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Beilstein Journal of Nanotechnology

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https://www.readbyqxmd.com/read/28503401/bio-inspired-micro-to-nanoporous-polymers-with-tunable-stiffness
#1
Julia Syurik, Ruth Schwaiger, Prerna Sudera, Stephan Weyand, Siegbert Johnsen, Gabriele Wiegand, Hendrik Hölscher
Background: Inspired by structural hierarchies and the related excellent mechanical properties of biological materials, we created a smoothly graded micro- to nanoporous structure from a thermoplastic polymer. Results: The viscoelastic properties for the different pore sizes were investigated in the glassy regime by dynamic flat-punch indentation. Interestingly, the storage modulus was observed to increase with increasing pore-area fraction. Conclusion: This outcome appears counterintuitive at first sight, but can be rationalized by an increase of the pore wall thickness as determined by our quantitative analysis of the pore structure...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503400/triptycene-terminated-thiolate-and-selenolate-monolayers-on-au-111
#2
Jinxuan Liu, Martin Kind, Björn Schüpbach, Daniel Käfer, Stefanie Winkler, Wenhua Zhang, Andreas Terfort, Christof Wöll
To study the implications of highly space-demanding organic moieties on the properties of self-assembled monolayers (SAMs), triptycyl thiolates and selenolates with and without methylene spacers on Au(111) surfaces were comprehensively studied using ultra-high vacuum infrared reflection absorption spectroscopy, X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy and thermal desorption spectroscopy. Due to packing effects, the molecules in all monolayers are substantially tilted...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503399/functional-dependence-of-resonant-harmonics-on-nanomechanical-parameters-in-dynamic-mode-atomic-force-microscopy
#3
Federico Gramazio, Matteo Lorenzoni, Francesc Pérez-Murano, Enrique Rull Trinidad, Urs Staufer, Jordi Fraxedas
We present a combined theoretical and experimental study of the dependence of resonant higher harmonics of rectangular cantilevers of an atomic force microscope (AFM) as a function of relevant parameters such as the cantilever force constant, tip radius and free oscillation amplitude as well as the stiffness of the sample's surface. The simulations reveal a universal functional dependence of the amplitude of the 6th harmonic (in resonance with the 2nd flexural mode) on these parameters, which can be expressed in terms of a gun-shaped function...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503398/synthesis-of-coaxial-nanotubes-of-polyaniline-and-poly-hydroxyethyl-methacrylate-by-oxidative-initiated-chemical-vapor-deposition
#4
Alper Balkan, Efe Armagan, Gozde Ozaydin Ince
Vapor-phase synthesis techniques of polymeric nanostructures offer unique advantages over conventional, solution-based techniques because of their solventless nature. In this work, we report the fabrication of coaxial polymer nanotubes using two different chemical vapor deposition methods. The fabrication process involves the deposition of an outer layer of the conductive polyaniline (PANI) by oxidative chemical vapor deposition, followed by the deposition of the inner layer of poly(2-hydroxyethyl methacrylate) (pHEMA) hydrogel by initiated chemical vapor deposition...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503397/relationships-between-chemical-structure-mechanical-properties-and-materials-processing-in-nanopatterned-organosilicate-fins
#5
Gheorghe Stan, Richard S Gates, Qichi Hu, Kevin Kjoller, Craig Prater, Kanwal Jit Singh, Ebony Mays, Sean W King
The exploitation of nanoscale size effects to create new nanostructured materials necessitates the development of an understanding of relationships between molecular structure, physical properties and material processing at the nanoscale. Numerous metrologies capable of thermal, mechanical, and electrical characterization at the nanoscale have been demonstrated over the past two decades. However, the ability to perform nanoscale molecular/chemical structure characterization has only been recently demonstrated with the advent of atomic-force-microscopy-based infrared spectroscopy (AFM-IR) and related techniques...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503396/hybrid-nanomaterials-from-the-laboratory-to-the-market
#6
EDITORIAL
Verónica de Zea Bermudez, Fabrice Leroux, Pierre Rabu, Andreas Taubert
No abstract text is available yet for this article.
