Mark Aarts, Willem Q Boon, Blaise Cuénod, Marjolein Dijkstra, René van Roij, Esther Alarcon-Llado
Fluidic devices exhibiting ion current rectification (ICR), or ionic diodes, are of broad interest for applications including desalination, energy harvesting, and sensing, among others. For such applications a large conductance is desirable, which can be achieved by simultaneously using thin membranes and wide pores. In this paper we demonstrate ICR in micrometer sized conical channels in a thin silicon membrane with pore diameters comparable to the membrane thickness but both much larger than the electrolyte screening length...
December 9, 2022: ACS Applied Materials & Interfaces