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Chlorine Dioxide

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https://www.readbyqxmd.com/read/28806070/high-levels-of-daytime-molecular-chlorine-and-nitryl-chloride-at-a-rural-site-on-the-north-china-plain
#1
Xiaoxi Liu, Hang Qu, Lewis Gregory Huey, Yuhang Wang, Steven Sjostedt, Limin Zeng, Keding Lu, Yusheng Wu, Min Hu, Min Shao, Tong Zhu, Yuanhang Zhang
Molecular chlorine (Cl2) and nitryl chloride (ClNO2) concentrations were measured using chemical ionization mass spectrometry at a rural site over the North China Plain during June 2014. High levels of daytime Cl2 up to ~450 pptv were observed. The average diurnal Cl2 mixing ratios showed a maximum around noon at ~100 pptv. ClNO2 exhibited a strong diurnal variation with early morning maxima reaching ppbv levels and afternoon minima sustained above 60 pptv. A moderate correlation (R(2)=0.31) between Cl2 and sulfur dioxide was observed, perhaps indicating a role for power plant emissions in the generation of the observed chlorine...
August 14, 2017: Environmental Science & Technology
https://www.readbyqxmd.com/read/28774629/characterization-of-halogenated-dbps-and-identification-of-new-dbps-trihalomethanols-in-chlorine-dioxide-treated-drinking-water-with-multiple-extractions
#2
Jiarui Han, Xiangru Zhang, Jiaqi Liu, Xiaohu Zhu, Tingting Gong
Chlorine dioxide (ClO2) is a widely used alternative disinfectant due to its high biocidal efficiency and low-level formation of trihalomethanes and haloacetic acids. A major portion of total organic halogen (TOX), a collective parameter for all halogenated DBPs, formed in ClO2-treated drinking water is still unknown. A commonly used pretreatment method for analyzing halogenated DBPs in drinking water is one-time liquid-liquid extraction (LLE), which may lead to a substantial loss of DBPs prior to analysis...
August 2017: Journal of Environmental Sciences (China)
https://www.readbyqxmd.com/read/28774604/impact-of-combining-chlorine-dioxide-and-chlorine-on-dbp-formation-in-simulated-indoor-swimming-pools
#3
Daekyun Kim, Nuray Ates, Sehnaz Sule Kaplan Bekaroglu, Meric Selbes, Tanju Karanfil
The main objective of this study was to assess the combined use of chlorine dioxide (ClO2) and chlorine (Cl2) on the speciation and kinetics of disinfection by-product (DBP) formation in swimming pools using synthetic pool waters prepared with a body fluid analog (BFA) and/or fresh natural water. At 1:25 (mass ratio) of ClO2 to Cl2, there was no significant reduction in the formation of trihalomethanes (THMs) and haloacetic acids (HAAs) for both BFA solution and natural water compared to the application of Cl2 alone...
August 2017: Journal of Environmental Sciences (China)
https://www.readbyqxmd.com/read/28704664/a-primary-estimation-of-pcdd-fs-release-reduction-from-non-wood-pulp-and-paper-industry-in-china-based-on-the-investigation-of-pulp-bleaching-with-chlorine-converting-to-chlorine-dioxide
#4
Qingcong Xiao, Xiaoqian Song, Wenchao Li, Yuanna Zhang, Hongchen Wang
Chlorine bleaching technology (C process, CEH process, H process and theirs combination), which was identified as a primary formation source of PCDD/Fs, is still widely used by the vast majority of Chinese non-wood pulp and paper mills (non-wood PMs). The purpose of this study was to provide information and data support for further eliminating dioxin for non-wood PMs in China, and especially to evaluate the PCDD/Fs release reduction for those mills converting their pulp bleaching processes from CEH to ECF. The PCDD/Fs concentrations of the bleached pulp and bleaching wastewater with ECF bleaching were in the ranges of 0...
June 29, 2017: Chemosphere
https://www.readbyqxmd.com/read/28666531/the-influence-of-ocean-halogen-and-sulfur-emissions-in-the-air-quality-of-a-coastal-megacity-the-case-of-los-angeles
#5
Maria Muñiz-Unamunzaga, Rafael Borge, Golam Sarwar, Brett Gantt, David de la Paz, Carlos A Cuevas, Alfonso Saiz-Lopez
The oceans are the main source of natural halogen and sulfur compounds, which have a significant influence on the oxidizing capacity of the marine atmosphere; however, their impact on the air quality of coastal cities is currently unknown. We explore the effect of marine halogens (Cl, Br and I) and dimethyl sulfide (DMS) on the air quality of a large coastal city through a set of high-resolution (4-km) air quality simulations for the urban area of Los Angeles, US, using the Community Multiscale Air Quality (CMAQ model)...
