Laser cooling quantum physics

Phonon-assisted upconversion photoluminescence (UCPL) plays an important role in a wide range of fields such as optical refrigeration, sensitive optical thermometry, quantum state control, and upconversion optoelectronics. High photoluminescence quantum yield (PLQY) and strong electron-phonon coupling are two basic prerequisites of efficient UCPL materials. The self-trapped exciton (STE) system with the above-mentioned advantages hints that it may be a good candidate for phonon-assisted UCPL. Here, we synthesized Rb2 CuCl3 single crystals (SCs) which yield a high PLQY of the STE emission at 400 nm, and an efficient phonon-assisted UCPL was demonstrated at room temperature...

We report the production and spectroscopic characterization of strontium(I) phenoxide (SrOC6 H5 or SrOPh) and variants featuring electron-withdrawing groups designed to suppress vibrational excitation during spontaneous emission from the electronically excited state. Optical cycling closure of these species, which is the decoupling of the vibrational state changes from spontaneous optical decay, is found by dispersed laser-induced fluorescence spectroscopy to be high, in accordance with theoretical predictions...

We report the measurement of the photoelectron angular distribution of two-photon single-ionization near the 2p^{2} ^{1}D^{e} double-excitation resonance in helium, benchmarking the fundamental nonlinear interaction of two photons with two correlated electrons. This observation is enabled by the unique combination of intense extreme ultraviolet pulses, delivered at the high-repetition-rate free-electron laser in Hamburg (FLASH), ionizing a jet of cryogenically cooled helium atoms in a reaction microscope. The spectral structure of the intense self-amplified spontaneous emission free-electron laser pulses has been resolved on a single-shot level to allow for post selection of pulses, leading to an enhanced spectral resolution, and introducing a new experimental method...

An ensemble of atoms can operate as a quantum sensor by placing atoms in a superposition of two different states. Upon measurement of the sensor, each atom is individually projected into one of the two states. Creating quantum correlations between the atoms, that is entangling them, could lead to resolutions surpassing the standard quantum limit1-3  set by projections of individual atoms. Large amounts of entanglement4-6 involving the internal degrees of freedom of laser-cooled atomic ensembles4-16 have been generated in collective cavity quantum-electrodynamics systems, in which many atoms simultaneously interact with a single optical cavity mode...

Laser cooled atoms have proven transformative for precision metrology, playing a pivotal role in state-of-the-art clocks and interferometers and having the potential to provide a step-change in our modern technological capabilities. To successfully explore their full potential, laser cooling platforms must be translated from the laboratory environment and into portable, compact quantum sensors for deployment in practical applications. This transition requires the amalgamation of a wide range of components and expertise if an unambiguously chip-scale cold atom sensor is to be realized...

The generation of strongly squeezed vacuum states of light is a key technology for future ground-based gravitational wave detectors (GWDs) to reach sensitivities beyond their quantum noise limit. For some proposed observatory designs, an operating laser wavelength of 1550 nm or around 2  μm is required to enable the use of cryogenically cooled silicon test masses for thermal noise reduction. Here, we present for the first time the direct measurement of up to 11.5 dB squeezing at 1550 nm over the complete detection bandwidth of future ground-based GWDs ranging from 10 kHz down to below 1 Hz...

Laser cooling is a key ingredient for quantum control of atomic systems in a variety of settings. In divalent atoms, two-stage Doppler cooling is typically used to bring atoms to the μK regime. Here, we implement a pulsed radial cooling scheme using the ultranarrow ^{1}S_{0}-^{3}P_{0} clock transition in ytterbium to realize subrecoil temperatures, down to tens of nK. Together with sideband cooling along the one-dimensional lattice axis, we efficiently prepare atoms in shallow lattices at an energy of 6 lattice recoils...

Laser cooling atoms and molecules to ultralow temperatures has produced plenty of opportunities in fundamental physics, precision metrology, and quantum science. Although theoretically proposed over 40 years, the laser cooling of certain lattice vibrations (i.e., phonon) remains a challenge owing to the complexity of solid structures. Here, we demonstrate Raman cooling of a longitudinal optical phonon in two-dimensional semiconductor WS2 by red-detuning excitation at the sideband of the exciton (bound electron-hole pair)...

The presence of Polycyclic Aromatic Hydrocarbon (PAH) molecules in the interstellar medium, recently confirmed by the detection of cyano-naphthalenes, has renewed the interest of extensive spectroscopic and physical-chemistry studies on such large species. The present study reports the jet-cooled rovibrational infrared study of three centrosymmetric two-ring PAH molecules, viz., naphthalene (C10 H8 ), [1,5] naphthyridine (C8 H6 N2 ), and biphenyl (C12 H10 ), in the in-plane ring C-H bending (975-1035 cm-1 ) and C-C ring stretching (1580-1620 cm-1 ) regions...

Rapid and repeated photon cycling has enabled precision metrology and the development of quantum information systems using atoms and simple molecules. Extending optical cycling to structurally complex molecules would provide new capabilities in these areas, as well as in ultracold chemistry. Increased molecular complexity, however, makes realizing closed optical transitions more difficult. Building on already established strong optical cycling of diatomic, linear triatomic, and symmetric top molecules, recent work has pointed the way to cycling of larger molecules, including phenoxides...

