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https://www.readbyqxmd.com/read/28225195/protective-effect-of-hydroxytyrosol-in-arsenic-induced-mitochondrial-dysfunction-in-rat-brain
#1
Manisha Soni, Chandra Prakash, Sfurti Sehwag, Vijay Kumar
The present study was planned to investigate the protective effect of hydroxytyrosol (HT) against arsenic (As)-induced mitochondrial dysfunction in rat brain. Rats exposed to sodium arsenite (25 ppm for 8 weeks) showed decreased mitochondrial complexes (I, II, IV) activities, mitochondrial superoxide dismutase (MnSOD), and catalase activities in brain mitochondria. As-treated rats showed reduced mRNA expression of complex I (ND-1, ND-2), IV (COX-1, COX-4) subunits, and uncoupling protein-2 (UCP-2). In addition to this, As exposure downregulated the protein expression of MnSOD...
February 22, 2017: Journal of Biochemical and Molecular Toxicology
https://www.readbyqxmd.com/read/28225109/on-the-coordination-non-innocence-of-antimony-in-nickel-ii-complexes-of-the-tetradentate-o-ph2p-c6h4-3sb-ligand
#2
J Stuart Jones, Casey R Wade, Mengxi Yang, François P Gabbaï
In a continuation of our investigations into the unusual properties of antimony-based ligands, we have decided to investigate the structure of the complexes formed by the tetradentate ligands (o-(Ph2P)C6H4)3E (E = P (1), As (2), Sb (3)) with NiCl2. We observed that the structure of the resulting complexes depends on the nature of the central pnictogen atom E, with the phosphorus- and arsenic-based systems adopting ionic structures of the type [ClNi(o-(Ph2P)C6H4)3E][Cl] (E = P ([4][Cl]), As ([5][Cl])) while the known antimony complex ClNi(o-(Ph2P)C6H4)3SbCl (6-Cl) is molecular, with a chloride anion bound to the antimony atom trans from the nickel atom...
February 22, 2017: Dalton Transactions: An International Journal of Inorganic Chemistry
https://www.readbyqxmd.com/read/28224177/joint-toxicity-of-arsenic-copper-and-glyphosate-on-behavior-reproduction-and-heat-shock-protein-response-in-caenorhabditis-elegans
#3
Yunbiao Wang, Anastasia N Ezemaduka, Zhuheng Li, Zhanyan Chen, Chuantao Song
The soil nematode Caenorhabditis elegans was used in 24-h acute exposures to arsenic (As), copper (Cu) and glyphosate (GPS) and to mixtures of As/Cu and As/GPS to investigate the effects of mixture exposures in the worms. A synergistic type of interaction was observed for acute toxicity with the As/Cu and As/GPS mixtures. Sublethal 24-h exposures of 1/1000, 1/100 and 1/10 of the LC50 concentrations for As, Cu and GPS individually and for As/Cu and As/GPS mixtures were conducted to observe responses in locomotory behavior (head thrashing), reproduction, and heat shock protein expression...
February 21, 2017: Bulletin of Environmental Contamination and Toxicology
https://www.readbyqxmd.com/read/28223993/diacylglycerol-kinases-are-widespread-in-higher-plants-and-display-inducible-gene-expression-in-response-to-beneficial-elements-metal-and-metalloid-ions
#4
Hugo F Escobar-Sepúlveda, Libia I Trejo-Téllez, Paulino Pérez-Rodríguez, Juan V Hidalgo-Contreras, Fernando C Gómez-Merino
Diacylglycerol kinases (DGKs) are pivotal signaling enzymes that phosphorylate diacylglycerol (DAG) to yield phosphatidic acid (PA). The biosynthesis of PA from phospholipase D (PLD) and the coupled phospholipase C (PLC)/DGK route is a crucial signaling process in eukaryotic cells. Next to PLD, the PLC/DGK pathway is the second most important generator of PA in response to biotic and abiotic stresses. In eukaryotic cells, DGK, DAG, and PA are implicated in vital processes such as growth, development, and responses to environmental cues...
2017: Frontiers in Plant Science
https://www.readbyqxmd.com/read/28223206/accumulation-of-heavy-metals-in-people-on-a-gluten-free-diet
#5
Stephanie L Raehsler, Rok Seon Choung, Eric V Marietta, Joseph A Murray
BACKGROUND & AIMS: Specific foods such as fish and rice have high concentrations of metals such as arsenic, mercury, lead, cadmium, and cobalt. Many gluten-free diets (GFDs) include these foods, so we evaluated whether a GFD was associated with increased metal bioaccumulation. METHODS: We performed a population-based cross-sectional study using data collected from the National Health and Nutrition Examination Survey (NHANES), from 2009 through 2012, collecting information on the diagnosis of celiac disease and adherence to a GFD...
