keyword
https://read.qxmd.com/read/38607136/studying-the-structure-and-properties-of-epoxy-composites-modified-by-original-and-functionalized-with-hexamethylenediamine-by-electrochemically-synthesized-graphene-oxide
#21
JOURNAL ARTICLE
Anton Mostovoy, Amirbek Bekeshev, Sergey Brudnik, Andrey Yakovlev, Andrey Shcherbakov, Nurgul Zhanturina, Arai Zhumabekova, Elena Yakovleva, Vitaly Tseluikin, Marina Lopukhova
In this study, we used multilayer graphene oxide (GO) obtained by anodic oxidation of graphite powder in 83% sulfuric acid. The modification of GO was carried out by its interaction with hexamethylenediamine (HMDA) according to the mechanism of nucleophilic substitution between the amino group of HMDA (HMDA) and the epoxy groups of GO, accompanied by partial reduction of multilayer GO and an increase in the deformation of the carbon layers. The structure and properties of modified HMDA-GO were characterized using research methods such as scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy and Raman spectroscopy...
March 28, 2024: Nanomaterials
https://read.qxmd.com/read/38602421/tuning-surface-phase-and-magnetization-of-superparamagnetic-magnetite-by-ionic-liquids-single-step-microwave-assisted-synthesis
#22
JOURNAL ARTICLE
Eda Cagli, Aidan Klemm, Adam Ali, Zheng Gai, Kinga A Unocic, Michelle K Kidder, Burcu Gurkan
Achieving colloidal and chemical stability in ferrofluids by surface modification requires multiple steps, including purification, ex situ modification steps, and operation at high temperatures. In this study, a single-step microwave-assisted methodology is developed for iron oxide nanoparticle (IONP) synthesis utilizing a series of imidazolium-based ionic liquids (ILs) with chloride, bis(trifluoromethylsulfonyl)imide, and pyrrolide anions as the reaction media, thus eliminating the use of volatile organics while enabling rapid synthesis at 80 °C as well as in situ surface functionalization...
April 11, 2024: ACS Applied Materials & Interfaces
https://read.qxmd.com/read/38602034/jump-height-ingenerated-by-countermovement-and-arm-swing-better-correlates-with-proagility-shuttle-run-tests-but-not-with-change-of-direction-deficits-in-collegiate-female-athletes
#23
JOURNAL ARTICLE
Naoyuki Yamashita, Daisuke Sato, Takaaki Mishima
BACKGROUND: Jumping and linear sprinting performances show a moderate correlation with change of direction (COD) ability. However, the extent of these correlations remains unknown through statistical analysis. Thus, this study statistically compared correlation coefficients between COD, COD deficit (CODD), and jumping and linear sprint performances. METHODS: National-level basketball (29) and baseball (18) intercollegiate female athletes performed 20-m linear sprint, proagility (5-10-5) test, squat jump (SJ), countermovement jump with (CMJarm) and without (CMJ) arm swing and modified reactive strength index (RSImod)...
April 10, 2024: Journal of Sports Medicine and Physical Fitness
https://read.qxmd.com/read/38595643/the-importance-of-core-strength-for-change-of-direction-speed
#24
REVIEW
Henrieta Horníková, Erika Zemková
Change of direction speed (CODS) is determined by several physical aspects, such as linear sprint speed, reactive strength and power of leg muscles. It appears that core strength may also play a role in CODS, however, its relationship to CODS remains unclear. The aim of this narrative review was to analyze the literature addressing a) the relationship between core strength and CODS and b) the effect of core strength training on CODS. This analysis revealed a significant relationship between the parameters of core strength and stability (the pressure of the activated core muscles during lower limb movement and the greatest mean force output of maximum volunteered contraction) and the time in the Agility T-Test...
2024: Frontiers in Physiology
https://read.qxmd.com/read/38592515/compliant-iontronic-triboelectric-gels-with-phase-locked-structure-enabled-by-competitive-hydrogen-bonding
#25
JOURNAL ARTICLE
Guoli Du, Yuzheng Shao, Bin Luo, Tao Liu, Jiamin Zhao, Ying Qin, Jinlong Wang, Song Zhang, Mingchao Chi, Cong Gao, Yanhua Liu, Chenchen Cai, Shuangfei Wang, Shuangxi Nie
Rapid advancements in flexible electronics technology propel soft tactile sensing devices toward high-level biointegration, even attaining tactile perception capabilities surpassing human skin. However, the inherent mechanical mismatch resulting from deficient biomimetic mechanical properties of sensing materials poses a challenge to the application of wearable tactile sensing devices in human-machine interaction. Inspired by the innate biphasic structure of human subcutaneous tissue, this study discloses a skin-compliant wearable iontronic triboelectric gel via phase separation induced by competitive hydrogen bonding...