June 27, 2017: Science of the Total Environment
https://www.readbyqxmd.com/read/28659553/microbial-fouling-in-a-water-treatment-plant-and-its-control-using-biocides
#6
T S Rao, Rajesh Kumar, P Balamurugan, G K Vithal
 Water treatment plants (WTP) are vital in the food, pharmaceutical and chemical process industries. This investigation describes the dense microbial fouling by microbes and organic compounds in a WTP of a heavy water producing industrial unit. On-site observations showed severe algal and bacterial growth in the various units of the WTP which are open to the atmosphere and very dense fungal fouling in the closed vacuum degasser unit. Digital and microscopic images showed that the microbial fouling problem was primarily due to a fungus...
2017: Biocontrol Science
https://www.readbyqxmd.com/read/28658907/effect-of-5-chlorine-dioxide-irrigant-on-micro-push-out-bond-strength-of-resin-sealer-to-radicular-dentin-an-in-vitro-study
#7
Rejitha R Kamalasanan, Swapna V Devarasanahalli, Ranjini M Aswathanarayana, K Rashmi, Yashwanth Gowda, Roopa R Nadig
INTRODUCTION: Chlorine dioxide (ClO2) has been recently investigated as a possible root canal irrigant due to its broad spectrum of antimicrobial action, tissue dissolution and smear layer removal properties. Literature is scarce on the effect of chlorine dioxide irrigation on the resin sealer dentin bond strength. AIM: To compare 5% chlorine dioxide (ClO2) with or without Ethylene Diamine Tetra Acetic acid (EDTA) with 3% Sodium hypochlorite (NaOCl) and EDTA combination as endodontic irrigants on the adhesion of AH Plus sealer to radicular dentin using micro- Push out Bond Strength (µPBS) test...
May 2017: Journal of Clinical and Diagnostic Research: JCDR
https://www.readbyqxmd.com/read/28642746/virucidal-activity-of-fogged-chlorine-dioxide-and-hydrogen-peroxide-based-disinfectants-against-human-norovirus-and-its-surrogate-feline-calicivirus-on-hard-to-reach-surfaces
#8
Naim Montazeri, Clyde Manuel, Eric Moorman, Janak R Khatiwada, Leonard L Williams, Lee-Ann Jaykus
Human norovirus (NoV) is the leading cause of foodborne illnesses in the United States. Norovirus is shed in high numbers in the feces and vomitous of infected individuals. Contact surfaces contaminated with bodily fluids harboring infectious virus particles serve as vehicles for pathogen transmission. Environmental stability of NoV and its resistance to many conventional disinfectants necessitate effective inactivation strategies to control the spread of virus. We investigated the efficacy of two commercial disinfectants, hydrogen peroxide (7...
2017: Frontiers in Microbiology
https://www.readbyqxmd.com/read/28631818/inactivation-of-bacillus-cereus-spores-on-red-chili-peppers-using-a-combined-treatment-of-aqueous-chlorine-dioxide-and-hot-air-drying
#9
Songyi Kim, Huyong Lee, Jee-Hoon Ryu, Hoikyung Kim
The effect of a combined treatment using aqueous chlorine dioxide (ClO2 ) and hot-air drying to inactivate Bacillus cereus spores on red chili peppers was evaluated. Ten washed and dried pepper samples, each comprising half of a single pepper (Capsicum annuum L.), were inoculated with B. cereus spore suspension. The inoculated samples were washed with sodium hypochlorite (NaOCl; 50, 100, or 200 μg/mL) or ClO2 (50, 100, or 200 μg/mL) solution for 1 min and then air-dried (25 ± 1 °C, 47 ± 1% relative humidity), which was followed by drying with hot air at 55 °C for up to 48 h...
June 20, 2017: Journal of Food Science
https://www.readbyqxmd.com/read/28622629/bacterial-community-dynamics-in-a-cooling-tower-with-emphasis-on-pathogenic-bacteria-and-legionella-species-using-universal-and-genus-specific-deep-sequencing
#10
Rui P A Pereira, Jörg Peplies, Manfred G Höfle, Ingrid Brettar
Cooling towers are the major source of outbreaks of legionellosis in Europe and worldwide. These outbreaks are mostly associated with Legionella species, primarily L. pneumophila, and its surveillance in cooling tower environments is of high relevance to public health. In this study, a combined NGS-based approach was used to study the whole bacterial community, specific waterborne and water-based bacterial pathogens, especially Legionella species, targeting the 16S rRNA gene. This approach was applied to water from a cooling tower obtained by monthly sampling during two years...
