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https://www.readbyqxmd.com/read/29223036/study-on-temperature-and-near-infrared-driving-characteristics-of-hydrogel-actuator-fabricated-via-molding-and-3d-printing
#1
Qian Zhao, Yunhong Liang, Lei Ren, Feng Qiu, Zhihui Zhang, Luquan Ren
A hydrogel material system which was fit for molding and 3D printing was developed to fabricate bilayer hydrogel actuators with controllable temperature and near infrared laser responses. Polymerization on interface boundary of layered structure enhanced the bonding strength of hydrogel actuators. By utilizing anisotropic of microstructure along with thickness direction, bilayer hydrogel actuators fabricated via molding realized intelligent bending/shrinking responses, which guided the preparation of hydrogel ink for 3D printing...
December 2, 2017: Journal of the Mechanical Behavior of Biomedical Materials
https://www.readbyqxmd.com/read/29221419/ionic-solvation-and-solvent-solvent-interaction-effects-on-the-charge-and-potential-distributions-in-electric-double-layers
#2
R Vangara, F van Swol, D N Petsev
Electric double layers are complex systems that involve a wide variety of interactions between the different components of the electrolyte solutions and with the charged interface. While the role of all Coulombic types of interactions is clear, that of the non-Coulombic forces is less obvious. The focus in the present study is on the effect of bulk solvation interactions on the properties of the electric double layer. The analysis is based on classical density functional theory. This approach allows us to account for the correlations between all charged (ionic) and uncharged (solvent) species in the solution...
December 7, 2017: Journal of Chemical Physics
https://www.readbyqxmd.com/read/29221394/mesoscale-simulations-of-confined-nafion-thin-films
#3
P Vanya, J Sharman, J A Elliott
The morphology and transport properties of thin films of the ionomer Nafion, with thicknesses on the order of the bulk cluster size, have been investigated as a model system to explain the anomalous behaviour of catalyst/electrode-polymer interfaces in membrane electrode assemblies. We have employed dissipative particle dynamics (DPD) to investigate the interaction of water and fluorocarbon chains, with carbon and quartz as confining materials, for a wide range of operational water contents and film thicknesses...
December 7, 2017: Journal of Chemical Physics
https://www.readbyqxmd.com/read/29221017/polarization-switchable-and-wavelength-controllable-multi-functional-metasurface-for-focusing-and-surface-plasmon-polariton-wave-excitation
#4
Yonghong Ling, Lirong Huang, Wei Hong, Tongjun Liu, Luan Jing, Wenbin Liu, Ziyong Wang
Realizing versatile functionalities in a single photonic device is crucial for photonic integration. We here propose a polarization-switchable and wavelength-controllable multi-functional metasurface. By changing the polarization state of incident light, its functionality can be switched between the flat focusing lens and exciting surface-plasmon-polariton (SPP) wave. Interestingly, by tuning the wavelength of incident light, the generated SPP waves can also be controlled at desired interfaces, traveling along the upper or lower interface of the metasurface, or along both of them, depending on whether the incident light satisfies the first or second Kerker condition...
November 27, 2017: Optics Express
https://www.readbyqxmd.com/read/29220577/from-solvent-free-to-dilute-electrolytes-essential-components-for-a-continuum-theory
#5
Nir Gavish, Doron Elad, Arik Yochelis
The increasing number of experimental observations on highly concentrated electrolytes and ionic liquids show qualitative features that are distinct from dilute or moderately concentrated electrolytes, such as self-assembly, multiple-time relaxation, and under-screening, which all impact the emergence of fluid/solid interfaces, and transport in these systems. Since these phenomena are not captured by existing mean field models of electrolytes, there is a paramount need for a continuum framework for highly concentrated electrolytes and ionic liquids...
December 8, 2017: Journal of Physical Chemistry Letters
https://www.readbyqxmd.com/read/29220327/self-paced-operation-of-a-wheelchair-based-on-a-hybrid-brain-computer-interface-combining-motor-imagery-and-p300-potential
#6
Yang Yu, Zongtan Zhou, Yadong Liu, Jun Jiang, Erwei Yin, Nannan Zhang, Zhihua Wang, Yaru Liu, Xingjie Wu, Dewen Hu
This paper presents a hybrid brain-computer interface (BCI) that combines motor imagery (MI) and P300 potential for the asynchronous operation of a brain-controlled wheelchair whose design is based on a Mecanum wheel. This paradigm is completely user-centric. By sequentially performing MI tasks or paying attention to P300 flashing, the user can use eleven functions to control the wheelchair: move forward/backward, move left/right, move left45/right45, accelerate/decelerate, turn left/right, and stop. The practicality and effectiveness of the proposed approach were validated in eight subjects, all of whom achieved good performance...
