self-healing dental composite

OBJECTIVES: Previous efforts led to the development of two different polymeric biomaterials for periodontal regeneration with antibacterial photodynamic surface activity. The present study aimed to investigate osseointegration and bone formation of both materials in an ovine model. METHODS: Both biomaterials: 1) urethane dimethacrylate-based Biomaterial 1 (BioM1) and 2) tri-armed oligoester-urethane methacrylate-based Biomaterial 2 (BioM2) are enriched with beta-tri-calcium phosphate and the photosensitizer meso-tetra(hydroxyphenyl)chlorin (mTHPC)...

OBJECTIVE: Novel self-healing resin-based composites containing microcapsules have been developed to improve the mechanical performance of dental restorations. However, the long-term fatigue behaviour of these self-healing composites has still been hardly investigated. Therefore, this manuscript studied the fatigue behaviour of self-healing composites containing microcapsules by subjecting the specimens to traditional staircase tests and ageing in a custom-designed chewing simulator (Rub&Roll) to simulate oral ageing physiologically relevant conditions...

Studies on self-healing capsules embedded in cement composites to heal such cracks have recently been actively researched in order to improve the dimensional stability of concrete structures. In particular, capsule studies were mainly conducted to separately inject reactive healing solutions into different capsules. However, with this method, there is an important limitation in that the probability of self-healing is greatly reduced because the two healing solutions must meet and react. Therefore, we propose three-dimensional (3D) printer-based self-healing capsules with a membrane structure that allows two healing solutions to be injected into one capsule...

Microcapsules of urea-formaldehyde (UF) containing dicyclopentadiene (DCPD) were synthesized by the in situ polymerization technique for self-healing of epoxy. The dispersion of microcapsules in the epoxy matrix was achieved using ultrasonication. Composites of epoxy, having 0.5, 1.0, 1.5, and 2.0 wt.% of microcapsules capable of self-healing, were prepared. The shape and size of the microcapsules were determined by field emission electron microscopy. Spherical capsules of DCPD, with an average diameter of 172 nm, were obtained...

The preparation and application of microcapsules containing healing agents have become a crucial way to enhance the self-healing capability of bitumen. This intelligent material has become a hot topic in the field of pavement material and has greatly stimulated the development and applications of pavement engineering. However, there has been no research focused on the relationship of the multistructures from the viewpoint of molecular-size, microsize, and macrosize, which significantly limits the predictions of the self-healing efficiency and structure design of this self-healing material...

Crystalline admixture (CA) can be incorporated into concrete to achieve self-healing of concrete cracks. In this study, both CA and superabsorbent polymer (SAP) were used as self-healing agents to investigate the effects of CA on the self-healing performance and mechanical properties of mortar with internally added SAP at different self-healing ages. The healing effect of cracks in mortar is assessed by crack observation and impermeability. The structure and composition of the filler in the cracks were analyzed by microscopic experiment...

Polymer topology, which plays a principal role in the rheology of polymeric fluids, and non-equilibrium materials, which exhibit time-varying rheological properties, are topics of intense investigation. Here, we push composites of circular DNA and dextran out-of-equilibrium via enzymatic digestion of DNA rings to linear fragments. Our time-resolved rheology measurements reveal discrete state-switching, with composites undergoing abrupt transitions between dissipative and elastic-like states. The gating time and lifetime of the elastic-like states, and the magnitude and sharpness of the transitions, are surprisingly decorrelated from digestion rates and non-monotonically depend on the DNA fraction...

Caries is considered to be the most prevalent non-communicable disease in humans, mainly deriving from acidogenic bacterial biofilm and resulting in the demineralization and decomposition of hard dental tissue. Herein, a composite responsive foam brace loaded with magnesium organic framework (MPC) is designed for caries prevention and tooth remineralization. MPC can intelligently release organic antibacterial molecules (gallic acid) and mineralized ions (Mg2+ , Ca2+ and PO4 3- ) under acidic conditions (pH < 5...

Polymer nanocomposites, which combine the advantages of polymers and fillers, are widely used in the field of automobile and aviation. Polyimine (PI) is an emerging thermoset material with remarkable properties, such as malleability, recyclability, and self-healing. Silicon carbide nano-whiskers (SiCw), as a cheap and high-hardness filler material, are chosen to enhance the properties of polyimine matrix. Silicon carbide nano-whisker-reinforced polyimine (PI-SiCw) nanocomposites were successfully fabricated by heat pressing, which was confirmed by FTIR and XPS tests...

In recent years, extensive research has been conducted on the development of high-performance flexible tactile sensors, pursuing the next generation of highly intelligent electronics with diverse potential applications in self-powered wearable sensors, human-machine interactions, electronic skin, and soft robotics. Among the most promising materials that have emerged in this context are functional polymer composites (FPCs), which exhibit exceptional mechanical and electrical properties, enabling them to be excellent candidates for tactile sensors...

