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https://www.readbyqxmd.com/read/28819129/dielectric-properties-of-y-and-nb-co-doped-tio2-ceramics
#1
Xianwei Wang, Bihui Zhang, Linhai Xu, Xiaoer Wang, Yanchun Hu, Gaohang Shen, Lingyun Sun
In this work, the (Y0.5Nb0.5)xTi1-xO2 (x = 0.001, 0.01, 0.02, 0.04, 0.06 and 0.1) ceramics (as called YNTO) were fabricated by synthesized through a standard solid-state reaction. As revealed by the X-ray diffraction (XRD) spectra, the YNTOs exhibit tetragonal rutile structure. Meanwhile, the grain size of YNTO ceramics increased and then decreased with the increase of x value, and the largest value reached when x = 0.02. All the YNTO samples display colossal permittivity (~10(2)-10(5)) over a wide temperature and frequency range...
August 17, 2017: Scientific Reports
https://www.readbyqxmd.com/read/28804526/solid-state-ionics-a-japan-perspective
#2
Osamu Yamamoto
The 70-year history of scientific endeavor of solid state ionics research in Japan is reviewed to show the contribution of Japanese scientists to the basic science of solid state ionics and its applications. The term 'solid state ionics' was defined by Takehiko Takahashi of Nagoya University, Japan: it refers to ions in solids, especially solids that exhibit high ionic conductivity at a fairly low temperature below their melting points. During the last few decades of exploration, many ion conducting solids have been discovered in Japan such as the copper-ion conductor Rb4Cu16I7Cl13, proton conductor SrCe1-x Y x O3, oxide-ion conductor La0...
2017: Science and Technology of Advanced Materials
https://www.readbyqxmd.com/read/28799936/oily-wastewater-treatment-by-adsorption-membrane-filtration-hybrid-process-using-powdered-activated-carbon-natural-zeolite-powder-and-low-cost-ceramic-membranes
#3
Yaser Rasouli, Mohsen Abbasi, Seyed Abdollatif Hashemifard
In this research, four types of low cost and high performance ceramic microfiltration (MF) membranes have been employed in an in-line adsorption-MF process for oily wastewater treatment. Mullite, mullite-alumina, mullite-alumina-zeolite and mullite-zeolite membranes were fabricated as ceramic MF membranes by low cost kaolin clay, natural zeolite and α-alumina powder. Powdered activated carbon (PAC) and natural zeolite powder in concentrations of 100-800 mg L(-1) were used as adsorbent agent in the in-line adsorption-MF process...
August 2017: Water Science and Technology: a Journal of the International Association on Water Pollution Research
https://www.readbyqxmd.com/read/28791801/one-piece-internal-zirconia-abutments-for-single-tooth-restorations-on-narrow-and-regular-diameter-implants-a-5-year-prospective-follow-up-study
#4
Andrée Nilsson, Lars-Åke Johansson, Christina Lindh, Anders Ekfeldt
BACKGROUND: Studies have reported an increased risk for fractures of zirconia abutments compared with titanium abutments. PURPOSE: The aim of this study was to evaluate single-tooth implant restorations with one-piece yttria-stabilized internal zirconia abutments on narrow and regular diameter implants up to 6 years after insertion. MATERIAL AND METHODS: This study comprises 52 consecutively treated patients, with a median age of 19 years...
August 9, 2017: Clinical Implant Dentistry and related Research
https://www.readbyqxmd.com/read/28782955/quantification-of-the-partitioning-ratio-of-minor-actinide-surrogates-between-zirconolite-and-glass-in-glass-ceramic-for-nuclear-waste-disposal
#5
Chang-Zhong Liao, Chengshuai Liu, Minhua Su, Kaimin Shih
Zirconolite-based glass-ceramic is considered a promising wasteform for conditioning minor actinide-rich nuclear wastes. Recent studies on this wasteform have sought to enhance the partitioning ratio (PR) of minor actinides in zirconolite crystal. To optimize the PR in the SiO2-Al2O3-CaO-TiO2-ZrO2 system, a novel conceptual approach, which can be derived from the chemical composition and quantity of zirconolite crystal in glass-ceramic, was introduced based on the results of Rietveld quantitative X-ray diffraction analysis and transmission electron microscopy energy dispersive X-ray spectroscopy...
