Geochemistry, Geophysics, Geosystems : G³

Carbonate clumped isotope geochemistry has primarily focused on mass spectrometric determination of m/z 47 CO2 for geothermometry, but theoretical calculations and recent experiments indicate paired analysis of the m/z 47 (13 C18 O16 O) and m/z 48 (12 C18 O18 O) isotopologues (referred to as <mml:math xmlns:mml="https://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mtext>Δ</mml:mtext><mml:mrow><mml:mn>47</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math> and <mml:math xmlns:mml="https://www...

Tectonic pseudotachylytes are thought to be unique to certain water-deficient seismogenic environments and their presence is considered to be rare in the geological record. Here, we present field and experimental evidence that frictional melting can occur in hydrothermal fluid-rich faults hosted in the continental crust. Pseudotachylytes were found in the >40 km-long Bolfín Fault Zone of the Atacama Fault System, within two ca. 1 m-thick (ultra)cataclastic strands hosted in a damage-zone made of chlorite-epidote-rich hydrothermally altered tonalite...

Increased use and improved methodology of carbonate clumped isotope thermometry has greatly enhanced our ability to interrogate a suite of Earth-system processes. However, interlaboratory discrepancies in quantifying carbonate clumped isotope (Δ47 ) measurements persist, and their specific sources remain unclear. To address interlaboratory differences, we first provide consensus values from the clumped isotope community for four carbonate standards relative to heated and equilibrated gases with 1,819 individual analyses from 10 laboratories...

Micromagnetic tomography aims at reconstructing large numbers of individual magnetizations of magnetic particles from combining high-resolution magnetic scanning techniques with micro X-ray computed tomography (microCT). Previous work demonstrated that dipole moments can be robustly inferred, and mathematical analysis showed that the potential field of each particle is uniquely determined. Here, we describe a mathematical procedure to recover higher orders of the magnetic potential of the individual magnetic particles in terms of their spherical harmonic expansions (SHE)...

Fluid release from subducting oceanic lithosphere is a key process for subduction zone geodynamics, from controlling arc volcanism to seismicity and tectonic exhumation. However, many fundamental details of fluid composition, flow pathways, and reactivity with slab-forming rocks remain to be thoroughly understood. In this study we investigate a multi-kilometer-long, high-pressure metasomatic system preserved in the lawsonite-eclogite metamorphic unit of Alpine Corsica, France. The fluid-mediated process was localized along a major intra-slab interface, which is the contact between basement and cover unit...

The architecture and mechanical properties of the subduction interface impact large-scale subduction processes, including mass and volatile recycling, upper-plate orogenesis, and seismic behavior. The nature of the deep subduction interface, where a dominantly frictional megathrust likely transitions to a distributed ductile shear zone, is poorly understood, due to a lack of constraints on rock types, strain distribution, and interface thickness in this depth range. We characterized these factors in the Condrey Mountain Schist, a Late Jurassic to Early Cretaceous subduction complex in northern California that consists of an upper and lower unit...

Understanding the impact of earthquakes on subaqueous environments is key for submarine paleoseismological investigations seeking to provide long-term records of past earthquakes. For this purpose, event deposits (e.g., turbidites) are, among others, identified and stratigraphically correlated over broad areas to test for synchronous occurrence of gravity flows. Hence, detailed spatiotemporal petrographic and geochemical fingerprints of such deposits are required to advance the knowledge about sediment source and the underlying remobilization processes induced by past earthquakes...

International Ocean Discovery Program Expeditions 352 and 351 drilled into the Western Pacific Izu-Bonin forearc and rear arc. The drill cores revealed that the forearc is composed of forearc basalts (FAB) and boninites and the rear arc consists of FAB-like rocks. These rocks are pervaded by calcite veins. Blocky vein microtextures enclosing host rock fragments dominate in all locations and suggest hydrofracturing and advective fluid flow. Significant diffusion-fed and crystallization pressure-driven antitaxial veining is restricted to the rear arc...

The important role played by the upper plate in convergence zones dynamics has long been underestimated but is now more and more emphasized. However, the influence of its thickness and/or strength on orogenic systems evolution remains largely unknown. Here we present results from 3D thermo-mechanical numerical simulations of convergence zones (including oceanic subduction followed by continental subduction/collision), in which we vary the rheological profile of the overriding plate (OP). For this, we systematically modify the crustal thickness of the overriding lithosphere and the temperature at the Moho to obtain a thermal thickness of the overriding lithosphere ranging from 80 to 180 km...

Calcite veins hosted in pillow lavas of the Late Cretaceous Troodos suprasubduction zone ophiolite provide insights into the timing and physicochemical environment of postmagmatic fracturing and fluid circulation through oceanic crust. This study presents rare earth element and yttrium (REE+Y) concentrations, δ13 C, δ18 O, 87 Sr/86 Sr, and clumped isotopic (Δ47 ) compositions of vein calcites in order to investigate their fluid sources, formation temperatures, and precipitation ages. These geochemical data are combined with microtextural analyses...