June 6, 2017: Water Research
https://www.readbyqxmd.com/read/28609731/degradation-of-sulfamethoxazole-using-ozone-and-chlorine-dioxide-compound-specific-stable-isotope-analysis-transformation-product-analysis-and-mechanistic-aspects
#11
Sarah Willach, Holger V Lutze, Kevin Eckey, Katja Löppenberg, Michelle Lüling, Jens Terhalle, Jens-Benjamin Wolbert, Maik A Jochmann, Uwe Karst, Torsten C Schmidt
The sulfonamide antibiotic sulfamethoxazole (SMX) is a widely detected micropollutant in surface and groundwaters. Oxidative treatment with e.g. ozone or chlorine dioxide is regularly applied for disinfection purposes at the same time exhibiting a high potential for removal of micropollutants. Especially for nitrogen containing compounds such as SMX, the related reaction mechanisms are largely unknown. In this study, we systematically investigated reaction stoichiometry, product formation and reaction mechanisms in reactions of SMX with ozone and chlorine dioxide...
June 3, 2017: Water Research
https://www.readbyqxmd.com/read/28601522/comparative-toxicological-effects-of-two-antifouling-biocides-on-the-marine-diatom-chaetoceros-lorenzianus-damage-and-post-exposure-recovery
#12
Pooja Chavan, Rajesh Kumar, Ramalingam Kirubagaran, Vayalam P Venugopalan
Antifouling biocides are commonly used in coastal electric power stations to prevent biofouling in their condenser cooling systems. However, the environmental impact of the chemical biocides is less understood than the thermal stress effects caused by the condenser effluents. In this study, Chaetoceros lorenzianus, a representative marine diatom, was used to analyse the toxicity of two antifouling biocides, chlorine and chlorine dioxide. The diatom cells were subjected to a range of concentrations of the biocides (from 0...
June 8, 2017: Ecotoxicology and Environmental Safety
https://www.readbyqxmd.com/read/28582734/characterization-of-titanium-dioxide-nanoparticle-removal-in-simulated-drinking-water-treatment-processes
#13
Hui-Hsien Chang, Tsun-Jen Cheng, Chin-Pao Huang, Gen-Shuh Wang
This study characterized the fate of nano-TiO2 in both powder (TiO2(P)) and suspension (TiO2(S)) forms in simulated drinking water treatments. Nano-TiO2 solutions of 0.1, 1.0, and 10mg/L were prepared with deionized water and raw waters from the Changxing and Fengshan Water Treatment Plants in Taiwan to assess the effects of water matrices on nano-TiO2 behavior during water treatment. After the laboratory simulated water treatment, including pre-chlorination, coagulation, sedimentation, filtration and post-chlorination, the residual Ti concentration ranged from 2...
December 1, 2017: Science of the Total Environment
https://www.readbyqxmd.com/read/28577109/phosgene-induced-acute-lung-injury-ali-differences-from-chlorine-induced-ali-and-attempts-to-translate-toxicology-to-clinical-medicine
#14
REVIEW
Wenli Li, Juergen Pauluhn
BACKGROUND: Phosgene (carbonyl dichloride) gas is an indispensable chemical inter-mediate used in numerous industrial processes. There is no clear consensus as to its time- and inhaled-dose-dependent etiopathologies and associated preventive or therapeutic treatment strategies. METHODS: Cardiopulmonary function was examined in rats exposed by inhalation to the alveolar irritant phosgene or to the airway irritant chlorine during and following exposure. Terminal measurements focused on hematology, protein extravasation in bronchoalveolar lavage (BAL), and increased lung weight...
December 2017: Clinical and Translational Medicine
https://www.readbyqxmd.com/read/28541794/natural-organic-matter-characterization-by-hpsec-and-its-contribution-to-trihalomethane-formation-in-athens-water-supply-network
#15
Stelios A Samios, Spyros K Golfinopoulos, Przemyslaw Andrzejewski, Joanna Świetlik
Samples from the two main watersheds that provide Athens Water Supply and Sewerage Company (AWSSC) with raw water were examined for Dissolved Organic Carbon (DOC) and for their molecular weight distribution (MWD). In addition, water samples from water treatment plants (WTPs) and from the water supply network were examined for trihalomethane (THMs) levels. The main purpose of this study was to reveal the molecular composition of natural organic matter (NOM) and identify the individual differences between NOM from the two main Athens watersheds...
