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https://www.readbyqxmd.com/read/28299778/the-short-lived-neon-damsel-pomacentrus-coelestis-implications-for-population-dynamics
#1
M J Kingsford, M D O'Callaghan, L Liggins, G Gerlach
Daily increments of Pomacentrus coelestis, an abundant and well-studied fish, were validated for the life of the fish and depending on the location, age-maxima were estimated to be 127-160 days on reefs separated by tens to hundreds of kilometres on the Great Barrier Reef. This contrasts with congeners and other damselfishes that live for 5 years or more. Otoliths of P. coelestis were thinner and had different patterns of banding when compared with relatively long-lived congeners. It is suggested that banding patterns in P...
March 16, 2017: Journal of Fish Biology
https://www.readbyqxmd.com/read/28280999/histomorphologic-and-ultrastructural-recovery-of-myopathy-in-rats-treated-with-low-level-laser-therapy
#2
Natalia Servetto, David Cremonezzi, Juan Carlos Simes, Antonio Di Pietro, Vilma R Campana
The purpose of the present work was to study the effect of low-level laser therapy (LLLT): helium-neon (He-Ne) and gallium arsenide (Ga-As) laser on the histomorphology of muscle and mitochondria in experimental myopathy in rats. Thirty Suquía strain female rats were distributed in groups: (A) control (intact), (B) injured, (C) injured and treated with He-Ne laser, (D) injured and treated with Ga-As laser, (E) irradiated with He-Ne laser on the non-injured muscle, and (F) irradiated with Ga-As laser on the non-injured muscle...
March 9, 2017: Lasers in Medical Science
https://www.readbyqxmd.com/read/28256134/formation-of-exotic-networks-of-water-clusters-in-helium-droplets-facilitated-by-the-presence-of-neon-atoms
#3
Gary E Douberly, Roger E Miller, Sotiris S Xantheas
Water clusters are formed in helium droplets via the sequential capture of monomers. One or two neon atoms are added to each droplet prior to the addition of water. The infrared spectrum of the droplet ensemble reveals several signatures of polar, water tetramer clusters having dipole moments between 2D and 3D. Comparison with ab initio computations supports the assignment of the cluster networks to noncyclic "3 + 1" clusters, which are ∼5.3 kcal/mol less stable than the global minimum nonpolar cyclic tetramer...
March 8, 2017: Journal of the American Chemical Society
https://www.readbyqxmd.com/read/28249441/communication-neutral-atom-imaging-using-a-pulsed-electromagnetic-lens
#4
Jamie R Gardner, Erik M Anciaux, Mark G Raizen
We report on progress towards a neutral atom imaging device that will be used for chemically sensitive surface microscopy and nanofabrication. Our novel technique for improving refractive power and correcting chromatic aberration in atom lenses is based on a fundamental paradigm shift from continuous-beam focusing to a pulsed, three-dimensional approach. Simulations of this system suggest that it will pave the way toward the long-sought goal of true atom imaging on the nanoscale. Using a prototype lens with a supersonic beam of metastable neon, we have imaged complex patterns with lower distortion and higher resolution than has been shown in any previous experiment...
February 28, 2017: Journal of Chemical Physics
https://www.readbyqxmd.com/read/28124404/vacuum-ultraviolet-photon-mediated-production-of-18-f-f2
#5
Anna Krzyczmonik, Thomas Keller, Anna Kirjavainen, Sarita Forsback, Olof Solin
The chemistry of F2 and its derivatives are amenable to facile aliphatic or aromatic substitution, as well as electrophilic addition. The main limitation in the use of [(18) F]F2 for radiopharmaceutical synthesis is the low specific activity achieved by the traditional methods of production. The highest specific activities, 55 GBq/µmol, for [(18) F]F2 have been achieved so far by using electrical discharge in the post-target production of [(18) F]F2 gas from [(18) F]CH3 F. We demonstrate that [(18) F]F2 is produced by illuminating a gas mixture of neon/F2 /[(18) F]CH3 F with vacuum ultraviolet (VUV) photons generated by an excimer laser...