International Ocean Discovery Program Expedition 352 recovered sedimentary-volcaniclastic successions and extensional structures (faults and extensional veins) that allow the reconstruction of the Izu-Bonin forearc tectonic evolution using a combination of shipboard core data, seismic reflection images, and calcite vein microstructure analysis. The oldest recorded biostratigraphic ages within fault-bounded sedimentary basins (Late Eocene to Early Oligocene) imply a ~15 Ma hiatus between the formation of the igneous basement (52 to 50 Ma) and the onset of sedimentation...

During continental collision, considerable amounts of buoyant continental crust subduct to depth and subsequently exhume. Whether various exhumation paths contribute to contrasting styles of magmatism across modern collision zones is unclear. Here we present 2D thermomechanical models of continental collision combined with petrological databases to investigate the effect of the main contrasting buoyancy forces, in the form of continental crustal buoyancy versus oceanic slab age (i.e., its thickness). We specifically focus on the consequences for crustal exhumation mechanisms and magmatism...

Anhydrous phase B and stishovite formed directly from olivine in experiments at 14 GPa and 1400 °CThe structure of anhydrous phase B is determined ab initio from precession electron diffraction tomography in transmission electron microscopyElastic and seismic properties of anhydrous phase B are calculated.

The flanks of the ultraslow-spreading Mid-Cayman Spreading Center (MCSC) are characterized by domal massifs or oceanic core complexes (OCCs). The most prominent of these, Mount Dent, comprises lower-crustal and upper-mantle lithologies and hosts the Von Damm vent field ~12 km west of the axial deep. Here, presented autonomous underwater vehicle-derived swath sonar (multibeam) mapping and deep-towed side-scan sonar imagery lead to our interpretation that: (i) slip along the OCC-bounding detachment fault is ceasing, (ii) the termination zone, where detachment fault meets the hanging wall, is disintegrating, (iii) the domed surface of the OCC is cut by steep north-south extensional faulting, and (iv) the breakaway zone is cut by outward facing faults...

Halogens are primarily located within surface reservoirs of the Earth; as such they have proven to be effective tracers for the identification of subducted volatiles within the mantle. Subducting lithologies exhibit a wide variety of halogen compositions, yet the mantle maintains a fairly uniform signature, suggesting halogens may be homogenized during subduction to the mantle or during eruption. Here we present halogen (Cl, Br, and I), K, noble gas, and major and trace element data on olivines from three seamounts along the Hawaiian-Emperor seamount chain to determine if the deep mantle source has retained evidence of halogen heterogeneities introduced through subduction...

The Izu-Bonin-Mariana (IBM) fore arc preserves igneous rock assemblages that formed during subduction initiation circa 52 Ma. International Ocean Discovery Program (IODP) Expedition 352 cored four sites in the fore arc near the Ogasawara Plateau in order to document the magmatic response to subduction initiation and the physical, petrologic, and chemical stratigraphy of a nascent subduction zone. Two of these sites (U1440 and U1441) are underlain by fore-arc basalt (FAB). FABs have mid-ocean ridge basalt (MORB)-like compositions, however, FAB are consistently lower in the high-field strength elements (TiO2 , P2 O5 , Zr) and Ni compared to MORB, with Na2 O at the low end of the MORB field and FeO* at the high end...

The observed variability of trace-element concentration in basaltic lavas and melt inclusions carries information about heterogeneity in the mantle. The difficulty is to disentangle the contributions of source heterogeneity (i.e., spatial variability of mantle composition before melting) and process heterogeneity (i.e., spatial and temporal variability in melt transport). Here we investigate the end-member hypothesis that variability arises due to source heterogeneity alone. We model the attenuation of trace-element variability introduced into the bottom of a one-dimensional, steady-state melting column...

Sampling of sediment cores using plastic U-channels has made possible the acquisition of detailed records of paleomagnetic secular variation, geomagnetic polarity, environmental magnetic studies, and relative paleointensity over the past several million years. U-channel measurements provide the great advantage of rapid measurements of long sediment cores, but the signal resolution is attenuated by the response function of the magnetometer sensors, which therefore restrains the recovery of rapid and large-amplitude field changes...

In seismic tomography we map the wave speed structure inside the Earth, but we ultimately seek to interpret those images in terms of physical parameters. This is challenging because many parameters can trade-off with each other to produce a given wave speed. The problem is compounded by the convention of mapping seismic structures as perturbations relative to a 1-D reference model, rather than absolute wave speeds. Using a full waveform tomography model of Europe as a case study, we quantify the extent to which thermochemical and dynamic properties can be constrained using only S wave speed, expressed in absolute values...

Imaging the lithosphere is key to understand mechanisms of extension as rifting progresses. Continental rifting results in a combination of mechanical stretching and thinning of the lithosphere, decompression upwelling, heating, sometimes partial melting of the asthenosphere, and potentially partial melting of the mantle lithosphere. The northern East African Rift system is an ideal locale to study these processes as it exposes the transition from tectonically active continental rifting to incipient seafloor spreading...