August 7, 2017: Inorganic Chemistry
https://www.readbyqxmd.com/read/28777535/electrospun-nanofibers-new-concepts-materials-and-applications
#6
Jiajia Xue, Jingwei Xie, Wenying Liu, Younan Xia
Electrospinning is a simple and versatile technique that relies on the electrostatic repulsion between surface charges to continuously draw nanofibers from a viscoelastic fluid. It has been applied to successfully produce nanofibers, with diameters down to tens of nanometers, from a rich variety of materials, including polymers, ceramics, small molecules, and their combinations. In addition to solid nanofibers with a smooth surface, electrospinning has also been adapted to generate nanofibers with a number of secondary structures, including those characterized by a porous, hollow, or core-sheath structure...
August 4, 2017: Accounts of Chemical Research
https://www.readbyqxmd.com/read/28776981/high-capacity-superior-cyclic-performances-in-all-solid-state-lithium-ion-batteries-based-on-78li2s-22p2s5-glass-ceramic-electrolytes-prepared-via-simple-heat-treatment
#7
Yibo Zhang, Rujun Chen, Ting Liu, Yang Shen, Yuanhua Lin, Ce-Wen Nan
Highly Li-ion conductive 78Li2S-22P2S5 glass-ceramic electrolytes were prepared by simple heat treatment of the glass phase obtained via mechanical ball milling. A high ionic conductivity of ∼1.78 × 10(-3) S cm(-1) is achieved at room temperature and is attributed to the formation of a crystalline phase of high lithium-ion conduction. All-solid-state lithium-ion batteries based on these glass-ceramic electrolytes are assembled by using Li2S nanoparticles or low-cost commercially available FeS2 as active cathode materials and Li-In alloys as anode...
August 16, 2017: ACS Applied Materials & Interfaces
https://www.readbyqxmd.com/read/28774090/assessment-of-effects-of-si-ca-p-biphasic-ceramic-on-the-osteogenic-differentiation-of-a-population-of-multipotent-adult-human-stem-cells
#8
Patricia Ros-Tárraga, Rubén Rabadan-Ros, Angel Murciano, Luis Meseguer-Olmo, Piedad N De Aza
A new type of bioceramic with osteogenic properties, suitable for hard tissue regeneration, was synthesised. The ceramic was designed and obtained in the Nurse's A-phase-silicocarnotite subsystem. The selected composition was that corresponding to the eutectoid 28.39 wt % Nurse's A-phase-71.61 wt % silicocarnotite invariant point. We report the effect of Nurse's A-phase-silicocarnotite ceramic on the capacity of multipotent adult human mesenchymal stem cells (ahMSCs) cultured under experimental conditions, known to adhere, proliferate and differentiate into osteoblast lineage cells...
November 29, 2016: Materials
https://www.readbyqxmd.com/read/28773196/surface-plasmon-resonance-or-biocompatibility-key-properties-for-determining-the-applicability-of-noble-metal-nanoparticles
#9
REVIEW
Ana Maria Craciun, Monica Focsan, Klara Magyari, Adriana Vulpoi, Zsolt Pap
Metal and in particular noble metal nanoparticles represent a very special class of materials which can be applied as prepared or as composite materials. In most of the cases, two main properties are exploited in a vast number of publications: biocompatibility and surface plasmon resonance (SPR). For instance, these two important properties are exploitable in plasmonic diagnostics, bioactive glasses/glass ceramics and catalysis. The most frequently applied noble metal nanoparticle that is universally applicable in all the previously mentioned research areas is gold, although in the case of bioactive glasses/glass ceramics, silver and copper nanoparticles are more frequently applied...
July 21, 2017: Materials
https://www.readbyqxmd.com/read/28773155/variation-of-structure-and-photoluminescence-properties-of-ce-3-doped-mgalon-transparent-ceramics-with-different-doping-content
#10
Xin Liu, Bowen Chen, Bingtian Tu, Hao Wang, Weimin Wang, Zhengyi Fu
Transparent MgAlON:Ce fluorescent ceramics with doping content of 0.005, 0.01, and 0.02 at % were fabricated by pressureless sintering. All the samples were dense and large in grain size. Under the excitation of 320 nm UV, the samples emitted blue lights centered around 410 nm. The 0.005 and 0.01 at % Ce(3+) doped samples were single phase by XRD detection, and possessed good optical and mechanical properties, and luminous thermal stability. The fluorescence lifetime, the CL and PL spectra analysis, indicated that most of the luminous centers were segregated in GB, and there was still a small part of second phase existing in 0...
