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https://www.readbyqxmd.com/read/28441470/al2o3-and-sio2-atomic-layer-deposition-layers-on-zno-photoanodes-and-degradation-mechanisms
#1
Qian Cheng, Manpuneet Kaur Benipal, Qianlang Liu, Xingye Wang, Peter A A Crozier, Candace K Chan, Robert J Nemanich
Strategies for protecting unstable semiconductors include the utilization of surface layers comprised of thin films deposited using atomic layer deposition (ALD). The protective layer is expected to: (1) be stable against reaction with photogenerated holes, (2) prevent direct contact of the unstable semiconductor with the electrolyte, and (3) prevent the migration of ions through the semiconductor/electrolyte interface, while still allowing photogenerated carriers to transport to the interface and participate in the desired redox reactions...
April 25, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28440629/relevant-features-of-a-triethylene-glycol-dimethyl-ether-based-electrolyte-for-application-in-lithium-battery
#2
Lorenzo Carbone, Daniele Di Lecce, Mallory Gobet, Stephen Munoz, Matthew Devany, Steve Greenbaum, Jusef Hassoun
Triethylene glycol dimethyl ether (TREGDME) dissolving lithium trifluoromethane sulfonate (LiCF3SO3) is studied as a suitable electrolyte medium for lithium battery. Thermal and rheological characteristics, transport properties of the dissolved species, and the electrochemical behavior in lithium cell represent the most relevant investigated properties of the new electrolyte. The self-diffusion coefficients, the lithium transference numbers, the ionic conductivity, and the ion association degree of the solution are determined by pulse field gradient nuclear magnetic resonance and electrochemical impedance spectroscopy...
April 25, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28440567/dawson-type-polyoxomolybdate-anions-p2mo18o626-captured-by-ionic-liquid-on-graphene-oxide-as-high-capacity-anode-material-for-lithium-ion-batteries
#3
Yu-Fei Song, Jun Hu, Hongling Diao, Wenjing Luo
The development of advanced anode materials is of significance for the next generation of lithium ion batteries (LIBs). Herein, the imidazolium-based ionic liquids (ILs) was covalently grafted on the surface of graphene oxides (GO) via the carboxyl-amino bond,providing a loading hotbed for the Dawson-type POM of (NH4)6P2Mo18O62 (denoted as P2Mo18). The as-prepared GO-IL-P2Mo18 nanocomposite was characterized by FT-IR, Raman, TGA, SEM, TEM and XPS. When the nanocomposite was used as the anode material for lithium ion batteries (LIBs), it showed a high reversible capacity of 903...
April 25, 2017: Chemistry: a European Journal
https://www.readbyqxmd.com/read/28440379/high-voltage-positive-electrode-materials-for-lithium-ion-batteries
#4
REVIEW
Wangda Li, Bohang Song, Arumugam Manthiram
The ever-growing demand for advanced rechargeable lithium-ion batteries in portable electronics and electric vehicles has spurred intensive research efforts over the past decade. The key to sustaining the progress in Li-ion batteries lies in the quest for safe, low-cost positive electrode (cathode) materials with desirable energy and power capabilities. One approach to boost the energy and power densities of batteries is to increase the output voltage while maintaining a high capacity, fast charge-discharge rate, and long service life...
April 25, 2017: Chemical Society Reviews
https://www.readbyqxmd.com/read/28440299/a-reversible-dendrite-free-high-areal-capacity-lithium-metal-electrode
#5
Hui Wang, Masaki Matsui, Hiroko Kuwata, Hidetoshi Sonoki, Yasuaki Matsuda, Xuefu Shang, Yasuo Takeda, Osamu Yamamoto, Nobuyuki Imanishi
Reversible dendrite-free low-areal-capacity lithium metal electrodes have recently been revived, because of their pivotal role in developing beyond lithium ion batteries. However, there have been no reports of reversible dendrite-free high-areal-capacity lithium metal electrodes. Here we report on a strategy to realize unprecedented stable cycling of lithium electrodeposition/stripping with a highly desirable areal-capacity (12 mAh cm(-2)) and exceptional Coulombic efficiency (>99.98%) at high current densities (>5 mA cm(-2)) and ambient temperature using a diluted solvate ionic liquid...