January 25, 2017: Journal of Labelled Compounds & Radiopharmaceuticals
https://www.readbyqxmd.com/read/28070989/fullerenes-in-space
#6
John Paul Maier, Ewen Kyle Campbell
In 1985 the football structure of $\textrm{C}_{60}$, buckminsterfullerene was proposed and subsequently confirmed following its macroscopic synthesis in 1990. From the very beginning the role of $\textrm{C}_{60}$ and $\textrm{C}_{60}^{+}$ in space was considered, particularly in the context of the enigmatic diffuse interstellar bands. These are absorption features found in the spectra of reddened star light. The first astronomical observations were made around one hundred years ago and despite significant efforts none of the interstellar molecules responsible have been identified...
January 10, 2017: Angewandte Chemie
https://www.readbyqxmd.com/read/28059541/delocalization-of-a-vacancy-across-two-neon-atoms-bound-by-the-van-der-waals-force
#7
H Sann, C Schober, A Mhamdi, F Trinter, C Müller, S K Semenov, M Stener, M Waitz, T Bauer, R Wallauer, C Goihl, J Titze, F Afaneh, L Ph H Schmidt, M Kunitski, H Schmidt-Böcking, Ph V Demekhin, N A Cherepkov, M S Schöffler, T Jahnke, R Dörner
We experimentally study 2p photoionization of neon dimers (Ne_{2}) at a photon energy of hν=36.56  eV. By postselection of ionization events which lead to a dissociation into Ne^{+}+Ne we obtain the photoelectron angular emission distribution in the molecular frame. This distribution is symmetric with respect to the direction of the charged vs neutral fragment. It shows an inverted Cohen-Fano double slit interference pattern of two spherical waves emitted coherently but with opposite phases from the two atoms of the dimer...
December 23, 2016: Physical Review Letters
https://www.readbyqxmd.com/read/27995259/on-the-accuracy-of-the-general-state-specific-polarizable-continuum-model-for-the-description-of-correlated-ground-and-excited-states-in-solution
#8
Jan-Michael Mewes, John M Herbert, Andreas Dreuw
Equilibrium and non-equilibrium formulations of the state-specific polarizable-continuum model (SS-PCM) are evaluated in combination with correlated ground- and excited-state densities provided by the algebraic-diagrammatic construction method (ADC) for the polarization propagator via the computationally efficient intermediate-state representation (ISR) formalism. Since the influence of the SS-PCM onto quantum-chemical method is naturally limited to the presence of the apparent surface charges in the one-electron Hamiltonian and hence fully contained in the polarized MOs, the herein presented solvent model can be combined with all implemented orders and variants of ADC...
January 4, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/27988636/-i-papuaneon-i-a-new-genus-of-jumping-spiders-from-papua-new-guinea-araneae-salticidae-neonini
#9
Wayne P Maddison
The genus Neon Simon stands alone as a phylogenetically isolated astioid jumping spider, the only member of the Neonini. The new genus Papuaneon is established for the jumping spider Papuaneon tualapa sp. nov. from Papua New Guinea. Resembling a large, hirsute Neon, it is here shown to be the sister group to Neon, based on data from the nuclear 28S and Actin 5C, and the mitochondrial 16SND1 region. Photographs of living specimens are provided.
November 29, 2016: Zootaxa
https://www.readbyqxmd.com/read/27976905/structure-and-electronic-transitions-of-c7h4o2-and-c7h5o2-ions-neon-matrix-and-theoretical-studies
#10
Jan Fulara, Sonia Erattupuzha, Iryna Garkusha, John P Maier
C7H4O2(+) and C7H5O2(+) ions and the respective neutrals have been investigated by absorption spectroscopy in neon matrixes following mass selection of ions produced from salicylic acid. Three electronic transitions starting at 649.6, 431.0, and 372.0 nm are detected for C7H4O2(+) and assigned on the basis of CASPT2 energies and Franck-Condon simulations as the excitations from the X (2)A″ to the 1 (2)A″, 2 (2)A″, and 3 (2)A″ electronic states of 6-(oxomethylene)-2,4-cyclohexadien-1-one ion (A(+)). Absorptions commencing at 366...
