self-healing dental composite

Background and objectives Direct pulp capping (dPC) is a therapeutic process that involves the application of a protective chemical to an exposed pulp with the intent to facilitate the restoration and preservation of its vitality and function. Despite numerous proposed solutions, researchers have yet to find a dependable, non-absorbable bioactive pulp capping substance that constantly activates cellular healing processes, consequently preserving pulpal vitality over an extended period of time. The objective of this study was to assess and contrast the efficacy of a novel tricalcium silicate cement and calcium hydroxide in preserving the long-term health of the dental pulp following dPC using clinical and radiographic observations...

This study utilizes desalted and denitrated treated aluminum dross (TAD) as a raw material, along with kaolin and 10 ppi (pores per inch) polyurethane foam as a template. The slurry is converted into an aluminum dross green body with a three-dimensional network structure using the impregnation method. A three-dimensional network aluminum dross ceramic framework (TAD3D ) is created at a sintering temperature of 1350 °C. The liquid 5A05 aluminum alloy at a temperature of 950 °C infiltrates into the voids of TAD3D through pressureless infiltration, resulting in TAD3D /5A05Al composite material with an interpenetrating phase composite (IPC) structure...

The aim of this study was to improve the self-healing properties of dental nanocomposite using nanoparticles of TiO2 and chitosan. We evaluated flexural and compressive strength, crack-healing, and self-healing lifespan after 3 months of water aging. The effect of the developed composite on cell viability and toxicity was assessed by an MTT assay on human alveolar basal epithelial cells (A549 cell line). The nanocomposite included 7.5 wt% polyurea-formaldehyde (PUF) and 0, 0.5, and 1 wt% n-TiO2 and chitosan...

Eutectic gallium-indium liquid metal (EGaIn-LM), with a considerable capacity and unique self-healing properties derived from its intrinsic liquid nature, has gained tremendous attention for lithium-ion batteries (LIBs) anode applications. However, the fluidity of the LM could trigger continuous consumption of the electrolyte, and its liquid-solid transition during the lithiation/de-lithiation process may result in the rupture of the solid electrolyte interface (SEI). Herein, we employed LM as an initiator to in-situ assemble the 3D hydrogel framework for dynamic encapsulating itself, the LM nanoparticles could be homogeneously confined into the hydrogel-derived carbon framework (HDC) after calcination...

Two-dimensional (2D) nanomaterials, with extraordinary physical and chemical characteristics, have long been regarded as a promising nanofiller in organic coatings for marine corrosion protection. The past decade has witnessed the high-speed progress of 2D nanomaterials reinforced organic composite coatings, and plenty of breakthroughs have been achieved as yet. This review covers an in-depth and all-around outline of the up-to-date advances in 2D nanomaterials modified organic coatings employed for marine corrosion protection realm...

Dental enamel is a mineralized extracellular matrix, and enamel defect is a common oral disease. However, the self-repair capacity of enamel is limited due to the absence of cellular components and organic matter. Efficacy of biomimetic enamel mineralization using calcium phosphate ion clusters (CPICs), is an effective method to compensate for the limited self-healing ability of fully developed enamel. Preparing and stabilizing CPICs presents a significant challenge, as the addition of certain stabilizers can diminish the mechanical properties or biosafety of mineralized enamel...

This study presents a transparent and ion-conductive hydrogel with suppressed water loss. The hydrogel comprises agarose polymer doped with sucrose and sodium chloride salt (NaCl-Suc/A hydrogel). Sucrose increases the water retention of the agarose gel, and the Na and Cl ions dissolved in the gel provide ionic conductivity. The NaCl-Suc/A gel shows high retention capability and maintains a 45% water uptake after 4 h of drying at 60 °C without encapsulation at the optimum gel composition. The doped NaCl-Suc/A hydrogel demonstrates improved mechanical properties and ionic conductivity of 1...

AIM: The purpose of this study was to i) synthesise TEGDMA-DHEPT microcapsules in a laboratory setting; ii) characterise the resultant microcapsules for quality measures. MATERIALS & METHODS: Microcapsules were prepared by in situ polymerization of PUF shells. Microcapsules characterisation include size analysis, optical and SEM microscopy to measure the diameter and analyse the morphology of PUF microcapsules. FT-IR spectrometer evaluated microcapsules and benzyl peroxide catalyst polymerization independently...

OBJECTIVES: This study investigated the impact of using γ-methacryloxypropyl trimethoxy silane (MPS) for surface silanization of poly (urea-formaldehyde) (PUF) microcapsules which enclose a healing liquid of "triethylene glycol dimethacrylate (TEGDMA) and N,N dihydroxyethyl-p-toluidine (DHEPT)" on some mechanical properties of an experimental dental composite as well as its self-healing efficiency. METHODS: Synthesis of PUF microcapsules was done via in situ polymerization, followed by silanization with MPS silane...

