of MnO2 on the surface of OCC. The as-prepared rGO@PANI-NFN/OCC composite exhibited a high area specific capacitance of 4438 mF cm-2 and maintained an initial capacitance of 88...