July 13, 2017: Materials
https://www.readbyqxmd.com/read/28773116/zirconia-hydroxyapatite-composites-synthesized-via-sol-gel-influence-of-hydroxyapatite-content-and-heating-on-their-biological-properties
#11
Flavia Bollino, Emilia Armenia, Elisabetta Tranquillo
Zirconia (ZrO₂) and zirconia-based glasses and ceramics are materials proposed for use in the dental and orthopedic fields. In this work, ZrO₂ glass was modified by adding different amounts of bioactive and biocompatible hydroxyapatite (HAp). ZrO₂/HAp composites were synthesized via the sol-gel method and heated to different temperatures to induce modifications of their chemical structure, as ascertained by Fourier transform infrared spectroscopy (FTIR) analysis. The aim was to investigate the effect of both HAp content and heating on the biological performances of ZrO₂...
July 5, 2017: Materials
https://www.readbyqxmd.com/read/28773102/raman-and-photoemission-spectroscopic-analyses-of-explanted-biolox-%C3%A2-delta-femoral-heads-showing-metal-transfer
#12
Paola Taddei, Eleonora Pavoni, Saverio Affatato
Biolox(®) delta has been widely used in joint replacements thanks to its high strength and wear resistance. In this study, eleven Biolox(®) delta femoral head retrievals affected by metal transfer (MT) were analysed by Raman spectroscopy to estimate the tetragonal to monoclinic zirconia phase transformation, whose occurrence may compromise ceramic chemical stability and mechanical strength. The residual stress state was evaluated by both Raman and photoemission spectroscopy. Vm monoclinic zirconia contents were higher near the centre of the articulating surface and in the MT area than in the border control area of the retrievals...
July 3, 2017: Materials
https://www.readbyqxmd.com/read/28773095/in-vivo-damage-of-the-head-neck-junction-in-hard-on-hard-total-hip-replacements-effect-of-femoral-head-size-metal-combination-and-12-14-taper-design
#13
Massimiliano Baleani, Paolo Erani, Barbara Bordini, Federica Zuccheri, Mateusz Kordian Mąkosa, Dalila De Pasquale, Alina Beraudi, Susanna Stea
Recently, concerns have been raised about the potential effect of head-neck junction damage products at the local and systemic levels. Factors that may affect this damage process have not been fully established yet. This study investigated the possible correlations among head-neck junction damage level, implant design, material combination, and patient characteristics. Head-neck junctions of 148 retrieved implants were analysed, including both ceramic-on-ceramic (N = 61) and metal-on-metal (N = 87) bearings...
July 1, 2017: Materials
https://www.readbyqxmd.com/read/28773058/high-mobility-thin-film-transistors-based-on-amorphous-indium-zinc-tin-oxide
#14
Imas Noviyana, Annisa Dwi Lestari, Maryane Putri, Mi-Sook Won, Jong-Seong Bae, Young-Woo Heo, Hee Young Lee
Top-contact bottom-gate thin film transistors (TFTs) with zinc-rich indium zinc tin oxide (IZTO) active layer were prepared at room temperature by radio frequency magnetron sputtering. Sintered ceramic target was prepared and used for deposition from oxide powder mixture having the molar ratio of In2O3:ZnO:SnO2 = 2:5:1. Annealing treatment was carried out for as-deposited films at various temperatures to investigate its effect on TFT performances. It was found that annealing treatment at 350 °C for 30 min in air atmosphere yielded the best result, with the high field effect mobility value of 34 cm2/Vs and the minimum subthreshold swing value of 0...
June 26, 2017: Materials
https://www.readbyqxmd.com/read/28772833/effect-of-partial-crystallization-on-the-structural-and-luminescence-properties-of-er-3-doped-phosphate-glasses
#15
Pablo Lopez-Iscoa, Turkka Salminen, Teemu Hakkarainen, Laeticia Petit, Davide Janner, Nadia G Boetti, Mika Lastusaari, Diego Pugliese, Petriina Paturi, Daniel Milanese
Er-doped phosphate glass ceramics were fabricated by melt-quenching technique followed by a heat treatment. The effect of the crystallization on the structural and luminescence properties of phosphate glasses containing Al₂O₃, TiO₂, and ZnO was investigated. The morphological and structural properties of the glass ceramics were characterized by Field Emission-Scanning Electron Microscopy (FE-SEM), X-ray Diffraction (XRD), and micro-Raman spectroscopy. Additionally, the luminescence spectra and the lifetime values were measured in order to study the influence of the crystallization on the spectroscopic properties of the glasses...