April 9, 2024: Nano-Micro Letters
https://read.qxmd.com/read/38591689/interfacial-exchange-dynamics-of-biomolecular-condensates-are-highly-sensitive-to-client-interactions
#26
JOURNAL ARTICLE
Ushnish Rana, Ned S Wingreen, Clifford P Brangwynne, Athanassios Z Panagiotopoulos
Phase separation of biomolecules can facilitate their spatiotemporally regulated self-assembly within living cells. Due to the selective yet dynamic exchange of biomolecules across condensate interfaces, condensates can function as reactive hubs by concentrating enzymatic components for faster kinetics. The principles governing this dynamic exchange between condensate phases, however, are poorly understood. In this work, we systematically investigate the influence of client-sticker interactions on the exchange dynamics of protein molecules across condensate interfaces...
April 14, 2024: Journal of Chemical Physics
https://read.qxmd.com/read/38591628/flame-retardant-and-transparent-unsaturated-polyester-based-on-p-n-liquid-flame-retardants-and-modified-halloysite-nanotubes
#27
JOURNAL ARTICLE
Yanli Dou, Aixun Ju, Zheng Zhong, Yutong Huo, Weiguo Yao
Unsaturated polyester resin (UPR) with excellent flame retardant is mainly obtained by adding large amounts of flame retardants, usually at the expense of mechanical properties. In this work, a reactive flame retardant containing phosphorus and nitrogen (DOPO-N) was successfully synthesized and incorporated in UPR as a crosslinker. The mechanical and flame-retardant properties of UPR composites were enhanced. UPR/30DOPO-N passed a UL-94 V-1 rating with a limiting oxygen index (LOI) of 30.8%. The tensile strength of UPR/30DOPO-N increased by 24...
February 5, 2024: Materials
https://read.qxmd.com/read/38591511/alkaline-activation-of-binders-a-comparative-study
#28
JOURNAL ARTICLE
Bianca Ignacio Almeida Alves, Markssuel Teixeira Marvila, José Alexandre Tostes Linhares Júnior, Carlos Maurício Fontes Vieira, Jonas Alexandre, Afonso Rangel Garcez de Azevedo
Binders formulated with activated alkali materials to replace Portland cement, which has high polluting potential due to CO2 emissions in its manufacture, have increasingly been developed. The objective of this study is to evaluate the main properties of activated alkali materials (AAM) produced by blast furnace slag, fly ash, and metakaolin. Initially, binders were characterized by their chemical, mineralogical and granulometric composition. Later, specimens were produced, with molarity variation between 4...
January 30, 2024: Materials
https://read.qxmd.com/read/38590296/starters-vs-non-starters-differences-in-vertical-jump-force-time-metrics-in-female-professional-volleyball-players
#29
JOURNAL ARTICLE
Damjana V Cabarkapa, Dimitrije Cabarkapa, Andrew C Fry
As one of the fundamental volleyball skills, countermovement vertical jump (CMJ) has been commonly implemented in the applied sports setting as a non-invasive and time-efficient assessment of athletes' lower-body neuromuscular function. The purpose of the present study was to examine the differences in CMJ characteristics between starters and non-starters within a cohort of professional female volleyball players. Nineteen athletes competing in one of the top European leagues (i.e., SuperLeague) volunteered to participate in the present investigation...
2024: Frontiers in sports and active living
https://read.qxmd.com/read/38586443/copolyester-toughened-poly-lactic-acid-biodegradable-material-prepared-by-in-situ-formation-of-polyethylene-glycol-and-citric-acid
#30
JOURNAL ARTICLE
Xipo Zhao, Peidong Li, Fan Mo, Yuejun Zhang, Zepeng Huang, Jiajie Yu, Ling Zhou, Siwen Bi, Shaoxian Peng
Polylactic acid (PLA) is a high-modulus, high-strength bio-based thermoplastic polyester with good biodegradability, which is currently a promising environmentally friendly material. However, its inherent brittleness has hindered its widespread use. In this study, we reported a simple and non-toxic strategy for toughening PLA, using biodegradable materials such as polyethylene glycol (PEG) and citric acid (CA) as precursors. Through reactive melt blending with PLA, PEG and CA form PEGCA copolyesters in situ during blending...