February 18, 2017: Clinical Gastroenterology and Hepatology
https://www.readbyqxmd.com/read/28222373/phytochelatins-play-key-roles-for-the-difference-in-root-arsenic-accumulation-of-different-triticum-aestivum-cultivars-in-comparison-with-arsenate-uptake-kinetics-and-reduction
#6
Gao Ling Shi, Lai Qing Lou, Dao Jun Li, Zhu Bing Hu, Qing Sheng Cai
In the previous studies, we have found that arsenic (As) accumulation in roots of bread wheat (Triticum aestivum L.) seedlings were significantly different among different wheat cultivars, and As(V) tolerant wheat cultivars have much higher capacities of root As accumulation. However, the reason for the difference remains unclear. Four wheat cultivars with high (MM45 and FM8) or low (QF1 and HM29) levels of arsenic (As) accumulation were selected to investigate the relationship between root As(V) uptake kinetics and root As accumulation...
February 4, 2017: Chemosphere
https://www.readbyqxmd.com/read/28222184/ecological-and-human-health-risks-associated-with-abandoned-gold-mine-tailings-contaminated-soil
#7
Veronica Mpode Ngole-Jeme, Peter Fantke
Gold mining is a major source of metal and metalloid emissions into the environment. Studies were carried out in Krugersdorp, South Africa, to evaluate the ecological and human health risks associated with exposure to metals and metalloids in mine tailings contaminated soils. Concentrations of arsenic (As), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), lead (Pb), manganese (Mn), nickel (Ni), and zinc (Zn) in soil samples from the area varied with the highest contamination factors (expressed as ratio of metal or metalloid concentration in the tailings contaminated soil to that of the control site) observed for As (3...
2017: PloS One
https://www.readbyqxmd.com/read/28219238/public-health-risk-of-arsenic-species-in-chicken-tissues-from-live-poultry-markets-of-guangdong-province-china
#8
Yuanan Hu, Wenfeng Zhang, Hefa Cheng, Shu Tao
Arsenic-based feed additives, such as roxarsone (ROX), are still legally and widely used in food animal production in many countries. This study was conducted to systematically characterize the content and speciation of arsenic in chicken tissues from live poultry markets and in commercial chicken feeds in Guangdong, a major poultry production and consumption province in China, and to assess the corresponding public health risk. The total arsenic contents in the commercial feeds could be modeled as a mixture of two log-normal distributions (geometric means: 0...
February 21, 2017: Environmental Science & Technology
https://www.readbyqxmd.com/read/28218785/inhibition-of-shh-pathway-mechanisms-by-arsenic-trioxide-in-pediatric-medulloblastomas-a-comprehensive-literature-review
#9
P H S Klinger, A F Andrade, L E A Delsin, R G P Queiroz, C A Scrideli, L G Tone, E T Valera
Recent innovations in the genomic understanding of medulloblastomas have provided new ways to explore this highly invasive malignant brain cancer arising from the cerebellum. Among the four different medulloblastoma subgroups described to date, the sonic hedgehog (SHH) genetic pathway is the pathway activated in the tumorigenesis of medulloblastoma. SHH-related medulloblastomas are usually of nodular/desmoplastic histology and frequently occur in children under the age of three, an age group highly susceptible to the acute and long-term effects of treatment...
February 16, 2017: Genetics and Molecular Research: GMR
https://www.readbyqxmd.com/read/28218039/demethylation-and-alterations-in-the-expression-level-of-the-cell-cycle-related-genes-as-possible-mechanisms-in-arsenic-trioxide-induced-cell-cycle-arrest-in-human-breast-cancer-cells
#10
Farima Moghaddaskho, Haniyeh Eyvani, Mohsen Ghadami, Javad Tavakkoly-Bazzaz, Kamran Alimoghaddam, Ardeshir Ghavamzadeh, Seyed H Ghaffari
Arsenic trioxide (As2O3) has been used clinically as an anti-tumor agent. Its mechanisms are mostly considered to be the induction of apoptosis and cell cycle arrest. However, the detailed molecular mechanisms of its anti-cancer action through cell cycle arrest are poorly known. Furthermore, As2O3 has been shown to be a potential DNA methylation inhibitor, inducing DNA hypomethylation. We hypothesize that As2O3 may affect the expression of cell cycle regulatory genes by interfering with DNA methylation patterns...