December 29, 2016: Journal of Physical Chemistry. A
https://www.readbyqxmd.com/read/27968705/efficient-nonviral-transfection-of-primary-intervertebral-disc-cells-by-electroporation-for-tissue-engineering-application
#11
Rahel D May, Adel Tekari, Daniela A Frauchiger, Anna Krismer, Lorin M Benneker, Benjamin Gantenbein
Low back pain (LBP) is an increasing global health problem associated with intervertebral disc (IVD) trauma and degeneration. Current treatment options include surgical interventions with partial unsatisfactory outcomes reported such as failure to relieve LBP, nonunions, nerve injuries, or adjacent segment disease. Cell-based therapy and tissue engineered IVD constructs supplemented with transfected disc cells that incorporate factors enhancing matrix synthesis represent an appealing approach to regenerate the IVD...
January 2017: Tissue Engineering. Part C, Methods
https://www.readbyqxmd.com/read/27959532/conformational-landscape-of-the-1-1-diacetyl-water-complex-investigated-by-infrared-spectroscopy-and-ab-initio-calculations
#12
D Dargent, B Madebène, P Soulard, B Tremblay, E L Zins, M E Alikhani, P Asselin
The complexes of diacetyl with water have been studied experimentally by Fourier transform infrared (FTIR) spectroscopy coupled to solid neon matrix and supersonic jet, and anharmonic ab initio calculations. The vibrational analysis of neon matrix spectra over the 100-7500 cm(-1) infrared range confirms the existence of two nearly isoenergetic one-to-one (1/1) diacetyl-water S1 and S2 isomers already evidenced in a previous argon matrix study. A third form (S3) predicted slightly less stable ( J. Mol. Mod. 2015 , 21 , 214 ) is not observed...
December 21, 2016: Journal of Physical Chemistry. A
https://www.readbyqxmd.com/read/27917867/interatomic-coulombic-decay-cascades-in-multiply-excited-neon-clusters
#13
K Nagaya, D Iablonskyi, N V Golubev, K Matsunami, H Fukuzawa, K Motomura, T Nishiyama, T Sakai, T Tachibana, S Mondal, S Wada, K C Prince, C Callegari, C Miron, N Saito, M Yabashi, Ph V Demekhin, L S Cederbaum, A I Kuleff, M Yao, K Ueda
In high-intensity laser light, matter can be ionized by direct multiphoton absorption even at photon energies below the ionization threshold. However on tuning the laser to the lowest resonant transition, the system becomes multiply excited, and more efficient, indirect ionization pathways become operative. These mechanisms are known as interatomic Coulombic decay (ICD), where one of the species de-excites to its ground state, transferring its energy to ionize another excited species. Here we show that on tuning to a higher resonant transition, a previously unknown type of interatomic Coulombic decay, intra-Rydberg ICD occurs...
December 5, 2016: Nature Communications
https://www.readbyqxmd.com/read/27910676/in-situ-wavelength-calibration-of-the-edge-cxs-spectrometers-on-jet
#14
E Delabie, N Hawkes, T M Biewer, M G O'Mullane
A method for obtaining an accurate wavelength calibration over the entire focal plane of the JET edge CXS spectrometers is presented that uses a combination of the fringe pattern created with a Fabry-Pérot etalon and a neon lamp for cross calibration. The accuracy achieved is 0.03 Å, which is the same range of uncertainty as when neglecting population effects on the rest wavelength of the CX line. For the edge CXS diagnostic, this corresponds to a flow velocity of 4.5 km/s in the toroidal direction or 1.9 km/s in the poloidal direction...
November 2016: Review of Scientific Instruments
https://www.readbyqxmd.com/read/27910613/feasibility-of-line-ratio-spectroscopy-on-helium-and-neon-as-edge-diagnostic-tool-for-wendelstein-7-x
#15
T Barbui, M Krychowiak, R König, O Schmitz, J M Muñoz Burgos, B Schweer, A Terra
A beam emission spectroscopy system on thermal helium (He) and neon (Ne) has been set up at Wendelstein 7-X to measure edge electron temperature and density profiles utilizing the line-ratio technique or its extension by the analysis of absolutely calibrated line emissions. The setup for a first systematic test of these techniques of quantitative atomic spectroscopy in the limiter startup phase (OP1.1) is reported together with first measured profiles. This setup and the first results are an important test for developing the technique for the upcoming high density, low temperature island divertor regime...