April 3, 2024: RSC Advances
https://read.qxmd.com/read/38585126/synthesis-and-properties-of-a-novel-reactive-and-low-migration-resistant-antioxidant-and-its-application-in-rubber-composites
#31
JOURNAL ARTICLE
Xiaonan Wang, Chaoying Sun, Liang He, Yi Liu, Qingwei Sun, Lan Dong, Runguo Wang
The addition of antioxidants to rubber is one of the most economical and effective methods for delaying rubber aging. However, antioxidant migration can cause environmental pollution. To address this issue, a new reactive antioxidant was synthesized via the chemical bonding of glycidyl methacrylate (GMA) and p -aminodiphenylamine (PPDA). The product was characterized by Fourier-transform infrared spectroscopy, which confirmed the successful reaction between GMA and PPDA, resulting in a compound with the expected structure...
April 2, 2024: ACS Omega
https://read.qxmd.com/read/38582031/predictors-of-elevated-c-reactive-protein-among-pre-treatment-newly-diagnosed-breast-cancer-patients-a-cross-sectional-study
#32
JOURNAL ARTICLE
Wai Han Ng, Zalina Abu Zaid, Barakatun Nisak Mohd Yusof, Syafinaz Amin Nordin, Poh Ying Lim
BACKGROUND & AIMS: Accumulating evidence showed that inflammation contributes markedly to cancer progression, with C-reactive protein (CRP) being one of the lengthily studied inflammation marker. For breast cancer (BCa), pre-treatment elevated CRP upon diagnosis was linked with increased mortality. This study aimed to identify factors predictive of elevated CRP in pre-treatment BCa population that can serve as potential therapeutic targets to reduce inflammation. METHODS: This is a cross-sectional study using multiple logistic regression to identify predictors of elevated CRP among pre-treatment, newly diagnosed BCa patients...
April 3, 2024: Cancer Treatment and Research Communications
https://read.qxmd.com/read/38581891/an-efficient-method-of-preparing-si-fe-al-ca-alloy-from-coal-gasification-fine-slag-via-plasma-smelting-and-alternating-current-magnetic-field
#33
JOURNAL ARTICLE
Yaoxuan Wang, Haiyu Li, Zhaoyang Zhang, Xiaolin Guo, Hongbing Du, Hong Wang, Yanxin Zhuang, Pengfei Xing
It is of great significance to solve the environmental problems caused by the unreasonable treatment of coal gasification slag. This study successfully produced Si-Fe-Al-Ca alloy from low-carbon fine slag with petroleum coke as reducing agent in a plasma furnace with an alternating current magnetic field, which solved the problem of the high reactivity requirement of carbon reductant for plasma smelting. The optimum carbon content of the mixed low-carbon fine slag and petroleum coke is 105% of the theoretical value...
April 5, 2024: Journal of Environmental Management
https://read.qxmd.com/read/38581407/binding-strengths-and-orientations-in-co-2-adsorption-on-cationic-scandium-oxides-governing-factor-revealed-by-a-combined-infrared-spectroscopy-and-theoretical-study
#34
JOURNAL ARTICLE
Pengcheng Liu, Jia Han, Yan Chen, Haili Yu, Xiaoguo Zhou, Weijun Zhang
Carbon dioxide (CO2 ) adsorption is a critical step to curbing carbon emissions from fossil fuel combustion. Among various options, transition metal oxides have received extensive attention as promising CO2 adsorbents due to their affordability and sustainability for large-scale use. Here, the nature of binding interactions between CO2 molecules and cationic scandium oxides of different sizes, i.e., ScO+ , Sc2 O2 + , and Sc3 O4 + , is investigated by mass-selective infrared photodissociation spectroscopy combined with quantum chemical calculations...
April 6, 2024: Journal of Physical Chemistry. A
https://read.qxmd.com/read/38581079/when-you-think-you-should-transfuse%C3%A2-don-t
#35
JOURNAL ARTICLE
Richard R Gammon, Harold Alvarez, Camila Masias, Nancy Benitez, Claribel Resto
A 48-year-old female presented to the emergency department with severe fatigue. Admission laboratory test results were hemoglobin 6.6 g/dL, platelet count 287,000/μL, and white blood cell count 25,200/μL. Lactate dehydrogenase was elevated at 898 U/L, haptoglobin was markedly decreased (< 31 mg/dL), indirect bilirubin was elevated (5.3 mg/dL), and the absolute reticulocyte count was low at 0.0050/μL. A sample was sent to the immunohematology reference laboratory. The direct antiglobulin test immunoglobulin G was negative; C3 was 1+...