April 28, 2017: Materials
https://www.readbyqxmd.com/read/28772783/the-in-vitro-bioactivity-degradation-and-cytotoxicity-of-polymer-derived-wollastonite-diopside-glass-ceramics
#16
Amanda De Castro Juraski, Andrea Cecilia Dorion Rodas, Hamada Elsayed, Enrico Bernardo, Viviane Oliveira Soares, Juliana Daguano
Ca-Mg silicates are receiving a growing interest in the field of bioceramics. In a previous study, wollastonite-diopside (WD) glass-ceramics were successfully prepared by a new processing route, consisting of the heat treatment of a silicone resin embedding reactive oxide particles and a Ca/Mg-rich glass. The in vitro degradation, bioactivity, and cell response of these new WD glass-ceramics, fired at 900-1100 °C for 1 h, as a function of the Ca/Mg-rich glass content, are the aim of this investigation The results showed that WD glass-ceramics from formulations comprising different glass contents (70-100% at 900 °C, 30% at 1100 °C) exhibit the formation of an apatite-like layer on their surface after immersion in SBF for seven days, thus confirming their surface bioactivity...
April 18, 2017: Materials
https://www.readbyqxmd.com/read/28772602/wear-behavior-of-ceramic-cad-cam-crowns-and-natural-antagonists
#17
Ella A Naumova, Stephan Schneider, Wolfgang H Arnold, Andree Piwowarczyk
OBJECTIVE: Evaluation of wear behavior of computer-aided design/computer-aided manufacturing (CAD/CAM) crowns from various restorative materials and natural antagonists. METHOD: Full CAD/CAM crowns fabricated with nanoceramic resin (Lava Ultimate (LU)), a glass ceramic in a resin interpenetrating matrix (Vita Enamic (VE)) and a lithium silicate reinforced ceramic enriched with zirconia (Vita Suprinity (VS)) were cemented on human molars. The crown and antagonists were subjected to simulated chewing...
February 28, 2017: Materials
https://www.readbyqxmd.com/read/28772508/shear-bond-strength-of-al%C3%A2-o%C3%A2-sandblasted-y-tzp-ceramic-to-the-orthodontic-metal-bracket
#18
Seon Mi Byeon, Min Ho Lee, Tae Sung Bae
As the proportion of adult orthodontic treatment increases, mainly for aesthetic reasons, orthodontic brackets are directly attached to yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) restorations. This, study analyzed the shear bond strength (SBS) between various surface treated Y-TZP and orthodontic metal brackets. The Y-TZP specimens were conditioned by 110 μm Al₂O₃ sandblasting, or sandblasting followed by coating with one of the primers (silane, MDP, or an MDP-containing silane primer). After surface treatment, the orthodontic metal bracket was bonded to the specimen using a resin cement, and then 24 h storage in water and thermal cycling (5000 cycles, 5-55 °C), SBS was measured...
February 9, 2017: Materials
https://www.readbyqxmd.com/read/28772412/biocompatibility-and-inflammatory-potential-of-titanium-alloys-cultivated-with-human-osteoblasts-fibroblasts-and-macrophages
#19
Jana Markhoff, Martin Krogull, Christian Schulze, Christian Rotsch, Sandra Hunger, Rainer Bader
The biomaterials used to maintain or replace functions in the human body consist mainly of metals, ceramics or polymers. In orthopedic surgery, metallic materials, especially titanium and its alloys, are the most common, due to their excellent mechanical properties, corrosion resistance, and biocompatibility. Aside from the established Ti6Al4V alloy, shape memory materials such as nickel-titanium (NiTi) have risen in importance, but are also discussed because of the adverse effects of nickel ions. These might be reduced by specific surface modifications...
January 10, 2017: Materials
https://www.readbyqxmd.com/read/28771428/a-novel-ceramic-tibial-component-is-as-safe-as-its-metal-counterpart
#20
Klemens Trieb
Failure rates of 2-10% provide evidence for further development in knee arthroplasty. The purpose of our study was to examine the safety of the tibial component of a novel all-ceramic total knee replacement (TKR) (BPK-S Integration ceramic) consisting of BIOLOX®delta ceramic. The standards ISO 14879-1 and ASTM F1800-07 describe the test set-up for the experimental strength verification with a significantly increased maximum load of 5300 N (900 N are required) and post-fatigue burst strength testing. All specimens were able to prove their mechanical strength against fracture in the alternating load test...
August 3, 2017: Biomedizinische Technik. Biomedical Engineering
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