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O2-evoluting nanoparticles

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https://www.readbyqxmd.com/read/30082396/stabilized-photoanodes-for-water-oxidation-by-integration-of-organic-dyes-water-oxidation-catalysts-and-electron-transfer-mediators
#1
Degao Wang, Michael S Eberhart, Matthew V Sheridan, Ke Hu, Benjamin D Sherman, Animesh Nayak, Ying Wang, Seth L Marquard, Christopher J Dares, Thomas J Meyer
Stabilized photoanodes for light-driven water oxidation have been prepared on nanoparticle core/shell electrodes with surface-stabilized donor-acceptor chromophores, a water oxidation catalyst, and an electron-transfer mediator. For the electrode, fluorine-doped tin oxide FTO|SnO2 /TiO2 |-Org1-|1.1 nm Al2 O3 |-RuP2+ -WOC (water oxidation catalyst) with Org1 (1-cyano-2-(4-(diphenylamino)phenyl)vinyl)phosphonic acid), the mediator RuP2+ ([Ru(4,4-(PO3 H2 )2 -2,2-bipyridine)(2,2-bipyridine)2 ]2+ ), and the WOC, Ru(bda)(py(CH2 )(3or10) P(O3 H)2 )2 (bda is 2,2-bipyridine-6,6-dicarboxylate with x = 3 or 10), solar excitation resulted in photocurrents of ∼500 µA/cm2 and quantitative O2 evolution at pH 4...
August 6, 2018: Proceedings of the National Academy of Sciences of the United States of America
https://www.readbyqxmd.com/read/29982126/evolving-trends-in-bio-chemical-sensor-fabrication-incorporating-bimetallic-nanoparticles
#2
REVIEW
Riddhipratim Mandal, Anupriya Baranwal, Ananya Srivastava, Pranjal Chandra
Biosensor designing took a giant leap in its path of evolution after its merger with a wing of nanotechnology. Dramatic properties like high surface area to volume ratio, enhanced chemical and optical properties of nanoscale materials have revolutionized sensor technology in terms of their analytical performance. Many metallic nanoparticles (MeNPs) like gold, silver, platinum, palladium nanoparticles, etc. have been tremendously exploited for improving sensor performance. Over the years, there has been slow but steady shift in nanoscience research with an aim to explore composite MeNPs like bimetallic, trimetallic nanoparticles, etc...
June 21, 2018: Biosensors & Bioelectronics
https://www.readbyqxmd.com/read/29790548/role-of-flower-like-ultrathin-co-3-o-4-nanosheets-in-water-splitting-and-non-aqueous-li-o-2-batteries
#3
Haitao Wu, Wang Sun, Junrong Shen, David W Rooney, Zhenhua Wang, Kening Sun
The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are both fundamental and essential processes for various energy conversion and storage systems. The kinetics of ORR and OER play a critical role in their energy efficiency and practicality. Here, flower-like ultrathin Co3O4 nanosheets synthesized through a facile solvothermal technique were studied as a bifunctional catalyst for both water splitting and non-aqueous Li-O2 batteries. Due to the novel structure and highly active {110} and {100} exposed facets, which can effectively facilitate mass transfer and enhance catalytic capability, Co3O4 nanosheets exhibit better stability and higher ORR/OER activity than Co3O4 nanoparticles, Co3O4 bulks, Pt/C, and RuO2 in alkaline solution...
May 31, 2018: Nanoscale
https://www.readbyqxmd.com/read/29577122/co-oxidation-activity-of-pt-zn-and-znpt-nanocatalysts-a-comparative-study-by-in-situ-near-ambient-pressure-x-ray-photoelectron-spectroscopy
#4
Ahmed Naitabdi, Anthony Boucly, François Rochet, Robert Fagiewicz, Giorgia Olivieri, Fabrice Bournel, Rabah Benbalagh, Fausto Sirotti, Jean-Jacques Gallet
The investigation of nanocatalysts under ambient pressure by X-ray photoelectron spectroscopy gives access to a wealth of information on their chemical state under reaction conditions. Considering the paradigmatic CO oxidation reaction, a strong synergistic effect on CO catalytic oxidation was recently observed on a partly dewetted ZnO(0001)/Pt(111) single crystal surface. In order to bridge the material gap, we have examined whether this inverse metal/oxide catalytic effect could be transposed on supported ZnPt nanocatalysts deposited on rutile TiO2(110)...