April 6, 2024: Laboratory Medicine
https://read.qxmd.com/read/38580303/force-time-characteristics-of-repeated-bouts-of-depth-jumps-and-the-effects-of-compression-garments
#36
JOURNAL ARTICLE
Freddy Brown, Matt Hill, Derek Renshaw, Jason Tallis
No studies have reported ground reaction force (GRF) profiles of the repeated depth jump (DJ) protocols commonly used to study exercise-induced muscle damage. Furthermore, while compression garments (CG) may accelerate recovery from exercise-induced muscle damage, any effects on the repeated bout effect are unknown. Therefore, we investigated the GRF profiles of 2 repeated bouts of damage-inducing DJs and the effects of wearing CG for recovery. Nonresistance-trained males randomly received CG (n = 9) or placebo (n = 8) for 72 hours recovery, following 20 × 20 m sprints and 10 × 10 DJs from 0...
April 5, 2024: Journal of Applied Biomechanics
https://read.qxmd.com/read/38580020/enhanced-mechanical-and-long-lasting-antibacterial-properties-of-starch-pbat-blown-films-via-designing-of-reactive-micro-crosslinked-starch
#37
JOURNAL ARTICLE
Wenying Liu, Wenwen Yu, Jiaqi Wang, Jian Gao, Yi Ding, Sitong Zhang, Qiang Zheng
A functional starch (TPS-E) was designed and constructed by incorporating epoxy soybean oil (ESO) and an antibacterial agent polyhexamethylene guanidine hydrochloride (PHMG), then the film was prepared by reaction extrusion and blow molding using TPS-E and poly(butylene adipate-co-terephthalate) (PBAT). The micro-crosslinking structure, forming through ring-opening reaction between the epoxy active site of TPS-E and the end group of PBAT, improved the compatibility of starch/PBAT blend and reduce the dispersed starch phase size, leading to significantly increase the tensile strength...
April 3, 2024: International Journal of Biological Macromolecules
https://read.qxmd.com/read/38579644/polygonatum-sibiricum-polysaccharide-ameliorates-skeletal-muscle-aging-via-mitochondria-associated-membrane-mediated-calcium-homeostasis-regulation
#38
JOURNAL ARTICLE
Wenhao Chen, Zile Shen, Wenxi Dong, Guowei Huang, Dingye Yu, Weizhe Chen, Xialin Yan, Zhen Yu
BACKGROUND: Sarcopenia, an age-related disease, is characterized by a gradual loss of muscle mass, strength, and function. It has been linked to abnormal organelle function in myotubes, including the mitochondria and endoplasmic reticulum (ER). Recent studies revealed that mitochondria-associated membranes (MAM), the sites connecting mitochondria and the ER, may be implicated in skeletal muscle aging. In this arena, the potential of Polygonatum sibiricum polysaccharide (PSP) emerges as a beacon of hope...
March 24, 2024: Phytomedicine
https://read.qxmd.com/read/38567324/understanding-erosion-resistance-mechanisms-of-sodium-aluminate-silicate-hydrate-in-erosion-environments-a-molecular-dynamics-study
#39
JOURNAL ARTICLE
Qingyin Tang, Mengqi Sun, Xinghai Lu, Dongshuai Hou, Mengmeng Li, Pan Wang
Sodium-aluminate-silicate-hydrate (NASH) gel, as the primary reaction product stimulated by alkali in silica-aluminum-rich minerals, influences the mechanical and durability properties of geopolymers. In erosion environments, NASH demonstrates superior compressive strength and erosion resistance compared to hydration products of ordinary Portland cement. However, the underlying erosion resistance mechanism of NASH under such conditions remains unclear. Therefore, this study employs molecular dynamics research methodology to investigate the alteration in performance and deterioration mechanism of NASH in erosive environments...
March 26, 2024: RSC Advances
https://read.qxmd.com/read/38565082/reliability-in-novel-field-based-fitness-measurements-and-post-exercise-scores-from-a-physical-fitness-test-battery-in-older-adults
#40
JOURNAL ARTICLE
Manne Godhe, Gustaf Rönquist, Johnny Nilsson, Örjan Ekblom, Lillemor Nyberg, Gunnar Edman, Eva Andersson
INTRODUCTION: Physical fitness is strongly associated with daily physical function, health, and longevity in older adults. Field-based tests may provide a reasonable alternative compared to advanced laboratory testing. Separating post-exercise test-scores from reactivity measurements requires sufficient test-retest reliability. Post-exercise test-scores with reliability-analyses of field-based fitness-tests in older adults are lacking. The present study aimed to examine the test-retest-reliability of some novel easily accommodated fitness-test-measurements and compare pre-test scores with post-exercise results in these tests along with other field-based fitness tests in older adults...
April 2, 2024: Gerontology
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