April 25, 2017: Nature Communications
https://www.readbyqxmd.com/read/28439898/optimizing-autologous-nonmobilized-mononuclear-cell-collections-for-cellular-therapy-in-pediatric-patients-with-high-risk-leukemia
#6
Ehud Even-Or, Maria Di Mola, Muhammad Ali, Sarah Courtney, Elizabeth McDougall, Sarah Alexander, Tal Schechter, James A Whitlock, Christoph Licht, Joerg Krueger
BACKGROUND: The manufacturing of cellular products for immunotherapy, such as chimeric antigen receptor T cells, requires successful collection of mononuclear cells. Collections from children with high-risk leukemia present a challenge, especially because the established COBE Spectra apheresis device is being replaced by the novel Spectra Optia device (Optia) in many institutions. Published experience for mononuclear cell collections in children with Optia is lacking. Our aim was to compare the two collection devices and describe modified settings on the Optia to optimize mononuclear cell collections...
April 25, 2017: Transfusion
https://www.readbyqxmd.com/read/28439845/a-systematic-review-of-the-clinical-presentation-diagnosis-and-treatment-of-small-bowel-obstruction
#7
REVIEW
Srinivas R Rami Reddy, Mitchell S Cappell
PURPOSE OF REVIEW: This study aimed to systematically review small bowel obstruction (SBO), focusing on recent changes in diagnosis/therapy. RECENT FINDINGS: SBO incidence is about 350,000/annum in the USA. Etiologies include adhesions (65%), hernias (10%), neoplasms (5%), Crohn's disease (5%), and other (15%). Bowel dilatation occurs proximal to obstruction primarily from swallowed air and secondarily from intraluminal fluid accumulation. Dilatation increases mural tension, decreases mucosal perfusion, causes bacterial proliferation, and decreases mural tensile strength that increases bowel perforation risks...
June 2017: Current Gastroenterology Reports
https://www.readbyqxmd.com/read/28439557/designer-interphases-for-the-lithium-oxygen-electrochemical-cell
#8
Snehashis Choudhury, Charles Tai-Chieh Wan, Wajdi I Al Sadat, Zhengyuan Tu, Sampson Lau, Michael J Zachman, Lena F Kourkoutis, Lynden A Archer
An electrochemical cell based on the reversible oxygen reduction reaction: 2Li(+) + 2e (-) + O2↔ Li2O2, provides among the most energy dense platforms for portable electrical energy storage. Such Lithium-Oxygen (Li-O2) cells offer specific energies competitive with fossil fuels and are considered promising for electrified transportation. Multiple, fundamental challenges with the cathode, anode, and electrolyte have limited practical interest in Li-O2 cells because these problems lead to as many practical shortcomings, including poor rechargeability, high overpotentials, and specific energies well below theoretical expectations...
April 2017: Science Advances
https://www.readbyqxmd.com/read/28439465/single-exponential-decay-waveform-a-synergistic-combination-of-electroporation-and-electrolysis-e2-for-tissue-ablation
#9
Nina Klein, Enric Guenther, Paul Mikus, Michael K Stehling, Boris Rubinsky
BACKGROUND: Electrolytic ablation and electroporation based ablation are minimally invasive, non-thermal surgical technologies that employ electrical currents and electric fields to ablate undesirable cells in a volume of tissue. In this study, we explore the attributes of a new tissue ablation technology that simultaneously delivers a synergistic combination of electroporation and electrolysis (E2). METHOD: A new device that delivers a controlled dose of electroporation field and electrolysis currents in the form of a single exponential decay waveform (EDW) was applied to the pig liver, and the effect of various parameters on the extent of tissue ablation was examined with histology...
2017: PeerJ
https://www.readbyqxmd.com/read/28439284/the-translation-initiation-factor-1a-theif1a-from-tamarix-hispida-is-regulated-by-a-dof-transcription-factor-and-increased-abiotic-stress-tolerance
#10
Guiyan Yang, Lili Yu, Yucheng Wang, Chao Wang, Caiqiu Gao
Eukaryotic translation initiation factor 1A (eIF1A) functions as an mRNA scanner and AUG initiation codon locator. However, few studies have clarified the role of eIF1A in abiotic stress. In this study, we cloned eIF1A (TheIF1A) from Tamarix hispida and found its expression to be induced by NaCl and polyethylene glycol (PEG) in roots, stems, and leaves. Compared to control, TheIF1A root expression was increased 187.63-fold when exposed to NaCl for 6 h, suggesting a potential abiotic stress response for this gene...