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503395/the-role-of-2d-3d-spin-polarization-interactions-in-hybrid-copper-hydroxide-acetate-new-insights-from-first-principles-molecular-dynamics
#7
Ziyad Chaker, Guido Ori, Mauro Boero, Carlo Massobrio
The magnetic properties response of the layered hybrid material copper hydroxide acetate Cu2(OH)3CH3COO·H2O is studied as a function of the applied pressure within first-principles molecular dynamics. We are able to elucidate the interplay between the structural properties of this material and its magnetic character, both at the local (atomic) level and at the bulk level. We performed a detailed analysis of the intralayer spin configurations occurring for each value of the imposed projection along the z-axis for the total spin and of the applied pressure...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503394/investigation-of-growth-dynamics-of-carbon-nanotubes
#8
REVIEW
Marianna V Kharlamova
The synthesis of single-walled carbon nanotubes (SWCNTs) with defined properties is required for both fundamental investigations and practical applications. The revealing and thorough understanding of the growth mechanism of SWCNTs is the key to the synthesis of nanotubes with required properties. This paper reviews the current status of the research on the investigation of growth dynamics of carbon nanotubes. The review starts with the consideration of the peculiarities of the growth mechanism of carbon nanotubes...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28503393/measuring-adhesion-on-rough-surfaces-using-atomic-force-microscopy-with-a-liquid-probe
#9
Juan V Escobar, Cristina Garza, Rolando Castillo
We present a procedure to perform and interpret pull-off force measurements during the jump-off-contact process between a liquid drop and rough surfaces using a conventional atomic force microscope. In this method, a micrometric liquid mercury drop is attached to an AFM tipless cantilever to measure the force required to pull this drop off a rough surface. We test the method with two surfaces: a square array of nanometer-sized peaks commonly used for the determination of AFM tip sharpness and a multi-scaled rough diamond surface containing sub-micrometer protrusions...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487823/3d-nanoprinting-via-laser-assisted-electron-beam-induced-deposition-growth-kinetics-enhanced-purity-and-electrical-resistivity
#10
Brett B Lewis, Robert Winkler, Xiahan Sang, Pushpa R Pudasaini, Michael G Stanford, Harald Plank, Raymond R Unocic, Jason D Fowlkes, Philip D Rack
We investigate the growth, purity, grain structure/morphology, and electrical resistivity of 3D platinum nanowires synthesized via electron beam induced deposition with and without an in situ pulsed laser assist process which photothermally couples to the growing Pt-C deposits. Notably, we demonstrate: 1) higher platinum concentration and a coalescence of the otherwise Pt-C nanogranular material, 2) a slight enhancement in the deposit resolution and 3) a 100-fold improvement in the conductivity of suspended nanowires grown with the in situ photothermal assist process, while retaining a high degree of shape fidelity...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487822/probing-the-magnetic-superexchange-couplings-between-terminal-cu-ii-ions-in-heterotrinuclear-bis-oxamidato-type-complexes
#11
Mohammad A Abdulmalic, Saddam Weheabby, Francois E Meva, Azar Aliabadi, Vladislav Kataev, Bernd Büchner, Frederik Schleife, Berthold Kersting, Tobias Rüffer
The reaction of one equivalent of [n-Bu4N]2[Ni(opboR2)] with two equivalents of [Cu(pmdta)(X)2] afforded the heterotrinuclear Cu(II)Ni(II)Cu(II) containing bis(oxamidato) type complexes [Cu2Ni(opboR2)(pmdta)2]X2 (R = Me, X = NO3(-) (1); R = Et, X = ClO4(-) (2); R = n-Pr, X = NO3(-) (3); opboR2 = o-phenylenebis(NR-substituted oxamidato); pmdta = N,N,N',N",N"-pentamethyldiethylenetriamine). The identities of the heterotrinuclear complexes 1-3 were established by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction studies, which revealed the cationic complex fragments [Cu2Ni(opboR2)(pmdta)2](2+) as not involved in any further intermolecular interactions...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487821/surface-improvement-of-organic-photoresists-using-a-near-field-dependent-etching-method
#12
Felix J Brandenburg, Tomohiro Okamoto, Hiroshi Saito, Benjamin Leuschel, Olivier Soppera, Takashi Yatsui
Surface flattening techniques are extremely important for the development of future electrical and/or optical devices because carrier-scattering losses due to surface roughness severely limit the performance of nanoscale devices. To address the problem, we have developed a near-field etching technique that provides selective etching of surface protrusions, resulting in an atomically flat surface. To achieve finer control, we examine the importance of the wavelength of the near-field etching laser. Using light sources at wavelengths of 325 and 405 nm, which are beyond the absorption edge of the photoresist (310 nm), we compare the resulting cross-sectional etching volumes...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487820/recombinant-dna-technology-and-click-chemistry-a-powerful-combination-for-generating-a-hybrid-elastin-like-statherin-hydrogel-to-control-calcium-phosphate-mineralization
#13
Mohamed Hamed Misbah, Mercedes Santos, Luis Quintanilla, Christina Günter, Matilde Alonso, Andreas Taubert, José Carlos Rodríguez-Cabello
Understanding the mechanisms responsible for generating different phases and morphologies of calcium phosphate by elastin-like recombinamers is supreme for bioengineering of advanced multifunctional materials. The generation of such multifunctional hybrid materials depends on the properties of their counterparts and the way in which they are assembled. The success of this assembly depends on the different approaches used, such as recombinant DNA technology and click chemistry. In the present work, an elastin-like recombinamer bearing lysine amino acids distributed along the recombinamer chain has been cross-linked via Huisgen [2 + 3] cycloaddition...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487819/selective-detection-of-mg-2-ions-via-enhanced-fluorescence-emission-using-au-dna-nanocomposites