February 2017: Tumour Biology: the Journal of the International Society for Oncodevelopmental Biology and Medicine
https://www.readbyqxmd.com/read/28217148/profiling-metals-in-cordyceps-sinensis-by-using-inductively-coupled-plasma-mass-spectrometry
#11
Xin Wei, Hankun Hu, Baogeng Zheng, Zikri Arslan, Hung-Chung Huang, Weidong Mao, Yi-Ming Liu
Cordyceps sinensis (C. sinensis) is a natural product that has diverse nutritional and medicinal values. Since the availability of natural C. sinensis becomes limited its authentication and quality control is of high significance. Herein we report on profiling of metals in C. sinensis by using inductively coupled plasma mass spectrometry (ICP-MS). The analysis reveals that C. sinensis contains a wide array of essential elements, including P, Mg, Zn, Cu, Fe, etc. Toxic metals detected are Cd, Pb, and As. In all five samples analyzed Pb contents are below 2...
January 28, 2017: Analytical Methods: Advancing Methods and Applications
https://www.readbyqxmd.com/read/28216593/biomethylation-and-volatilization-of-arsenic-by-model-protozoan-tetrahymena-pyriformis-under-different-phosphate-regimes
#12
Xixiang Yin, Lihong Wang, Zhanchao Zhang, Guolan Fan, Jianjun Liu, Kaizhen Sun, Guo-Xin Sun
Tetrahymena pyriformis, a freshwater protozoan, is common in aquatic systems. Arsenic detoxification through biotransformation by T. pyriformis is important but poorly understood. Arsenic metabolic pathways (including cellular accumulation, effluxion, biomethylation, and volatilization) of T. pyriformis were investigated at various phosphate concentrations. The total intracellular As concentration increased markedly as the external phosphate concentration decreased. The highest concentration was 168.8 mg·kg(-1) dry weight, after exposure to As(V) for 20 h...
February 14, 2017: International Journal of Environmental Research and Public Health
https://www.readbyqxmd.com/read/28216136/arsenic-speciation-in-the-lower-athabasca-river-watershed-a-geochemical-investigation-of-the-dissolved-and-particulate-phases
#13
Mark W Donner, Muhammad Babar Javed, William Shotyk, Kevin A Francesconi, Tariq Siddique
Human and ecosystem health concerns for arsenic (As) in the lower Athabasca River downstream of Athabasca Bituminous Sands (ABS) mining (Alberta, Canada) prompted an investigation to determine its forms in surface and groundwater upstream and downstream of industry. Dissolved As species, together with total and particulate As, were used to evaluate the potential bioavailability of As in water as well as to decipher inputs from natural geological processes and ABS mining and upgrading activities. Water samples were collected from the river in October at 13 locations in 2014 and 19 locations in 2015, spanning up to 125 km...
February 17, 2017: Environmental Pollution
https://www.readbyqxmd.com/read/28216132/arsenic-v-bioconcentration-kinetics-in-freshwater-macroinvertebrates-and-periphyton-is-influenced-by-ph
#14
Adeline R Lopez, David H Funk, David B Buchwalter
Arsenic is an important environmental pollutant whose speciation and mobility in freshwater food webs is complex. Few studies have characterized uptake and efflux rates of arsenic in aquatic benthic invertebrates. Further, we lack a fundamental understanding of how pH influences uptake kinetics in these organisms or how this key environmental variable could alter dietary exposure for primary consumers. Here we used a radiotracer approach to characterize arsenate accumulation dynamics in benthic invertebrates, the influence of pH on uptake in a subset of these organisms, and the influence of pH on uptake of arsenate by periphyton - an important food source at the base of aquatic food webs...
February 16, 2017: Environmental Pollution
https://www.readbyqxmd.com/read/28216031/extreme-air-pollution-with-contaminants-originating-from-the-mining-metallurgical-processes
#15
Snezana M Serbula, Jelena S Milosavljevic, Ana A Radojevic, Jelena V Kalinovic, Tanja S Kalinovic
Levels of SO2 and metals/metalloids in the air near a copper smelter in Bor (Serbia) from 2009 to 2015 were presented in this study. Annual levels of SO2 were constantly above the proposed limit value (LV), at almost all the measuring sites. SO2 concentrations on an annual level measured in different zones in Bor were several times higher compared to the LV in 2011, 2012, 2014 and 2015. Enormously high daily SO2 concentrations measured at the suburban zone (3734μgm(-3)) was 187 times higher than the LV given by the World Health Organization...