Self-healing ceramic composites are promising smart materials for high-temperature applications. Experimental and numerical studies have been performed to more fully understand their behaviors, and kinetic parameters such as the activation energy and frequency factor have been reported to be indispensable for investigating healing phenomena. This article proposes a method of determining the kinetic parameters of self-healing ceramic composites using the oxidation kinetics model of strength recovery. These parameters are determined by an optimization method using experimental strength recovery data under various healing temperatures, times, and microstructural features on the fractured surfaces...

The objective of this review is to investigate the potential of functionalized magnetic polymer composites for use in electromagnetic micro-electro-mechanical systems (MEMS) for biomedical applications. The properties that make magnetic polymer composites particularly interesting for application in the biomedical field are their biocompatibility, their adjustable mechanical, chemical, and magnetic properties, as well as their manufacturing versatility, e.g., by 3D printing or by integration in cleanroom microfabrication processes, which makes them accessible for large-scale production to reach the general public...

Starting from the context of the principles of Sustainable Development and Circular Economy concepts, the paper presents a synthesis of research in the field of the development of materials of interest, such as cementitious composites or alkali-activated geopolymers. Based on the reviewed literature, the influence of compositional or technological factors on the physical-mechanical performance, self-healing capacity and biocidal capacity obtained was analyzed. The inclusion of TiO2 nanoparticles in the matrix increase the performances of cementitious composites, producing a self-cleaning capacity and an anti-microbial biocidal mechanism...

Electronic tattoos have great potential application in the biomedical field; moreover, the substrate-free electronic tattoo offers better comfortability and conformal contact. However, the substrate-free electronic tattoo is more prone to malfunction, including fall off and fracture. In this paper, a self-healing and self-adhesive substate-free tattoo based on PEDOT: PSS is studied and reported. The dry composite electrode will turn into self-healing material while it transforms into hydrogel, and a cut with a width up to 24 μm could be healed in 1 s...

In a "smart" corrosion-protective coating system, both the active anti-corrosion and the early corrosion detection of underlying metals are highly required. It is practical significant to develop materials that possess self-detecting of the early local corrosion and self-healing of coating defects simultaneously. The organic compound 8-hydroxyquinoline (8HQ) is an effective inhibitor and a fluorescent sensor probe for corrosion of aluminum alloy. Therefore, a layer double hydroxide (LDH) nanocontainer film loaded with the 8HQ was developed for the active corrosion protection purpose of aluminum alloy AA2024...

This paper aims to study the application feasibility of steel slag powder (SSP) in replacing limestone powder (LP) to enhance the heat release and self-healing properties of asphalt and an asphalt mixture. First, the microwave-heating characteristics of SSP and LP asphalt mortar were analyzed, and the differences in the microstructure and chemical composition between SSP and LP were compared. Secondly, through the DSR frequency sweep test, the optimal healing temperature of the two asphalt mortars was determined...

SMAF-ECC material composed of shape memory alloy fiber (SMAF) and engineered cementitious composite (ECC) has good bending and tensile properties, as well as good crack self-healing ability, energy consumption, and self-centering ability. The bond behavior between fiber and matrix is crucial to the effective utilization of the superelasticity of SMAF. The experimental study considered three variables: SMA fiber diameter, fiber end shape, and bond length. The pullout stress-strain curve of SMAF was obtained, and the maximum pullout stress, maximum bond stress, and fiber utilization rate were analyzed...

Soft self-healing materials are compelling candidates for stretchable devices because of their excellent compliance, extensibility, and self-restorability. However, most existing soft self-healing polymers suffer from crack propagation and irreversible fatigue failure due to easy breakage of their dynamic amorphous low-energy polymer networks. Herein, inspired by distinct structure-property relationship of biological tissues, we propose a supramolecular interfacial assembly strategy of preparing soft self-healing composites with unprecedented crack propagation resistance by structurally engineering preferentially-aligned lamellar structures within dynamic and super-stretchable poly(urea-ureathane) matrixes (which can be elongated to 24750× its original length)...

Recently, silsesquioxanes (SSQ) and polyhedral oligomeric silsesquioxanes (POSS) have gained much interest in the area of biomaterials, mainly due to their intrinsic properties such as biocompatibility, complete non-toxicity, the ability to self-assemble and to form a porous structure, facilitating cell proliferation, creating a superhydrophobic surface, osteoinductivity, and ability to bind hydroxyapatite. All the above has resulted in new developments in medicine. However, the application of POSS-containing materials in dentistry is still at initial stage and deserves a systematic description to ensure future development...

The introduction of the hydrogen economy, despite its obvious technological problems, creates a need for a significant number of niche-focused solutions, such as small-sized (10-100 W) fuel cells able to run on hydrogen of lesser purity than what is considered a standard in the case of PEMFCs. One of the solutions can be derived from the fact that an increase in the operational temperature of a cell significantly decreases its susceptibility to catalyst poisoning. Electrolytes suitable for the so-called medium temperature operational range of 120-400 °C, hence developed, are neither commercialized nor standardized...