December 2017: IEEE Transactions on Neural Systems and Rehabilitation Engineering
https://www.readbyqxmd.com/read/29220178/equilibrium-between-a-droplet-and-surrounding-vapor-a-discussion-of-finite-size-effects
#7
Andreas Troester, Fabian Schmitz, Peter Virnau, Kurt Binder
In a theoretical description of homogeneous nucleation one frequently assumes an ``equilibrium'' coexistence of a liquid droplet with surrounding vapor of a density exceeding that of a saturated vapor at bulk vapor-liquid two-phase coexistence. Thereby one ignores the caveat that in the thermodynamic limit, for which the vapor would be called supersaturated, such states will at best be metastable with finite lifetime, and thus not be well-defined within equilibrium statistical mechanics. In contrast, in a system of finite volume stable equilibrium coexistence of droplet and supersaturated vapor at constant total density is perfectly possible, and numerical analysis of equilibrium free energies of finite systems allows to obtain physically relevant results...
December 8, 2017: Journal of Physical Chemistry. B
https://www.readbyqxmd.com/read/29220151/integration-of-enzymes-in-polyaniline-sensitized-3d-inverse-opal-tio2-architectures-for-light-driven-biocatalysis-and-light-to-current-conversion
#8
Marc Riedel, Fred Lisdat
Inspired by natural photosynthesis, coupling of artificial light-sensitive entities with biocatalysts in a biohybrid format can result in advanced photobioelectronic systems. Herein, we report on the integration of sulfonated polyanilines (PMSA1) and PQQ glucose dehydrogenase (PQQ-GDH) into inverse opal TiO2 (IO-TiO2) electrodes. While PMSA1 introduces sensitivity for visible light into the biohybrid architecture and ensures the efficient wiring between the IO-TiO2 electrode and the biocatalytic entity, PQQ-GDH provides the catalytic activity for the glucose oxidation and therefore feeds the light-driven reaction with electrons for an enhanced light-to-current conversion...
December 8, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/29218401/using-multimedia-information-and-communication-technology-ict-to-provide-added-value-to-reminiscence-therapy-for-people-with-dementia-lessons-learned-from-three-field-studies
#9
REVIEW
Alexander Bejan, Ramazan Gündogdu, Katherina Butz, Nadine Müller, Christophe Kunze, Peter König
BACKGROUND: In the care of people with dementia (PwD), occupational therapies and activities aiming at maintaining the quality of life of PwD, such as reminiscence therapy (RT), are taking on a more and more important role. Information and communication technology (ICT) has the potential to improve and to facilitate RT by facilitating access to and selection of biographical information and related contents or by providing novel multimodal interaction forms to trigger memories; however, interactive multimedia technology is barely used in practice...
December 7, 2017: Zeitschrift Für Gerontologie und Geriatrie
https://www.readbyqxmd.com/read/29218352/an-ultra-low-frictional-interface-combining-fdts-sams-with-molybdenum-disulfide
#10
Xing'an Cao, Xuehui Gan, Yitian Peng, Yongxia Wang, Xingzhong Zeng, Haojie Lang, Jinan Deng, Kun Zou
Interfacial friction is of crucial importance to ensure the friction-reducing and anti-wear properties of mechanical microstructures in micro/nanoelectromechanical systems (MEMS/NEMS). An ultra-low frictional interface combining hydrophobic 1H,1H,2H,2H-perfluorodecyltrichlorosilane (FDTS) self-assembled monolayers (SAMs) coated on an AFM tip with mechanically exfoliated molybdenum disulfide (MoS2) nanosheets deposited on a planar Si/SiO2 substrate was achieved. The FDTS SAMs/MoS2 interface between the FDTS SAMs and the MoS2 nanosheets exhibits an ultra-low friction force that is independent of the relative humidity...