May 25, 2017: Journal of Environmental Science and Health. Part A, Toxic/hazardous Substances & Environmental Engineering
https://www.readbyqxmd.com/read/28508082/a-chlorine-free-protocol-for-processing-germanium
#16
Martin Glavinović, Michael Krause, Linju Yang, John A McLeod, Lijia Liu, Kim M Baines, Tomislav Friščić, Jean-Philip Lumb
Replacing molecular chlorine and hydrochloric acid with less energy- and risk-intensive reagents would markedly improve the environmental impact of metal manufacturing at a time when demand for metals is rapidly increasing. We describe a recyclable quinone/catechol redox platform that provides an innovative replacement for elemental chlorine and hydrochloric acid in the conversion of either germanium metal or germanium dioxide to a germanium tetrachloride substitute. Germanium is classified as a "critical" element based on its high dispersion in the environment, growing demand, and lack of suitable substitutes...
May 2017: Science Advances
https://www.readbyqxmd.com/read/28448049/controlled-release-of-chlorine-dioxide-in-a-perforated-packaging-system-to-extend-the-storage-life-and-improve-the-safety-of-grape-tomatoes
#17
Xiuxiu Sun, Elizabeth Baldwin, Anne Plotto, Jan Narciso, Christopher Ference, Mark Ritenour, Ken Harrison, Joseph Gangemi, Jinhe Bai
A controlled-release chlorine dioxide (ClO2) pouch was developed by sealing a slurry form of ClO2 into semipermeable polymer film; the release properties of the pouch were monitored in containers with or without fruit. The pouch was affixed to the inside of a perforated clamshell containing grape tomatoes, and the effect on microbial population, firmness, and weight loss was evaluated during a 14 day storage period at 20 °C. Within 3 days, the ClO2 concentration in the clamshells reached 3.5 ppm and remained constant until day 10...
April 7, 2017: Journal of Visualized Experiments: JoVE
https://www.readbyqxmd.com/read/28445648/electron-radiolysis-of-ammonium-perchlorate-a-reflectron-time-of-flight-mass-spectrometric-study
#18
Sándor Góbi, Alexandre Bergantini, Andrew M Turner, Ralf I Kaiser
Thin films of ammonium perchlorate (NH4ClO4) were exposed to energetic electrons at 5.5 K to explore the radiolytic decomposition mechanisms. The effects of radiolysis were monitored on line and in situ via Fourier transform infrared spectroscopy (FTIR) in the condensed phase along with electron impact ionization quadrupole mass spectrometry (EI-QMS) and single-photon photoionization reflectron time-of-flight mass spectrometry (PI-ReTOF-MS) during the temperature-programmed desorption (TPD) phase to probe the subliming molecules...
May 12, 2017: Journal of Physical Chemistry. A
https://www.readbyqxmd.com/read/28441005/plasma-activated-copper-nanocube-catalysts-for-efficient-carbon-dioxide-electroreduction-to-hydrocarbons-and-alcohols
#19
Dunfeng Gao, Ioannis Zegkinoglou, Nuria J Divins, Fabian Scholten, Ilya Sinev, Philipp Grosse, Beatriz Roldan Cuenya
Carbon dioxide electroreduction to chemicals and fuels powered by renewable energy sources is considered a promising path to address climate change and energy storage needs. We have developed highly active and selective copper (Cu) nanocube catalysts with tunable Cu(100) facet and oxygen/chlorine ion content by low-pressure plasma pretreatments. These catalysts display lower overpotentials and higher ethylene, ethanol, and n-propanol selectivity, resulting in a maximum Faradaic efficiency (FE) of ∼73% for C2 and C3 products...
May 1, 2017: ACS Nano
https://www.readbyqxmd.com/read/28418706/radiation-driven-formation-of-reactive-oxygen-species-in-oxychlorine-containing-mars-surface-analogues
#20
Christos D Georgiou, Dimitrios Zisimopoulos, Electra Kalaitzopoulou, Richard C Quinn
The present study demonstrates that γ-radiolyzed perchlorate-containing Mars soil salt analogues (in a CO2 atmosphere) generate upon H2O wetting the reactive oxygen species (ROS) superoxide radical (O2(•-)), hydrogen peroxide (H2O2), and hydroxyl radicals ((•)OH). This study also validates that analogue radiolysis forms oxychlorine species that, in turn, can UV-photolyze to (•)OH upon UV photolysis. This investigation was made possible by the development of a new assay for inorganic-origin O2(•-) and H2O2 determination and by the modification of a previous assay for soil (•)OH...
April 2017: Astrobiology
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