In this study, conversion coatings were produced on the AM50 magnesium alloy by a plasma electrolytic oxidation (PEO) process in alkaline-silicate electrolyte with the addition of potassium hexafluorophosphate, using a unipolar pulse power source. The coating microstructure and its composition were determined using scanning electron microscopy (SEM) and an X-ray photoelectron spectroscopy (XPS). The corrosion resistance of the conversion coatings was evaluated by means of potentiodynamic polarization tests (PDP) and electrochemical impedance spectroscopy (EIS) in a dilute Harrison solution (DHS)...

The objective of this study was to formulate dip coatings, incorporating casein, NaOH, and nanocrystalline hydroxyapatite (nanoHAp), with self-healing properties for application on ZnMg3.2 wt.% alloy in the field of biomedical applications. This study hypothesizes that the self-healing mechanism within the layer will impede substrate degradation by progressively filling defects where chlorides from simulated body fluids intervene. Furthermore, it aims to mitigate potential damage effects during the implantation process by the layer's self-healing capabilities...

Numerous aspects of dentistry have been transformed by smart materials. In recent years, there have been advancements in dental materials that exhibit improved biological compatibility. These materials are specifically designed to interact effectively with the fluids found in the oral cavity, including saliva and gingival crevicular fluids. The search for the optimum restorative material results in the development of a more recent generation of dental materials known as smart materials. Smart materials react to stimuli, including stress, temperature, moisture, pH, electric field, and magnetic field, in a regulated way...

According to definition and general agreement, smart materials have properties that can be altered in a controlled fashion by stimuli including stress, temperature, moisture, pH, and electric or magnetic fields. Various recent materials in materials science are in working order, meaning they must achieve their tasks and should go through intentional modification. Smart materials change one or more of their characteristics in response to inputs. They can be called as responsive materials. As these materials have been available for so long, they are used for a wide range of purposes...

The paper presents issues regarding self-healing isophorone diisocyanate (IPDI) microcapsules applied in fiber metal laminates (FMLs) based on magnesium AZ31 and a carbon-reinforced polymer composite. The aim of this work is to analyze the morphology of the produced PU/PUa microcapsules containing IPDI and their behavior in a self-healing layer in FMLs. By means of SEM, it was confirmed that the microcapsules (MCs) had a narrow size distribution. Therefore, the developed MCs, having sizes ranging from 10 to 35 µm, might contribute to an improved self-healing coating, which benefits from the advantages of both small and larger-sized MCs...

In order to study the self-healing performance of macroscopic fractures of asphalt mixtures, semicircular bending (SCB) tests were used to test 90# base asphalt mixtures, SBS (Styrene-Butadiene-Styrene) modified asphalt mixtures, and SBS + CR (Chloroprene Rubber) composite modified asphalt mixtures. The F-H-F (the asphalt mixture specimen was fatigued for a certain number of times, then healed under certain conditions, and then fatigued until destroyed) test was carried out, and the fatigue life recovery rate of the fatigue test before and after healing was defined as the healing index (HI)...

Learning about the strain/stress distribution in a material is essential to achieving its mechanical stability and proper functionality. Conventional techniques such as universal testing machines only apply to static samples with standardized geometry in laboratory environment. Soft mechanical sensors based on stretchable conductors, carbon-filled composites or conductive gels possess better adaptability, but still face challenges from complicated fabrication process, dependence on extra readout device and limited strain/stress mapping ability...

OBJECTIVE: Dental resin composites have been the most popular materials for repairing tooth decay in recent years. However, secondary caries and bulk fracture are the major hurdles that affect the lifetime of dental resin composites. This current study synthesized a novel antimicrobial and self-healing dental resin containing nanoparticle-modified self-healing microcapsules to combat secondary caries and restoration fracture. METHODS: Multifunctional dental resins containing 0-20% nanoparticle-modified self-healing microcapsules were prepared...

The development of modern building materials science involves the process of designing innovative materials that exhibit unique characteristics, such as energy efficiency, environmental friendliness, self-healing ability, and photocatalytic properties. This can be achieved by modifying cement with nano- and fine-dispersed additives that can give the material new properties. Such additives include a number of compounds based on the TiO2 -Bi2 O3 system. These compounds have photocatalytic activity in the near-UV and visible range of the spectrum, which can serve to create photocatalytic concretes...

This study investigated the effect of sustained loading on the cumulative damage of a newly developed smart cement-based self-healing composite material (SMA-ECC). SMA-ECC is composed of engineered cementitious composite (ECC) and shape memory alloy (SMA) fibers. A uniaxial compressive test with five predefined loading levels (0%, 30%, 40%, 50%, and 60% of compressive strength) was conducted on SMA-ECC hollow-cylindrical specimens and ECC control hollow-cylindrical specimens. The cumulative damage was mainly determined by changes in the total water absorption of different groups of specimens during three different periods (not loaded, at a predefined loading level, and after unloading)...

Dental composites are commonly utilized in dental treatments because they have the ability to preserve the natural appearance of teeth, are minimally invasive and conservative, and enhance the overall physical and mechanical attributes. Dental composites can experience damage, like small cracks, due to factors like temperature changes and physical strain, which can reduce their effectiveness. Detecting these tiny cracks in dental composites can be quite challenging, and in certain situations, it may even be impossible...