April 5, 2018: Nanoscale
https://www.readbyqxmd.com/read/29556357/chemiluminescence-imaging-of-duox2-derived-hydrogen-peroxide-for-longitudinal-visualization-of-biological-response-to-viral-infection-in-nasal-mucosa
#5
Hyun Jik Kim, Young Hun Seo, Sujin An, Ara Jo, Ick Chan Kwon, Sehoon Kim
Rationale: Hydrogen peroxide (H2 O2 ) provides an important mechanism for resisting infectious pathogens within the respiratory tract, and accordingly, the in situ analysis of H2 O2 generation in real time provides a valuable tool for assessing immune response. Methods: In this study, we applied a chemiluminescent nanoparticle-based real-time imaging approach to noninvasive evaluation of the Duox2-mediated H2 O2 generation after viral infection, and assessed its usefulness for analytical purposes in mouse nasal mucosa...
2018: Theranostics
https://www.readbyqxmd.com/read/29372212/enhanced-cyclability-of-li-o-2-batteries-with-cathodes-of-ir-and-mno-2-supported-on-well-defined-tin-arrays
#6
Limin Leng, Jing Li, Xiaoyuan Zeng, Xinlong Tian, Huiyu Song, Zhimin Cui, Ting Shu, Haishui Wang, Jianwei Ren, Shijun Liao
The cycling stability of Li-O2 batteries has been impeded by the lack of high-efficiency, and durable oxygen cathodes for the oxygen-reduction reaction (ORR) and the oxygen-evolution reaction (OER). Herein we report a novel TiN nanorod array-based cathode, which was firstly prepared by growing a TiN nanorod array on carbon paper (CP), and then followed by depositing MnO2 ultrathin sheets or Ir nanoparticles on the TiN nanorods to form well-ordered, three-dimensional (3D), and free-standing structured cathodes: TiN@MnO2 /CP and TiN@Ir/CP...
February 8, 2018: Nanoscale
https://www.readbyqxmd.com/read/29220576/oxygenic-hybrid-semiconducting-nanoparticles-for-enhanced-photodynamic-therapy
#7
Houjuan Zhu, Jingchao Li, Xiaoying Qi, Peng Chen, Kanyi Pu
Photodynamic nanotheranostics has shown great promise for cancer therapy; however, its therapeutic efficacy is limited due to the hypoxia of tumor microenvironment and the unfavorable bioavailability of existing photodynamic agents. We herein develop hybrid core-shell semiconducting nanoparticles (SPN-Ms) that can undergo O2 evolution in hypoxic solid tumor to promote photodynamic process. Such oxygenic nanoparticles are synthesized through a one-pot surface growth reaction and have a unique multilayer structure cored and coated with semiconducting polymer nanoparticles (SPNs) and manganese dioxide (MnO2 ) nanosheets, respectively...
January 10, 2018: Nano Letters
https://www.readbyqxmd.com/read/29178291/polyhedral-30-faceted-bivo-4-microcrystals-predominantly-enclosed-by-high-index-planes-promoting-photocatalytic-water-splitting-activity
#8
Ping Li, Xingyu Chen, Huichao He, Xin Zhou, Yong Zhou, Zhigang Zou
Unprecedented 30-faceted BiVO4 polyhedra predominantly surrounded by {132}, {321}, and {121} high-index facets are fabricated through the engineering of high-index surfaces by a trace amount of Au nanoparticles. The growth of high-index facets results in a 3-5 fold enhancement of O2 evolution from photocatalytic water splitting by the BiVO4 polyhedron, relative to its low-index counterparts. Theory calculations reveal that water dissociation is more energetically favorable on the high-index surfaces than on the low-index (010), (110), and (101) surfaces, which is accompanied by a notable reduction in the overpotential (0...
January 2018: Advanced Materials
https://www.readbyqxmd.com/read/28946470/sonochemical-synthesis-of-srmno-3-nanoparticles-as-an-efficient-and-new-catalyst-for-o-2-evolution-from-water-splitting-reaction
#9
Sousan Gholamrezaei, Masoud Salavati-Niasari
The principal focus of this investigation is to prepare the SrMnO3 nanostructures by different chemical methods such as ultrasonic, co-precipitation, microwave, and hydrothermal methods. The influence of calcination temperature, and ultrasound irradiation power, and the presence of surfactant investigated on morphology and size of SrMnO3 nanostructures. As-prepared nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray energy dispersive spectroscopy (EDS) and ultraviolet-visible (UV-Vis) spectroscopy...
January 2018: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28886624/nanobubbles-an-effective-way-to-study-gas-generating-catalysis-on-a-single-nanoparticle
#10
Shuping Li, Ying Du, Ting He, Yangbin Shen, Chuang Bai, Fandi Ning, Xin Hu, Wenhui Wang, Shaobo Xi, Xiaochun Zhou
Gas-generating catalysis is important to many energy-related research fields, such as photocatalytic water splitting, water electrolysis, etc. The technique of single-nanoparticle catalysis is an effective way to search for highly active nanocatalysts and elucidate the reaction mechanism. However, gas-generating catalysis remains difficult to investigate at the single-nanoparticle level because product gases, such as H2 and O2 , are difficult to detect on an individual nanoparticle. Here, we successfully find that nanobubbles can be used to study the gas-generating catalysis, i...