November 2016: Review of Scientific Instruments
https://www.readbyqxmd.com/read/27910523/first-measurement-of-the-edge-charge-exchange-recombination-spectroscopy-on-east-tokamak
#16
Y Y Li, X H Yin, J Fu, D Jiang, S Y Feng, B Lyu, Y J Shi, Y Yi, X J Zhou, C D Hu, M Y Ye, B N Wan
An edge toroidal charge exchange recombination spectroscopy (eCXRS) diagnostic, based on a heating neutral beam injection (NBI), has been deployed recently on the Experimental Advanced Superconducting Tokamak (EAST). The eCXRS, which aims to measure the plasma ion temperature and toroidal rotation velocity in the edge region simultaneously, is a complement to the exiting core CXRS (cCXRS). Two rows with 32 fiber channels each cover a radial range from ∼2.15 m to ∼2.32 m with a high spatial resolution of ∼5-7 mm...
November 2016: Review of Scientific Instruments
https://www.readbyqxmd.com/read/27910392/real-time-radiative-divertor-feedback-control-development-for-the-nstx-u-tokamak-using-a-vacuum-ultraviolet-spectrometer
#17
V A Soukhanovskii, R Kaita, B Stratton
A radiative divertor technique is planned for the NSTX-U tokamak to prevent excessive erosion and thermal damage of divertor plasma-facing components in H-mode plasma discharges with auxiliary heating up to 12 MW. In the radiative (partially detached) divertor, extrinsically seeded deuterium or impurity gases are used to increase plasma volumetric power and momentum losses. A real-time feedback control of the gas seeding rate is planned for discharges of up to 5 s duration. The outer divertor leg plasma electron temperature Te estimated spectroscopically in real time will be used as a control parameter...
November 2016: Review of Scientific Instruments
https://www.readbyqxmd.com/read/27908117/investigating-tunnel-and-above-barrier-ionization-using-complex-scaled-coupled-cluster-theory
#18
Thomas-C Jagau
The theory and implementation of the complex-scaled coupled-cluster method with singles and doubles excitations (cs-CCSD) for studying resonances induced by static electric fields are presented. Within this framework, Stark shifts and ionization rates are obtained directly from the real and imaginary parts of the complex energy. The method is applied to the ground states of hydrogen, helium, lithium, beryllium, neon, argon, and carbon at varying field strengths. Complex-scaled Hartree-Fock, second-order many-body perturbation theory, and CCSD results are reported and analyzed with a focus on the impact of electron correlation on the ionization process...
November 28, 2016: Journal of Chemical Physics
https://www.readbyqxmd.com/read/27886307/a-simple-guiding-principle-for-the-temperature-dependence-of-the-solubility-of-light-gases-in-imidazolium-based-ionic-liquids-derived-from-molecular-simulations
#19
Daniela Kerlé, Majid Namayandeh Jorabchi, Ralf Ludwig, Sebastian Wohlrab, Dietmar Paschek
We have determined the temperature dependence of the solvation behavior of a large collection of important light gases in imidazolium-based ionic liquids with the help of extensive molecular dynamics simulations. The motivation of our study is to unravel common features of the temperature dependent solvation under well controlled conditions, and to provide a guidance for cases, where experimental data from different sources disagree significantly. The solubility of molecular hydrogen, oxygen, nitrogen, methane, krypton, argon, neon and carbon dioxide in the imidazolium based ionic liquids of type 1-n-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([Cnmim][NTf2]) with varying alkyl side chain lengths n = 2, 4, 6, 8 is computed for a temperature range between 300 K and 500 K at 1 bar...
January 18, 2017: Physical Chemistry Chemical Physics: PCCP
https://www.readbyqxmd.com/read/27869265/radiation-induced-transformations-of-methanol-molecules-in-low-temperature-solids-a-matrix-isolation-study
#20
Elizaveta V Saenko, Vladimir I Feldman
The effect of X-ray irradiation on methanol molecules (CH3OH, CD3OH, and (13)CH3OH) isolated in solid noble gas matrices (Ne, Ar, Kr, and Xe) was studied by FTIR spectroscopy at 6 K. CH2OH˙, H2CO, HCO˙ and CO were found to be the main degradation products. Somewhat unexpectedly, the production of CO is quite prominent, even at low doses, and it strongly predominates in low-polarizable matrices (especially, in neon). This result is explained by inefficient quenching of excess energy in the H2CO molecules initially generated from methanol...
November 30, 2016: Physical Chemistry Chemical Physics: PCCP
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