2017: Frontiers in Plant Science
https://www.readbyqxmd.com/read/28439282/overexpression-of-cucumber-phospholipase-d-alpha-gene-cspld%C3%AE-in-tobacco-enhanced-salinity-stress-tolerance-by-regulating-na-k-balance-and-lipid-peroxidation
#11
Tuo Ji, Shuzhen Li, Meili Huang, Qinghua Di, Xiufeng Wang, Min Wei, Qinghua Shi, Yan Li, Biao Gong, Fengjuan Yang
Plant phospholipase D (PLD), which can hydrolyze membrane phospholipids to produce phosphatidic acid (PA), a secondary signaling molecule, has been proposed to function in diverse plant stress responses. In this research, we characterized the roles of the cucumber phospholipase D alpha gene (PLDα, GenBank accession number EF363796) in growth and tolerance to short- and long-term salt stress in transgenic tobacco (Nicotiana tabacum). Fresh and dry weights of roots, PLD activity and content, mitogen activated protein kinase (MAPK) gene expression, Na(+)-K(+) homeostasis, expression of genes encoding ion exchange, reactive oxygen species (ROS) metabolism and osmotic adjustment substances were investigated in wild type (WT) and CsPLDα-overexpression tobacco lines grown under short- and long-term high salt (250 mM) stress...
2017: Frontiers in Plant Science
https://www.readbyqxmd.com/read/28439085/a-high-power-and-fast-charging-li-ion-battery-with-outstanding-cycle-life
#12
M Agostini, S Brutti, M A Navarra, S Panero, P Reale, A Matic, B Scrosati
Electrochemical energy storage devices based on Li-ion cells currently power almost all electronic devices and power tools. The development of new Li-ion cell configurations by incorporating innovative functional components (electrode materials and electrolyte formulations) will allow to bring this technology beyond mobile electronics and to boost performance largely beyond the state-of-the-art. Here we demonstrate a new full Li-ion cell constituted by a high-potential cathode material, i.e. LiNi0.5Mn1.5O4, a safe nanostructured anode material, i...
April 24, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28437588/ehanced-solar-water-splitting-by-swift-charge-separation-in-au-feooh-sandwiched-single-crystalline-fe2o3-nanoflake-photoelectrodes
#13
Lei Wang, Nhat Truong Nguyen, Yajun Zhang, Yingpu Bi, Patrik Schmuki
In this work, single crystalline α-Fe2O3 nanoflakes (NFs) are formed in a highly dense array by Au seeding of a Fe substrate by a thermal oxidation technique. The NFs are conformally decorated with a thin FeOOH cocatalyst layer. Photoelectrochemical (PEC) measurements show that this photoanode with the α-Fe2O3/FeOOH NFs rooted on the Au/Fe structure exhibits a significantly enhanced PEC water oxidation performance compared to the plain α-Fe2O3 nanostructure on the Fe substrate. The α-Fe2O3/FeOOH NFs on Au/Fe photoanode yields a photocurrent density of 3...
April 24, 2017: ChemSusChem
https://www.readbyqxmd.com/read/28437484/ecg-view-ii-a-freely-accessible-electrocardiogram-database
#14
Young-Gun Kim, Dahye Shin, Man Young Park, Sukhoon Lee, Min Seok Jeon, Dukyong Yoon, Rae Woong Park
The Electrocardiogram Vigilance with Electronic data Warehouse II (ECG-ViEW II) is a large, single-center database comprising numeric parameter data of the surface electrocardiograms of all patients who underwent testing from 1 June 1994 to 31 July 2013. The electrocardiographic data include the test date, clinical department, RR interval, PR interval, QRS duration, QT interval, QTc interval, P axis, QRS axis, and T axis. These data are connected with patient age, sex, ethnicity, comorbidities, age-adjusted Charlson comorbidity index, prescribed drugs, and electrolyte levels...
2017: PloS One
https://www.readbyqxmd.com/read/28437078/a-step-towards-high-energy-silicon-based-thin-film-lithium-ion-batteries
#15
Antonia Reyes Jiménez, Richard Klöpsch, Ralf Wagner, Uta C Rodehorst, Martin Kolek, Roman Nölle, Martin Winter, Tobias Placke
The next generation of lithium ion batteries (LIBs) with increased energy density for large-scale applications, such as electric mobility, but also for small electronic devices, e.g. micro-batteries and on-chip batteries, requires advanced electrode active materials with enhanced specific and volumetric capacities. In this regard, silicon (Si) as anode material has attracted much attention due to its high specific capacity. However, the enormous volume changes during lithiation/de-lithiation are still a main obstacle avoiding the broad commercial use of Si-based electrodes...