October 11, 2017: Journal of the American Chemical Society
https://www.readbyqxmd.com/read/28849642/plasma-assisted-synthesis-of-self-supporting-porous-conps-c-nanosheet-as-efficient-and-stable-bifunctional-electrocatalysts-for-overall-water-splitting
#11
Qiuyan Jin, Bowen Ren, Dongqi Li, Hao Cui, Chengxin Wang
The utilization of a highly active and robust bifunctional catalyst for simultaneously producing H2 and O2 is still a major challenging issue, which is vital for improving the efficiency of overall water splitting. Herein, we employ a novel plasma-assisted strategy to rapidly and conveniently synthesize the three-dimensional (3D) porous composite nanosheets assembled on monodispersed Co nanoparticles encapsulated in a carbon framework (CoNPs@C) on a carbon cloth. Such a novel 3D hierarchical porous nanosheet improves the exposure and accessibility of active sites as well as ensures high electroconductibility...
September 20, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28842692/fe-based-hybrid-electrocatalysts-for-nonaqueous-lithium-oxygen-batteries
#12
Seun Lee, Gwang-Hee Lee, Hack Jun Lee, Mushtaq Ahmad Dar, Dong-Wan Kim
Lithium-oxygen batteries promise high energy densities, but are confronted with challenges, such as high overpotentials and sudden death during discharge-charge cycling, because the oxygen electrode is covered with the insulating discharge product, Li2O2. Here, we synthesized low-cost Fe-based nanocomposites via an electrical wire pulse process, as a hybrid electrocatalyst for the oxygen electrode of Li-O2 batteries. Fe3O4-Fe nanohybrids-containing electrodes exhibited a high discharge capacity (13,890 mA h gc(-1) at a current density of 500 mA gc(-1)), long cycle stability (100 cycles at a current rate of 500 mA gc(-1) and fixed capacity regime of 1,000 mA h gc(-1)), and low overpotential (1...
August 25, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28745829/nickel-diselenide-ultrathin-nanowires-decorated-with-amorphous-nickel-oxide-nanoparticles-for-enhanced-water-splitting-electrocatalysis
#13
Haoyi Li, Shuangming Chen, Haifeng Lin, Xiaobin Xu, Haozhou Yang, Li Song, Xun Wang
Well-designed hybrid materials based on noble metal-free elements have great potential to generate hydrogen (H2 ) and oxygen (O2 ) sustainably via overall water splitting for developing practical energy-related technologies. Herein, an accessible method is presented to synthesize nickel diselenide (NiSe2 ) ultrathin nanowires decorated with amorphous nickel oxide nanoparticles (NiOx NPs) as multifunctional electrocatalysts (NSWANs) for hydrogen and oxygen evolution reaction (HER and OER). The NSWANs exhibit quite low HER and OER overpotentials of 174 and 295 mV, respectively, holding the current density of 20 mA cm(-2) for 24 h continuous operations in alkaline media...
July 26, 2017: Small
https://www.readbyqxmd.com/read/28553490/visible-light-induced-water-splitting-in-an-aqueous-suspension-of-a-plasmonic-au-tio2-photocatalyst-with-metal-co-catalysts
#14
A Tanaka, K Teramura, S Hosokawa, H Kominami, T Tanaka
We found that plasmonic Au particles on titanium(iv) oxide (TiO2) act as a visible-light-driven photocatalyst for overall water splitting free from any additives. This is the first report showing that surface plasmon resonance (SPR) in a suspension system effectively induces overall water splitting. Modification with various types of metal nanoparticles as co-catalysts enhanced the evolution of H2 and O2. Among these, Ni-modified Au/TiO2 exhibited 5-times higher rates of H2 and O2 evolution than those of Ni-free Au/TiO2...
April 1, 2017: Chemical Science
https://www.readbyqxmd.com/read/28509548/u-iv-aqueous-speciation-from-the-monomer-to-uo-2-nanoparticles-two-levels-of-control-from-zwitterionic-glycine-ligands
#15
Clément Falaise, Harrison A Neal, May Nyman
The fate of U(IV)O2 in the environment in a colloidal form and its dissolution and growth in controlled environments is influenced by organic ligation and redox processes, where both affect solubility, speciation, and transport. Here we investigate U(IV) aqueous speciation from pH 0 to 3 with the glycine (Gly) ligand, the smallest amino acid. We document evolution of the monomeric to the hexameric form from pH 0 to 3 via UV-vis spectroscopy and small-angle X-ray scattering (SAXS). Crystals of the hexamer [U6 O4 (OH)4 (H2 O)6 (HGly)12 ]·12Cl- ·12(H2 O) (U6 ) were isolated at pH 2...