February 15, 2017: Science of the Total Environment
https://www.readbyqxmd.com/read/28215805/private-well-groundwater-quality-in-west-virginia-usa-2010
#16
R K Law, M W Murphy, E Choudhary
The Centers for Disease Control and Prevention (CDC), in collaboration with the West Virginia Bureau of Public Health (BPH), initiated an investigation to characterize private well water quality in West Virginia. The objective was to better characterize private well water across various aquifer geologies by testing household drinking water samples and comparing them to EPA's National Primary Drinking Water Standards. The BPH selected ten counties representing three regions to capture geologically diverse areas that represent varying aquifer geology...
February 16, 2017: Science of the Total Environment
https://www.readbyqxmd.com/read/28215088/mechanistic-modeling-of-genetic-circuits-for-arsr-arsenic-regulation
#17
Yves Berset, Davide Merulla, Aurélie Joublin, Vassily Hatzimanikatis, Jan Roelof van der Meer
Bioreporters are living cells that generate an easily measurable signal in the presence of a chemical compound. They acquire their functionality from synthetic gene circuits, whose configuration defines the response signal and signal-to-noise ratio. Bioreporters based on the Escherichia coli ArsR system have raised significant interest for quantifying arsenic pollution, but they need to be carefully optimized to accurately work in the required low concentration range (1-10 µg arsenite L-1). In order to better understand the general functioning of ArsR-based genetic circuits, we developed a comprehensive mechanistic model that was empirically tested and validated in E...
February 19, 2017: ACS Synthetic Biology
https://www.readbyqxmd.com/read/28214191/potential-of-different-am-fungi-native-from-as-contaminated-and-uncontaminated-soils-for-supporting-leucaena-leucocephala-growth-in-as-contaminated-soil
#18
Jerusa Schneider, Jochen Bundschuh, Wesley de Melo Rangel, Luiz Roberto Guimarães Guilherme
Arbuscular mycorrhizal (AM) fungi inoculation is considered a potential biotechnological tool for an eco-friendly remediation of hazardous contaminants. However, the mechanisms explaining how AM fungi attenuate the phytotoxicity of metal(oid)s, in particular arsenic (As), are still not fully understood. The influence of As on plant growth and the antioxidant system was studied in Leucaena leucocephala plants inoculated with different isolates of AM fungi and exposed to increasing concentrations of As (0, 35, and 75 mg dm(-3)) in a Typic Quartzipsamment soil...
February 14, 2017: Environmental Pollution
https://www.readbyqxmd.com/read/28213721/effect-of-chemical-amendments-on-remediation-of-potentially-toxic-trace-elements-ptes-and-soil-quality-improvement-in-paddy-fields
#19
Sung Chul Kim, Young Kyu Hong, Se Jin Oh, Seung Min Oh, Sang Phil Lee, Do Hyung Kim, Jae E Yang
Remediation of potentially toxic trace elements (PTEs) in paddy fields is fundamental for crop safety. In situ application of chemical amendments has been widely adapted because of its cost-effectiveness and environmental safety. The main purpose of this research was to (1) evaluate the reduction in dissolved concentrations of cadmium (Cd) and arsenic (As) with the application of chemical amendments and (2) monitor microbial activity in the soil to determine the remediation efficiency. Three different chemical amendments, lime stone, steel slag, and acid mine drainage sludge, were applied to paddy fields, and rice (Oryza sativa L...
February 17, 2017: Environmental Geochemistry and Health
https://www.readbyqxmd.com/read/28213223/electrochemical-determination-of-arsenic-in-natural-waters-using-carbon-fiber-ultra-microelectrodes-modified-with-gold-nanoparticles
#20
Patricio Carrera, Patricio J Espinoza-Montero, Lenys Fernández, Hugo Romero, José Alvarado
We have developed an anodic stripping voltammetry method that employs carbon fiber ultra-microelectrodes modified with gold nanoparticles to determine arsenic in natural waters. Gold nanoparticles were potentiostatically deposited on carbon fiber ultra-microelectrodes at -0.90V (vs SCE) for a time of 15s, to form the carbon fiber ultra-microelectrodes modified with gold nanoparticles. Cyclic voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy coupled to an X-ray microanalysis system were used to check and confirm the presence of gold nanoparticles on the carbon fiber ultra-microelectrodes...
May 1, 2017: Talanta
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