April 24, 2017: ACS Nano
https://www.readbyqxmd.com/read/28437061/nano-micro-hierarchical-structured-limn0-85fe0-15po4-cathode-material-for-advanced-lithium-ion-battery
#16
Zhihong Lei, Jiulin Wang, Jun Yang, Yanna Nuli, Zifeng Ma
Nano/micro-hierarchical-structured LiMn0.85Fe0.15PO4/C cathode materials were prepared by solvothermal synthesis combined with spray pyrolysis. XRD patterns and HRTEM images indicate that the LiMn0.85Fe0.15PO4/C are well crystallized and no impurity is observed. The as-prepared LiMn0.85Fe0.15PO4/C porous spherical (0.5-11 m) are accumulated by primary nanoparticles (~50 nm in width, 50-250 m in length). Adopting the sucrose as a carbon source, the cathode delivers a reversible discharge capacity of 171...
April 24, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28437015/one-step-solution-phase-growth-of-transition-metal-dichalcogenide-thin-films-directly-on-solid-substrates
#17
Anupam Giri, Heeseung Yang, Kalianan Thiyagarajan, Woosun Jang, Jae Min Myoung, Ranbir Singh, Aloysius Soon, Kilwon Cho, Unyong Jeong
Ultrathin transition metal dichalcogenides (TMDs) have exotic electronic properties. With success in easy synthesis of high quality TMD thin films, the potential applications will become more viable in electronics, optics, energy storage, and catalysis. Synthesis of TMD thin films has been mostly performed in vacuum or by thermolysis. So far, there is no solution phase synthesis to produce large-area thin films directly on target substrates. Here, this paper reports a one-step quick synthesis (within 45-90 s) of TMD thin films (MoS2 , WS2 , MoSe2 , WSe2 , etc...
April 24, 2017: Advanced Materials
https://www.readbyqxmd.com/read/28436604/solvent-free-mechanochemical-synthesis-of-nitrogen-doped-nanoporous-carbon-for-electrochemical-energy-storage
#18
Christina Schneidermann, Nicolas Jaeckel, Steffen Oswald, Lars Giebeler, Volker Presser, Lars Borchardt
Nitrogen-doped nanoporous carbons have been synthesized by a solvent-free mechanochemically-induced one-pot synthesis. This facile approach involves the mechanochemical treatment and carbonization of three solid materials: potassium carbonate, urea, and lignin, which is a waste product from pulp industry. The resulting nitrogen-doped porous carbons offer a very high specific surface area up to 3000 m2 g-1 and large pore volume up to 2 cm3 g-1. The mechanochemical reaction and the impact of activation and functionalization are investigated by nitrogen- and water physisorption and high-resolution X-ray photoelectron spectroscopy (XPS)...
April 24, 2017: ChemSusChem
https://www.readbyqxmd.com/read/28436543/facile-formation-of-a-solid-electrolyte-interface-as-a-smart-blocking-layer-for-high-stability-sulfur-cathode
#19
Junling Guo, Xinyu Du, Xiaolong Zhang, Fengxiang Zhang, Jinping Liu
The practical application of lithium-sulfur batteries (LSBs) is hindered by their poor cycle life, which stems mainly from the "redox shuttle reactions" of dissolved polysulfides. To develop a high-performance cathode for LSBs, encapsulation of polysulfides with a blocking layer is potentially straightforward. Herein, a novel strategy is reported encapsulate sulfur and the electrolyte together in porous carbon spheres by using a solid electrolyte interface (SEI) that can selectively sieve Li(+) ions while efficiently avoiding polysulfide accumulation and suppressing undesired polysulfide migration...
April 24, 2017: Advanced Materials
https://www.readbyqxmd.com/read/28436529/modifying-surface-forces-through-control-of-surface-potentials
#20
Ran Tivony, Jacob Klein
Combining direct surface force measurements with in situ regulation of surface potential provides an exceptional opportunity for investigating and manipulating interfacial phenomena. Recently, we studied the interaction between gold and mica surfaces in water with no added salt, while controlling the metal potential, and found that the surface charge at the metal may vary, and possibly even change its sign, as it progressively approaches the (constant-charge) mica surface [Langmuir, 2015, 31(47), 12845-12849]...
April 24, 2017: Faraday Discussions
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