December 8, 2017: Nanoscale
https://www.readbyqxmd.com/read/29216591/concomitant-monitoring-of-implant-formation-and-drug-release-of-in-situ-forming-poly-lactide-co-glycolide-acid-implants-in-a-hydrogel-matrix-mimicking-the-subcutis-using-uv-vis-imaging
#11
Yu Sun, Henrik Jensen, Nickolaj J Petersen, Susan W Larsen, Jesper Østergaard
For poly (lactide-co-glycolide acid) (PLGA)-based in situ forming implants, the rate of implant formation plays an important role in determining the overall drug release kinetics. Currently, in vitro techniques capable of characterizing the processes of drug release and implant formation at the same time are not available. A hydrogel-based in vitro experimental setup was recently developed requiring only microliter of formulation and forming a closed system potentially suitable for interfacing with various spectroscopic techniques...
December 2, 2017: Journal of Pharmaceutical and Biomedical Analysis
https://www.readbyqxmd.com/read/29216225/real-time-visualization-of-thrombus-formation-at-the-interface-between-connectors-and-tubes-in-medical-devices-by-using-optical-coherence-tomography
#12
Yuki Matsuhashi, Kei Sameshima, Yoshiki Yamamoto, Mitsuo Umezu, Kiyotaka Iwasaki
BACKGROUND: Blood-contacting devices have contributed to improving the treatment of patients. However, thrombus formation at the interface between a connector and tube is still a potential source of thrombus-related complications that induce stroke or myocardial infarction. We aimed to develop a non-blood-contacting real-time method for visualizing thrombus formation, and to experimentally investigate the time-dependent phenomenon of thrombus formation at the interface between a connector and a tube in a medical device...
2017: PloS One
https://www.readbyqxmd.com/read/29216094/analysis-and-reduction-of-the-tdi-ccd-charge-transfer-image-shift
#13
Yun-Hui Li, Xiao-Dong Wang, Wen-Guang Liu, Zhi Wang
Based on the description of the charge transfer process of a time delay integration charge coupled device (TDI CCD), it is pointed out that the relative displacement of the target image and the transferred charge introduces the charge transfer image shift problem in a line transfer period, which leads to the decrease of the modulation transfer function (MTF) in the scanning direction. Based on the basic definition of MTF, the charge transfer image shift model of the TDI CCD is established. According to the quantitative calculation of this model, the MTF curves of the three-phase TDI CCD are obtained under the condition of different pulse widths of computer interface (CI) signals...
November 20, 2017: Applied Optics
https://www.readbyqxmd.com/read/29215871/mpa-portable-a-stand-alone-software-package-for-analyzing-metaproteome-samples-on-the-go
#14
Thilo Muth, Fabian Kohrs, Robert Heyer, Dirk Benndorf, Erdmann Rapp, Udo Reichl, Lennart Martens, Bernhard Y Renard
Metaproteomics, the mass spectrometry-based analysis of proteins from multi-species samples faces severe challenges concerning data analysis and results interpretation. To overcome these shortcomings, we here introduce the MetaProteomeAnalyzer (MPA) Portable software. In contrast to the original server-based MPA application, this newly developed tool no longer requires computational expertise for installation, and is now independent of any relational database system. In addition, MPA Portable now supports state-of-the-art database search engines and a convenient command line interface for high-performance data processing tasks...
December 7, 2017: Analytical Chemistry
https://www.readbyqxmd.com/read/29215261/an-interface-equilibria-triggered-time-dependent-diffusion-model-of-the-boundary-potential-and-its-application-for-the-numerical-simulation-of-the-ion-selective-electrode-response-in-real-systems
#15
Vladimir V Egorov, Andrei D Novakovskii, Elena A Zdrachek
A simple dynamic model of the phase boundary potential of ion-selective electrodes is presented. The model is based on the calculations of the concentration profiles of the components in membrane and sample solution phases by means of finite difference method. The fundamental idea behind the discussed model is that the concentration gradients in membrane and sample solution phases determine only the diffusion of the components inside corresponding phases, but not the transfer across the interface. The transfer of the components across the interface at any instant of time is determined by the corresponding local interphase equilibria...
