Pei-Yu Liao, Jia-Xin Li, Jia-Chuan Liu, Qi Xiong, Ze-Yu Ruan, Tao Li, Wei Deng, Shang-Da Jiang, Jian-Hua Jia, Ming-Liang Tong
Photogenerated radicals are an indispensable member of the state-of-the-art photochromic material family, as they can effectively modulate the photoluminescence and photothermal conversion performance of radical-induced photochromic complexes. Herein, two novel radical-induced photochromic metal‒organic frameworks (MOFs), [Ag(TEPE)](AC)⋅7/4H2O⋅5/4EtOH (1) and [Ag(TEPE)](NC)⋅3H2O⋅EtOH (2), are reported. Distinctly different topological networks can be obtained by judiciously introducing alternative π-conjugated anionic guests, including a new topological structure (named as sfm) first reported in this work, describing as 4,4,4,4-c net...
March 26, 2024: Angewandte Chemie