The BeCs+ system represents a possible future candidate for the realization of samples of cold or ultra-cold molecular ion species that have not yet been investigated experimentally or theoretically. With the aim of highlighting the spectroscopic and electronic structure of the cesium and beryllium cation BeCs+ , we theoretically investigate ground and low lying excited states of 1,3 Σ+ , 1,3 Π and 1,3 Δ symmetries below the first nine asymptotic limits dissociating into Be+ (2s) + Cs(6s, 6p, 5d) and Be(2s2 , 2s2p, 2s3s, 2p2 ) + Cs+ ...

Bose-Einstein condensates (BECs) are macroscopic coherent matter waves that have revolutionized quantum science and atomic physics. They are important to quantum simulation1 and sensing2,3 , for example, underlying atom interferometers in space4 and ambitious tests of Einstein's equivalence principle5,6 . A long-standing constraint for quantum gas devices has been the need to execute cooling stages time-sequentially, restricting these devices to pulsed operation. Here we demonstrate continuous Bose-Einstein condensation by creating a continuous-wave (CW) condensate of strontium atoms that lasts indefinitely...

Laser cooling and trapping1,2 , and magneto-optical trapping methods in particular2 , have enabled groundbreaking advances in science, including Bose-Einstein condensation3-5 , quantum computation with neutral atoms6,7 and high-precision optical clocks8 . Recently, magneto-optical traps (MOTs) of diatomic molecules have been demonstrated9-12 , providing access to research in quantum simulation13 and searches for physics beyond the standard model14 . Compared with diatomic molecules, polyatomic molecules have distinct rotational and vibrational degrees of freedom that promise a variety of transformational possibilities...

Spectroscopic studies of aluminum monofluoride (AlF) have revealed its highly favorable properties for direct laser cooling. All Q lines of the strong A1 Π ← X1 Σ+ transition around 227 nm are rotationally closed and thereby suitable for the main cooling cycle. The same holds for the narrow, spin-forbidden a3 Π ← X1 Σ+ transition around 367 nm, which has a recoil limit in the µK range. We here report on the spectroscopic characterization of the lowest rotational levels in the a3 Π state of AlF for v = 0-8 using a jet-cooled, pulsed molecular beam...

First high-resolution spectra of cold (∼35 K) singlet bromomethylene HCBr in the CH stretching (v1 ) region from 2770 to 2850 cm-1 are reported using near quantum shot-noise limited laser absorption methods in a slit jet supersonic discharge expansion source. Three rovibrational bands are identified at high S/N (20:1-40:1) and rotationally assigned to (i) the CH stretch fundamental (v1 ) band X̃1,0,0←X̃0,0,0 and (ii) vibrational hot bands [X̃(1,1,0)←X̃(0,1,0) and X̃(1,0,1)←X̃(0,0,1)] arising from vibrationally excited HCBr populated in the discharge with single quanta in either the H-C-Br bend (v2 ) or C-Br stretch (v3 ) modes...

Quantum optical measurement techniques offer a rich avenue for quantum control of mechanical oscillators via cavity optomechanics. In particular, a powerful yet little explored combination utilizes optical measurements to perform heralded non-Gaussian mechanical state preparation followed by tomography to determine the mechanical phase-space distribution. Here, we experimentally perform heralded single-phonon and multiphonon subtraction via photon counting to a laser-cooled mechanical thermal state with a Brillouin optomechanical system at room temperature and use optical heterodyne detection to measure the s-parametrized Wigner distribution of the non-Gaussian mechanical states generated...

Imaging is central to gaining microscopic insight into physical systems, and new microscopy methods have always led to the discovery of new phenomena and a deeper understanding of them. Ultracold atoms in optical lattices provide a quantum simulation platform, featuring a variety of advanced detection tools including direct optical imaging while pinning the atoms in the lattice1,2 . However, this approach suffers from the diffraction limit, high optical density and small depth of focus, limiting it to two-dimensional (2D) systems...

The structural and dynamical characteristics of isolated molecules are essential, yet obtaining this information is difficult. We demonstrate laser-desorption jet-cooling/ionization-loss stimulated Raman spectroscopy to obtain Raman spectral signatures of nonvolatile molecules in the gas phase. The vibrational features of a test substance, the most abundant conformer of tryptamine, are compared and found to match those resulting from the scaled harmonic Raman spectrum obtained by density functional theory calculations...

The nature of the quantum-to-classical crossover remains one of the most challenging open question of Science to date. In this respect, moving objects play a specific role. Pioneering experiments over the last few years have begun exploring quantum behaviour of micron-sized mechanical systems, either by passively cooling single GHz modes, or by adapting laser cooling techniques developed in atomic physics to cool specific low-frequency modes far below the temperature of their surroundings. Here instead we describe a very different approach, passive cooling of a whole micromechanical system down to 500 μK, reducing the average number of quanta in the fundamental vibrational mode at 15 MHz to just 0...

We demonstrate superresolution optical sensing of the size of the wave packet of a single trapped ion. Our method extends the well-known ground state depletion (GSD) technique to the coherent regime. Here, we use a hollow beam to strongly saturate a coherently driven dipole-forbidden transition around a subdiffraction limited area at its center and observe state dependent fluorescence. By spatially scanning this laser beam over a single trapped ^{40}Ca^{+} ion, we are able to measure the wave packet sizes of cooled ions...