December 7, 2017: Analytical Chemistry
https://www.readbyqxmd.com/read/29215174/microscale-3d-printing-of-nanotwinned-copper
#16
Ali Behroozfar, Soheil Daryadel, S Reza Morsali, Salvador Moreno, Mahmoud Baniasadi, Rodrigo A Bernal, Majid Minary-Jolandan
Nanotwinned (nt)-metals exhibit superior mechanical and electrical properties compared to their coarse-grained and nanograined counterparts. nt-metals in film and bulk forms are obtained using physical and chemical processes including pulsed electrodeposition (PED), plastic deformation, recrystallization, phase transformation, and sputter deposition. However, currently, there is no process for 3D printing (additive manufacturing) of nt-metals. Microscale 3D printing of nt-Cu is demonstrated with high density of coherent twin boundaries using a new room temperature process based on localized PED (L-PED)...
December 7, 2017: Advanced Materials
https://www.readbyqxmd.com/read/29215097/the-molecular-dialogue-between-arabidopsis-thaliana-and-the-necrotrophic-fungus-botrytis-cinerea-leads-to-major-changes-in-host-carbon-metabolism
#17
Florian Veillet, Cécile Gaillard, Pauline Lemonnier, Pierre Coutos-Thévenot, Sylvain La Camera
Photoassimilates play crucial roles during plant-pathogen interactions, as colonizing pathogens rely on the supply of sugars from hosts. The competition for sugar acquisition at the plant-pathogen interface involves different strategies from both partners which are critical for the outcome of the interaction. Here, we dissect individual mechanisms of sugar uptake during the interaction of Arabidopsis thaliana with the necrotrophic fungus Botrytis cinerea using millicell culture insert, that enables molecular communication without physical contact...
December 7, 2017: Scientific Reports
https://www.readbyqxmd.com/read/29215082/the-myokinetic-control-interface-tracking-implanted-magnets-as-a-means-for-prosthetic-control
#18
S Tarantino, F Clemente, D Barone, M Controzzi, C Cipriani
Upper limb amputation deprives individuals of their innate ability to manipulate objects. Such disability can be restored with a robotic prosthesis linked to the brain by a human-machine interface (HMI) capable of decoding voluntary intentions, and sending motor commands to the prosthesis. Clinical or research HMIs rely on the interpretation of electrophysiological signals recorded from the muscles. However, the quest for an HMI that allows for arbitrary and physiologically appropriate control of dexterous prostheses, is far from being completed...
December 7, 2017: Scientific Reports
https://www.readbyqxmd.com/read/29214982/perspectives-on-theory-at-the-interface-of-physics-and-biology
#19
William Bialek
Theoretical physics is the search for simple and universal mathematical descriptions of the natural world. In contrast, much of modern biology is an exploration of the complexity and diversity of life. For many, this contrast is prima facie evidence that theory, in the sense that physicists use the word, is impossible in a biological context. For others, this contrast serves to highlight a grand challenge. I am an optimist, and believe (along with many colleagues) that the time is ripe for the emergence of a more unified theoretical physics of biological systems, building on successes in thinking about particular phenomena...
December 7, 2017: Reports on Progress in Physics
https://www.readbyqxmd.com/read/29214807/self-assembled-core-shell-cdte-poly-3-hexylthiophene-nanoensembles-as-novel-donor-acceptor-light-harvesting-systems
#20
Emin Istif, Antonia Kagkoura, Javier Hernández-Ferrer, Anastasios Stergiou, Theodosis Skaltsas, Raul Arenal, Ana M Benito, Wolfgang K Maser, Nikos Tagmatarchis
The self-assembly of novel core-shell nanoensembles consisting of regioregular poly(3-hexylthiophene) nanoparticles (P3HTNPs) of 100 nm as core and semiconducting CdTe quantum dots (CdTeQDs) as shell with a thickness of a few tens of nanometers was accomplished by employing a re-precipitation approach. The structure, morphology and composition of P3HTNPs/CdTeQDs nanoensembles were confirmed by high-resolution scanning transmission microscopy and dynamic light scattering studies. Intimate interface contact between the CdTeQDs shell and the P3HTNPs core leads to the stabilization of the P3HTNPs/CdTeQDs nanoensemble as probed by steady-state absorption spectroscopy...
December 7, 2017: ACS Applied Materials & Interfaces
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