June 5, 2017: Inorganic Chemistry
https://www.readbyqxmd.com/read/28482113/carbon-free-o2-cathode-with-three-dimensional-ultralight-nickel-foam-supported-ruthenium-electrocatalysts-for-li-o2-batteries
#16
Ziqiang Liu, Ningning Feng, Zihan Shen, Fujun Li, Ping He, Huigang Zhang, Haoshen Zhou
A new carbon- and binder-free O2 cathode was fabricated by electroplating Ru-nanoparticle-coated ultralight Ni foam, which has good electron-conducting and electrocatalytic properties. This all-metal monolithic structure was able to suppress CO2 evolution and provided 306 times higher capacity than commercial Ni foam-based O2 cathodes.
July 10, 2017: ChemSusChem
https://www.readbyqxmd.com/read/28374445/a-dendritic-nanostructured-copper-oxide-electrocatalyst-for-the-oxygen-evolution-reaction
#17
Tran Ngoc Huan, Gwenaëlle Rousse, Sandrine Zanna, Ivan T Lucas, Xiangzhen Xu, Nicolas Menguy, Victor Mougel, Marc Fontecave
To use water as the source of electrons for proton or CO2 reduction within electrocatalytic devices, catalysts are required for facilitating the proton-coupled multi-electron oxygen evolution reaction (OER, 2 H2 O→O2 +4 H(+) +4 e(-) ). These catalysts, ideally based on cheap and earth abundant metals, have to display high activity at low overpotential and good stability and selectivity. While numerous examples of Co, Mn, and Ni catalysts were recently reported for water oxidation, only few examples were reported using copper, despite promising efficiencies...
April 4, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/27980967/a-carbon-and-binder-free-nanostructured-cathode-for-high-performance-nonaqueous-li-o-2-battery
#18
Yueqi Chang, Shanmu Dong, Yuhang Ju, Dongdong Xiao, Xinhong Zhou, Lixue Zhang, Xiao Chen, Chaoqun Shang, Lin Gu, Zhangquan Peng, Guanglei Cui
Operation of the nonaqueous Li-O2 battery critically relies on the reversible oxygen reduction/evolution reactions in the porous cathode. Carbon and polymeric binder, widely used for the construction of Li-O2 cathode, have recently been shown to decompose in the O2 environment and thus cannot sustain the desired battery reactions. Identifying stable cathode materials is thus a major current challenge that has motivated extensive search for noncarbonaceous alternatives. Here, RuO x /titanium nitride nanotube arrays (RuO x /TiN NTA) containing neither carbon nor binder are used as the cathode for nonaqueous Li-O2 batteries...
August 2015: Advanced Science (Weinheim, Baden-Wurttemberg, Germany)
https://www.readbyqxmd.com/read/27899004/influence-of-binders-and-solvents-on-stability-of-ru-ruo-x-nanoparticles-on-ito-nanocrystals-as-li-o-2-battery-cathodes
#19
Svetoslava Vankova, Carlotta Francia, Julia Amici, Juqin Zeng, Silvia Bodoardo, Nerino Penazzi, Gillian Collins, Hugh Geaney, Colm O'Dwyer
Fundamental research on Li-O2 batteries remains critical, and the nature of the reactions and stability are paramount for realising the promise of the Li-O2 system. We report that indium tin oxide (ITO) nanocrystals with supported 1-2 nm oxygen evolution reaction (OER) catalyst Ru/RuOx nanoparticles (NPs) demonstrate efficient OER processes, reduce the recharge overpotential of the cell significantly and maintain catalytic activity to promote a consistent cycling discharge potential in Li-O2 cells even when the ITO support nanocrystals deteriorate from the very first cycle...
February 8, 2017: ChemSusChem
https://www.readbyqxmd.com/read/27883155/in-situ-integration-of-cofe-alloy-nanoparticles-with-nitrogen-doped-carbon-nanotubes-as-advanced-bifunctional-cathode-catalysts-for-zn-air-batteries
#20
Pingwei Cai, Yuan Hong, Suqin Ci, Zhenhai Wen
Electrochemical catalysis of O2 -incorporated reactions is a promising strategy for metal-air batteries. The performance of metal-air batteries is determined by the catalytic activities of the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Therefore, developing efficient catalysts with superior activities for the ORR and OER is of great significance to expand the application range of metal-air batteries. Herein, CoFe alloy nanoparticles adhered to the inside wall of nitrogen doped carbon nanotubes (CoFe@NCNTs) are synthesized and can function as a Janus particle to efficiently catalyze the ORR and OER with desirable activities in 0...
December 8, 2016: Nanoscale
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