Ya-Qian Zhang, Lin Liu, Wen-Ze Li, Bo-Han Wu, Chen-Ning Li, Jia-Qi Chu, Zheng-Bo Han
Herein, three In(III)-based metal-organic frameworks (In-MOFs) with different degrees of interpenetration (DOI), namely In-MOF-1, In-MOF-2, and In-MOF-3, constructed by In3+ and Y-shaped ligands 4,4',4″-s-triazine-2,4,6-triyltribenzoate (H3 TATB), are successfully synthesized through the ionothermal/solvothermal method. Subsequently, three novel In-MOFs, including noninterpenetration polycatenation, 2-fold interpenetrated, and 4-fold interpenetrated structure, are employed as the platform for systematically investigating the separation efficiency of CO2 /N2 , CO2 /CH4 , and CO2 /CH4 /N2 mixture gas system...
April 15, 2024: Inorganic Chemistry