keyword
https://read.qxmd.com/read/38635959/gas-phase-preparation-of-the-14%C3%AF-h%C3%A3-ckel-polycyclic-aromatic-anthracene-and-phenanthrene-isomers-c14h10-via-the-propargyl-addition-benzannulation-paba-mechanism
#1
JOURNAL ARTICLE
ChangYang Wang, Long Zhao, Ralf I Kaiser
Polycyclic aromatic hydrocarbons (PAHs) imply the missing link between resonantly stabilized free radicals and carbonaceous nanoparticles, commonly referred to as soot particles in combustion systems and interstellar grains in deep space. Whereas gas phase formation pathways to the simplest PAH - naphthalene (C10H8) - are beginning to emerge, reaction pathways leading to the synthesis of the 14π Hückel aromatic PAHs anthracene and phenanthrene (C14H10) are still incomplete. Here, by utilizing a chemical microreactor in conjunction with vacuum ultraviolet (VUV) photoionization (PI) of the products followed by detection of the ions in a reflectron time-of-flight mass spectrometer (ReTOF-MS), the reaction between the 1'- and 2'-methylnaphthyl radicals (C11H9•) with the propargyl radical (C3H3•) accesses anthracene (C14H10) and phenanthrene (C14H10) via the Propargyl Addition-BenzAnnulation (PABA) mechanism in conjunction with a hydrogen assisted isomerization...
April 18, 2024: Chemphyschem: a European Journal of Chemical Physics and Physical Chemistry
https://read.qxmd.com/read/38635905/brazilian-psychiatric-association-consensus-on-the-physical-structure-and-ideal-team-for-psychiatric-emergencies-services
#2
JOURNAL ARTICLE
Leonardo Baldaçara, Flávia Ismael, Daniel Kawakami, Gislene Alves da Rocha, Elie Leal de Barros Calfat, Deisy Mendes Porto, Beatriz Ferroli Cavalcante, Beatriz Plotegher Zaramella, Flávio Veloso Ribeiro, Roberto Mendes Dos Santos, Roberta Rossi Grudtner, Teng Chei Tung, Antônio Geraldo da Silva
INTRODUCTION: An integral part of Brazil's public health system, the psychiatric emergency service (PES) has been instrumental in improving qualified support for crisis situations of mental disorders, equitable, universally accessible, and humanized. The purpose of this article is to present a systematic review and consensus about the physical area and facilities, and ideal team qualified for psychiatric emergencies services on both Brazilian settings. METHODS: The authors conducted a literature search using electronic databases such as MEDLINE (PubMed), Scielo, the Cochrane Database, and documents from the WHO, the Brazilian Ministry of Health, and others deemed relevant by experts...
April 18, 2024: Revista Brasileira de Psiquiatria
https://read.qxmd.com/read/38635733/validity-of-self-reported-weight-and-height-among-female-young-adults-in-the-united-arab-emirates
#3
JOURNAL ARTICLE
Dalia Haroun, Aseel Ehsanallah
Self-reported weight and height serve as important metrics in estimating overweight and obesity prevalence within epidemiological studies, primarily due to their cost and time efficiency. However, the accuracy and reliability of these self-reported measures remain controversial, with conflicting reports emerging from different regions. This study aims to compare self-reported weight and height with measured values among young female adults in the United Arab Emirates. A cross-sectional study of 131 female university students aged 17-27 reported their weight and height on a self-administered questionnaire and on the same day had their height and weight measured...
2024: PloS One
https://read.qxmd.com/read/38635716/reversal-of-quantized-hall-drifts-at-noninteracting-and-interacting-topological-boundaries
#4
JOURNAL ARTICLE
Zijie Zhu, Marius Gächter, Anne-Sophie Walter, Konrad Viebahn, Tilman Esslinger
The transport properties of gapless edge modes at boundaries between topologically distinct domains are of fundamental and technological importance. We experimentally studied long-distance quantized Hall drifts in a harmonically confined topological pump of ultracold fermionic atoms. We found that quantized drifts halt and reverse their direction when the atoms reach a critical slope of the confining potential, revealing the presence of a topological boundary. The drift reversal corresponded to a band transfer between a band with Chern number C = +1 and another with C = -1 through a gapless edge mode, in agreement with the bulk-edge correspondence for noninteracting particles...
