Katarzyna Posmyk, Natalia Zawadzka, Łucja Kipczak, Mateusz Dyksik, Alessandro Surrente, Duncan K Maude, Tomasz Kazimierczuk, Adam Babiński, Maciej R Molas, Wakul Bumrungsan, Chanisara Chooseng, Watcharaphol Paritmongkol, William A Tisdale, Michał Baranowski, Paulina Plochocka
The optical response of two-dimensional (2D) perovskites, often referred to as natural quantum wells, is primarily governed by excitons, whose properties can be readily tuned by adjusting the perovskite layer thickness. We have investigated the exciton fine structure splitting in the archetypal 2D perovskite (PEA)2 (MA) n -1 Pb n I3 n +1 with varying numbers of inorganic octahedral layers n = 1, 2, 3, and 4. We demonstrate that the in-plane excitonic states exhibit splitting and orthogonally oriented dipoles for all confinement regimes...
February 7, 2024: Journal of the American Chemical Society