#14
Tanushree Basu, Khyati Rana, Niranjan Das, Bonamali Pal
The biophysical properties of DNA-modified Au nanoparticles (AuNPs) have attracted a great deal of research interest for various applications in biosensing. AuNPs have strong binding capability to the phosphate and sugar groups in DNA, rendering unique physicochemical properties for detection of metal ions. The formation of Au-DNA nanocomposites is evident from the observed changes in the optical absorption, plasmon band, zeta potential, DLS particle size distribution, as well as TEM and AFM surface morphology analysis...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487818/modeling-adsorption-of-brominated-chlorinated-and-mixed-bromo-chloro-dibenzo-p-dioxins-on-c60-fullerene-using-nano-qspr
#15
Piotr Urbaszek, Agnieszka Gajewicz, Celina Sikorska, Maciej Haranczyk, Tomasz Puzyn
Many technological implementations in the field of nanotechnology have involved carbon nanomaterials, including fullerenes such as the buckminsterfullerene, C60. The unprecedented properties of such organic nanomaterials (in particular their large surface area) gained extensive attention for their potential use as organic pollutant sorbents. Sorption interactions can be very hazardous and useful at the same time. This work investigates the influence of halogenation by bromine and/or chlorine in dibenzo-p-dioxins on their sorption ability on the C60 fullerene surface...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487817/first-examples-of-organosilica-based-ionogels-synthesis-and-electrochemical-behavior
#16
Andreas Taubert, Ruben Löbbicke, Barbara Kirchner, Fabrice Leroux
The article describes the synthesis and properties of new ionogels for ion transport. A new preparation process using an organic linker, bis(3-(trimethoxysilyl)propyl)amine (BTMSPA), yields stable organosilica matrix materials. The second ionogel component, the ionic liquid 1-methyl-3-(4-sulfobutyl)imidazolium 4-methylbenzenesulfonate, [BmimSO3H][PTS], can easily be prepared with near-quantitative yields. [BmimSO3H][PTS] is the proton conducting species in the ionogel. By combining the stable organosilica matrix with the sulfonated ionic liquid, mechanically stable, and highly conductive ionogels with application potential in sensors or fuel cells can be prepared...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487816/vapor-deposition-routes-to-conformal-polymer-thin-films
#17
REVIEW
Priya Moni, Ahmed Al-Obeidi, Karen K Gleason
Vapor phase syntheses, including parylene chemical vapor deposition (CVD) and initiated CVD, enable the deposition of conformal polymer thin films to benefit a diverse array of applications. This short review for nanotechnologists, including those new to vapor deposition methods, covers the basic theory in designing a conformal polymer film vapor deposition, sample preparation and imaging techniques to assess film conformality, and several applications that have benefited from vapor deposited, conformal polymer thin films...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28487815/phospholipid-arrays-on-porous-polymer-coatings-generated-by-micro-contact-spotting
#18
Sylwia Sekula-Neuner, Monica de Freitas, Lea-Marie Tröster, Tobias Jochum, Pavel A Levkin, Michael Hirtz, Harald Fuchs
Nanoporous poly(2-hydroxyethyl methacrylate-co-ethylene dimethacrylate) (HEMA-EDMA) is used as a 3D mesh for spotting lipid arrays. Its porous structure is an ideal matrix for lipid ink to infiltrate, resulting in higher fluorescent signal intensity as compared to similar arrays on strictly 2D substrates like glass. The embedded lipid arrays show high stability against washing steps, while still being accessible for protein and antibody binding. To characterize binding to polymer-embedded lipids we have applied Streptavidin as well as biologically important biotinylated androgen receptor binding onto 1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine-N-(cap biotinyl) (Biotinyl Cap PE) and anti-DNP IgE recognition of 2,4-dinitrophenyl[1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine-N-[6-[(2,4-dinitrophenyl)amino]hexanoyl] (DNP)] antigen...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28462071/synthesis-of-graphene-transition-metal-oxide-hybrid-nanoparticles-and-their-application-in-various-fields
#19
REVIEW
Arpita Jana, Elke Scheer, Sebastian Polarz
Single layer graphite, known as graphene, is an important material because of its unique two-dimensional structure, high conductivity, excellent electron mobility and high surface area. To explore the more prospective properties of graphene, graphene hybrids have been synthesised, where graphene has been integrated with other important nanoparticles (NPs). These graphene-NP hybrid structures are particularly interesting because after hybridisation they not only display the individual properties of graphene and the NPs, but also they exhibit further synergistic properties...
2017: Beilstein Journal of Nanotechnology
https://www.readbyqxmd.com/read/28462070/ion-beam-profiling-from-the-interaction-with-a-freestanding-2d-layer
#20
Ivan Shorubalko, Kyoungjun Choi, Michael Stiefel, Hyung Gyu Park
Recent years have seen a great potential of the focused ion beam (FIB) technology for the nanometer-scale patterning of a freestanding two-dimensional (2D) layer. Experimentally determined sputtering yields of the perforation process can be quantitatively explained using the binary collision theory. The main peculiarity of the interaction between the ion beams and the suspended 2D material lies in the absence of collision cascades, featured by no interaction volume. Thus, the patterning resolution is directly set by the beam diameters...
2017: Beilstein Journal of Nanotechnology
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