April 19, 2024: Science
https://read.qxmd.com/read/38635687/therapeutic-education-of-patients-with-coronary-heart-disease-impact-of-digital-platform-monitoring-in-preventing-major-cardiovascular-events-in-tunisia-study-protocol
#5
JOURNAL ARTICLE
Hela Ghali, Aymen El Hraiech, Hend Ben Souda, Majdi Karray, Bruno Pavy, Chekib Zedini
BACKGROUND: Faced with the increase in the number of chronic diseases with the aging of the population, and with the observation of the insufficiency of therapeutic control, a new need has emerged, that of having a patient as a partner in care. METHODS: This study is a randomized controlled trial. Patients with coronary heart disease will be recruited from one clinical site and randomly assigned into two groups: the intervention group and the control group. All participants will be followed up for a total of one year (with three-time points for data collection)...
2024: PloS One
https://read.qxmd.com/read/38635614/bacterial-and-fungal-secondary-infections-occurring-in-covid-19-patients-followed-in-intensive-care-a-retrospective-study
#6
JOURNAL ARTICLE
Erhan Ozyurt, Aylin Erman Daloglu, Kerem Inanoglu, Nilgun Kavrut Ozturk, Sadik Ozmen
INTRODUCTION: We aimed to investigate the effects of secondary bacterial and fungal infections on patient outcomes in patients followed up in the intensive care unit (ICU) due to coronavirus disease 2019 (COVID-19). METHODOLOGY: We retrospectively analyzed reverse transcriptase polymerase chain reaction (RT-PCR) positive COVID-19 patients followed in the ICU of our hospital between March 2020 and June 2021, using the hospital information system. Demographic data, pathogens causing a secondary infection, onset time of secondary infection, and patient outcomes were recorded...
March 31, 2024: Journal of Infection in Developing Countries
https://read.qxmd.com/read/38635609/allergic-bronchopulmonary-mycosis-due-to-schizophyllum-commune-in-a-patient-with-chronic-hepatitis-b
#7
JOURNAL ARTICLE
Rui Xu, Jianfeng Zhang, Jiangnan Zheng, Qiaozhen Wu
INTRODUCTION: Schizophyllum commune (S. commune) is an opportunistic pathogenic fungus and can cause infection of the respiratory system in immunocompromised hosts. Allergic bronchopulmonary mycosis (ABPM) is the major disease caused by S. commune. However, identification of S. commune using routine mycological diagnostic methods is difficult. It is easy to make mistakes in diagnosis and treatment, resulting in deterioration of the disease. We report the first case of ABPM due to S. commune in a Chinese patient with chronic hepatitis B...
March 31, 2024: Journal of Infection in Developing Countries
https://read.qxmd.com/read/38635605/prevalence-and-characterization-of-carbapenem-resistant-enterobacterales-among-inpatients-and-outpatients-in-skikda-algeria
#8
JOURNAL ARTICLE
Amina Bougouizi, Zohra Chekroud, Hamza Rahab, Ali Boumegoura, Abdelaziz Touati
INTRODUCTION: The spread of Carbapenemase-producing Enterobacterales (CPEs) has become a significant concern in Algeria, with limited data available on their presence in community settings. This research investigated the resistance mechanisms of carbapenem-resistant Enterobacterales (CREs) collected from hospitals and the community in Skikda city, Algeria, between December 2020 and June 2022. METHODOLOGY: The study collected Enterobacterales strains resistant to ertapenem from inpatient and outpatient populations...
March 31, 2024: Journal of Infection in Developing Countries
https://read.qxmd.com/read/38635594/does-the-priority-of-ambulance-guarantee-no-delay-a-mipsstw-model-of-emergency-vehicle-routing-optimization-considering-complex-traffic-conditions-for-highway-incidents
#9
JOURNAL ARTICLE
Siliang Luan, Zhongtai Jiang
Globally, traffic accidents on the highway network contribute significantly to a high fatality rate, drawing considerable attention from health institutions. The efficiency of transportation plays a vital role in mitigating the severe consequences of these incidents. This study delves into the issues of emergency vehicles experiencing delays despite having priority. Therefore, we construct mixed-integer linear programming with semi-soft time windows (MIPSSTW) model for optimizing emergency vehicle routing in highway incidents...
2024: PloS One
https://read.qxmd.com/read/38635541/evaluation-of-logistics-management-information-system-and-availability-of-non-program-tracer-drugs-in-public-health-facilities-in-bahir-dar-city-northwest-ethiopia
#10
JOURNAL ARTICLE
Biset Asrade Mekonnen, Minichile Chanie Worku, Bereket Bahiru Tefera
The logistics management information system (LMIS) plays a crucial role in effective record-keeping and reporting, ensuring efficient management of stock status and consumption data. A proficient LMIS improves accountability and supports informed logistic decisions in healthcare. Conversely, a subpar LMIS negatively affects essential medicine availability, compromising overall healthcare service efficiency. This study aimed to evaluate the status of the logistics management information system and the availability of non-program tracer drugs (NPTDs) in public health facilities within Bahir Dar City...
2024: PloS One
https://read.qxmd.com/read/38635489/correlation-analysis-between-echinocytosis-stages-and-blood-viscosity-during-oxygenator-perfusion-an-in-vitro-study
#11
JOURNAL ARTICLE
Shigeyuki Okahara, Satoshi Miyamoto, Zu Soh, Masaru Yoshino, Hidenobu Takahashi, Hideshi Itoh, Toshio Tsuji
The study aimed to investigate the effect of red blood cell (RBC) morphology on oxygenator perfusion, focusing on stages of echinocytosis and their correlation with blood viscosity. A test circuit with an oxygenator and human RBC mixtures was used to induce changes in RBC shape by increasing sodium salicylate concentrations (0, 10, 20, 30, 60, and 120 mmol/L), while hematocrit, blood temperature, and anticoagulation were maintained. Blood viscosity was measured using a continuous blood viscosity monitoring system based on pressure-flow characteristics...
April 18, 2024: ASAIO Journal: a Peer-reviewed Journal of the American Society for Artificial Internal Organs
https://read.qxmd.com/read/38635484/heat-related-emergency-department-visits-united-states-may-september-2023
#12
JOURNAL ARTICLE
Ambarish Vaidyanathan, Abigail Gates, Claudia Brown, Emily Prezzato, Aaron Bernstein
Unprecedented heat waves can affect all persons, but some are more sensitive to the effects of heat, including children and adults with underlying health conditions, pregnant women, and outdoor workers. Many regions of the United States experienced record-breaking high temperatures in 2023, with populations exposed to extremely high temperatures for prolonged periods. CDC examined emergency department (ED) visits associated with heat-related illness (HRI) from the National Syndromic Surveillance Program and compared daily HRI ED visit rates during the warm-season months (May-September) of 2023 with those during 2018-2022...
April 18, 2024: MMWR. Morbidity and Mortality Weekly Report
https://read.qxmd.com/read/38635332/aliovalent-substitution-tunes-physical-properties-in-a-conductive-bis-dithiolene-two-dimensional-metal-organic-framework
#13
JOURNAL ARTICLE
Lei Wang, Andrea Daru, Bhavnesh Jangid, Jie-Hao Chen, Ningxin Jiang, Shrayesh N Patel, Laura Gagliardi, John S Anderson
Two-dimensional conductive metal-organic frameworks have emerged as promising electronic materials for applications in (opto)electronic, thermoelectric, magnetic, electrocatalytic, and energy storage devices. Many bottom-up or postsynthetic protocols have been developed to isolate these materials or further modulate their electronic properties. However, some methodologies commonly used in classic semiconductors, notably, aliovalent substitution, are conspicuously absent. Here, we demonstrate how aliovalent Fe(III) to Ni(II) substitution enables the isolation of a Ni bis(dithiolene) material from a previously reported Fe analogue...
April 18, 2024: Journal of the American Chemical Society
https://read.qxmd.com/read/38635318/academic-detailing-as-a-health-information-technology-implementation-method-supporting-the-design-and-implementation-of-an-emergency-department-based-clinical-decision-support-tool-to-prevent-future-falls
#14
JOURNAL ARTICLE
Hanna J Barton, Apoorva Maru, Margaret A Leaf, Daniel J Hekman, Douglas A Wiegmann, Manish N Shah, Brian W Patterson
BACKGROUND: Clinical decision support (CDS) tools that incorporate machine learning-derived content have the potential to transform clinical care by augmenting clinicians' expertise. To realize this potential, such tools must be designed to fit the dynamic work systems of the clinicians who use them. We propose the use of academic detailing-personal visits to clinicians by an expert in a specific health IT tool-as a method for both ensuring the correct understanding of that tool and its evidence base and identifying factors influencing the tool's implementation...
April 18, 2024: JMIR Human Factors
https://read.qxmd.com/read/38635201/from-alcohol-detoxification-to-treatment-a-qualitative-interview-study-on-perceived-barriers-and-assessed-potential-of-mhealth-among-individuals-postdetoxification
#15
JOURNAL ARTICLE
Danilo Romero, Alexander Rozental, Per Carlbring, Magnus Johansson, Johan Franck, Anne H Berman, Philip Lindner
OBJECTIVE: Most individuals attending detoxification clinics do not pursue subsequent treatment. Earlier research has suggested that emerging technologies like mHealth interventions could address the postdetoxification treatment gap, yet it remains unclear whether patients themselves endorse such approaches. Our study aimed to qualitatively explore perceived treatment barriers and assessed potential of mHealth among individuals who have undergone alcohol detoxification. METHOD: We conducted a single-interview-per-participant qualitative study, sampling participants ( n = 23) that had visited the Stockholm substance use disorder emergency department for alcohol-related reasons, of whom n = 8 were purposively included due to having missed their scheduled follow-up outpatient appointment...
April 18, 2024: Psychology of Addictive Behaviors
https://read.qxmd.com/read/38635166/challenges-and-breakthroughs-in-enhancing-temperature-tolerance-of-sodium-ion-batteries
#16
REVIEW
Chang Che, Feng Wu, Yu Li, Ying Li, Shuqiang Li, Chuan Wu, Ying Bai
Lithium-based batteries (LBBs) are highly researched and recognized as a mature electrochemical energy storage (EES) system in recent years. However, their stability and effectiveness are primarily confined to room temperature conditions. At temperatures significantly below 0 °C or above 60 °C, LBBs experience substantial performance degradation. Under such challenging extreme contexts, sodium-ion batteries (SIBs) emerge as a promising complementary technology, distinguished by their fast dynamics at low temperature region and superior safety under elevated temperatures...
April 18, 2024: Advanced Materials
https://read.qxmd.com/read/38635150/magnetic-resonance-metrics-for-identification-of-cuprizone-induced-demyelination-in-the-mouse-model-of-neurodegeneration-a-review
#17
REVIEW
Emma Friesen, Kamya Hari, Maxina Sheft, Jonathan D Thiessen, Melanie Martin
Neurodegenerative disorders, including Multiple Sclerosis (MS), are heterogenous disorders which affect the myelin sheath of the central nervous system (CNS). Magnetic Resonance Imaging (MRI) provides a non-invasive method for studying, diagnosing, and monitoring disease progression. As an emerging research area, many studies have attempted to connect MR metrics to underlying pathophysiological presentations of heterogenous neurodegeneration. Most commonly, small animal models are used, including Experimental Autoimmune Encephalomyelitis (EAE), Theiler's Murine Encephalomyelitis (TMEV), and toxin models including cuprizone (CPZ), lysolecithin, and ethidium bromide (EtBr)...
April 18, 2024: Magma
https://read.qxmd.com/read/38635141/group-based-trajectory-modeling-of-fluid-balance-in-elderly-patients-with-acute-ischemic-stroke-analysis-from-multicenter-icus
#18
JOURNAL ARTICLE
Jia Tang, Changdong Wu, Zhenguang Zhong
INTRODUCTION: Acute ischemic stroke (AIS) significantly contributes to severe disability and mortality among the elderly. This study aims to explore the association between longitudinal fluid balance (FB) trajectories and clinical outcomes in elderly patients with AIS. Our hypothesis posits the existence of multiple latent trajectories of FB in patients with AIS during the initial 7 days following ICU admission. METHODS: Patients (age ≥ 65 years) with AIS and continuous FB records were identified from two large databases...
April 18, 2024: Neurology and Therapy
https://read.qxmd.com/read/38635028/from-images-to-insights-a-neuroradiologist-s-practical-guide-on-white-matter-fiber-tract-anatomy-and-dti-patterns-for-pre-surgical-planning
#19
JOURNAL ARTICLE
Inês S Freire, Tânia S Lopes, Sónia G Afonso, Daniela J Pereira
INTRODUCTION: Diffusion tensor imaging (DTI) is a valuable non-invasive imaging modality for mapping white matter tracts and assessing microstructural integrity, and can be used as a "biomarker" in diagnosis, differentiation, and therapeutic monitoring. Although it has gained clinical importance as a marker of neuropathology, limitations in its interpretation underscore the need for caution. METHODS: This review provides an overview of the principles and clinical applicability of DTI...
April 18, 2024: Neuroradiology
https://read.qxmd.com/read/38635005/predictors-of-30-day-recurrent-emergency-department-visits-for-hyperglycemia-in-patients-with-types-1-and-2-diabetes-a-population-based-cohort-study
#20
JOURNAL ARTICLE
Justin W Yan, Branka Vujcic, Britney N Le, Kristine Van Aarsen, Tom Chen, Fardowsa Halane, Kristin K Clemens
OBJECTIVES: This study's aims were to describe the outcomes of patients with diabetes presenting with their first ED visit for hyperglycemia, and to identify predictors of recurrent ED visits for hyperglycemia. METHODS: Using linked databases, we conducted a population-based cohort study of adult and pediatric patients with types 1 and 2 diabetes presenting with a first ED visit for hyperglycemia from April 2010 to March 2020 in Ontario, Canada. We determined the proportion of patients with a recurrent ED visit for hyperglycemia within 30 days of the index visit...
April 18, 2024: CJEM
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