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Journal of Oleo Science

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https://www.readbyqxmd.com/read/28701656/pedologic-factors-affecting-virgin-olive-oil-quality-of-chemlali-olive-trees-olea-europaea-l
#1
Mouna Ben Rached, Gianni Galaverna, Martina Cirlini, Dalenda Boujneh, Mokhtar Zarrouk, Mokhtar Guerfel
The aim of this study examined the characterization of extra virgin olive oil samples from the main cultivar Chemlali, grown in five olive orchards with different soil type (Sandy, Clay, Stony, Brown, Limestone and Gypsum). Volatile compounds were studied using headspace-solid phase micro-extraction (HS-SPME) and gas chromatography-mass spectrometry (GC-MS) technics. Moreover, the sterol profile was established using gas chromatography-mass spectrometry. 35 different volatile compounds were identified: alcohols, esters, aldehydes, ketones and hydrocarbons...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701655/preventive-effects-of-the-dietary-intake-of-medium-chain-triacylglycerols-on-immobilization-induced-muscle-atrophy-in-rats
#2
Shuhei Nishimura, Makoto Inai, Tetsuo Takagi, Yudai Nonaka, Shogo Urashima, Kazumitsu Honda, Toshiaki Aoyama, Shin Terada
Previous studies have shown that medium-chain triacylglycerols (MCTs) exert favorable effects on protein metabolism. This study evaluated the effects of the dietary intake of MCTs on rat skeletal muscle mass and total protein content during casting-induced hindlimb immobilization, which causes substantial protein degradation and muscle atrophy. Rats were fed a standard diet containing long-chain triacylglycerols (LCTs) or MCTs for 3 days and then a unilateral hindlimb was immobilized while they received the same diet...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701654/volatile-compounds-from-the-different-organs-of-houttuynia-cordata-and-litsea-cubeba-l-citriodora
#3
Yoshinori Asakawa, Kenichi Tomiyama, Kazutoshi Sakurai, Yukihiro Kawakami, Yoshihiro Yaguchi
The volatile compounds obtained from the different organs of Houttuynia cordata (Saururaceae) and Litsea cubeba (Lauraceae) were analyzed by Gas Chromatography/Mass Spectrometry (GC/MS), Headspace Solid Phase Micro Extraction-Gas Chromatography/Mass Spectrometry (HS-SPME-GC/MS), and GC/olfactometry (GC/O). The major component of all parts of H. cordata is assigned as 4-tridecanone. Each organ produces myrcene as the major monoterpenoid. The major monoterpene in the rhizomes and roots was β-pinene instead of myrcene...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701653/comparative-study-on-volatile-compounds-of-alpinia-japonica-and-elettaria-cardamomum
#4
Yoshinori Asakawa, Agnieszka Ludwiczuk, Kazutoshi Sakurai, Kenichi Tomiyama, Yukihiro Kawakami, Yoshihiro Yaguchi
The volatile compounds obtained from the ether extracts, headspace gases and steam distillates of Alpinia japonica and Elettaria cardamomum were analyzed by GC/MS. Both species were rich sources of naturally rare fenchane-type monoterpenoids, fenchene, fenchone, fenchyl alcohol and its acetate, together with 1,8-cineole. The distributions of volatile sesquiterpenoids were very poor in both species. Chiralities of fenchone in A. japonica and E. cardamomum were 99% of (1S,4R)-(+)-form. Camphor in A. japonica is composed of a mixture of (1R,4R)-(+)-form (94...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701652/electrochemical-synthesis-of-dihydrobenzofurans-and-evaluation-of-their-insect-antifeedant-activities
#5
Masanori Morimoto, Masamitsu Urakawa, Koichiro Komai
Electrochemically synthesized dihydrobenzofurans were evaluated for their insect antifeedant activities against phytophagous insects. They were prepared through the coupling reactions of various alkenes with a phenoxy cation generated by oxidation near the cathode in the electrolytic reaction. The insect antifeedant activities of these synthetic dihydrobenzofurans were evaluated in the common cutworm (Spodoptera litura) and diamond back moth (Plutella xylostella) with the dual choice leaf disk bioassay method...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701651/biotransformation-of-1r-4s-menthone-and-1s-4r-menthone-by-the-common-cutworm-spodoptera-litura-larvae
#6
Shinsuke Marumoto, Yoshiharu Okuno, Yuki Hagiwara, Mitsuo Miyazawa
Using biotransformation as a biocatalytic process has the advantage of being able to proceed under mild conditions and with high regio- and enantioselectivity. This study investigated the biotransformation of (-)-(1R,4S)-menthone (1) and (+)-(1S,4R)-menthone (2) by Spodoptera litura larvae. Compound 1 was converted to (-)-(1R,4S)-7-hydroxymenthone (1-1), (+)-(1R,3S,4S)-7-hydroxyneomenthol (1-2) and (-)-(1R,4S,8R)-p-menth-3-one-9-oic acid (1-3). The metabolism of substrate 2 generated three enantiomers of the above metabolites, designated as 2-1 to 2-3, respectively...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701650/characteristic-changes-in-the-aroma-profile-of-patchouli-depending-on-manufacturing-process
#7
Toshio Hasegawa, Kazuma Yoshitome, Takashi Fujihara, Mardi Santoso, Muhammad Abdul Aziz
Patchouli is used as an incense material and essential oil. The characteristic odor of patchouli leaves results from the drying process used in their production; however, there have to date been no reports on the changes in the odor of patchouli leaves during the drying process. We investigated the aroma profile of dried patchouli leaves using the hexane extracts of fresh and dried patchouli leaves. We focused on the presence or absence of the constituents of the fresh and dried extracts, and the differences in the content of the common constituents...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28701649/deodorizing-substance-in-black-cumin-nigella-sativa-l-seed-oil
#8
Toru Nakasugi, Takushi Murakawa, Koji Shibuya, Masanori Morimoto
A deodorizing substance in black cumin (Nigella sativa L.), a spice for curry and vegetable foods in Southwest Asia, was examined. The essential oil prepared from the seeds of this plant exhibited strong deodorizing activity against methyl mercaptan, which is a main factor in oral malodor. After purification with silica gel column chromatography, the active substance in black cumin seed oil was identified as thymoquinone. This monoterpenic quinone functions as the main deodorizing substance in this oil against methyl mercaptan...
July 12, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626144/glass-bead-based-genetic-transformation-an-efficient-method-for-transformation-of-thraustochytrid-microorganisms
#9
Takumi Adachi, Takehiko Sahara, Hidetoshi Okuyama, Naoki Morita
Here, we describe a new method for genetic transformation of thraustochytrids, well-known producers of polyunsaturated fatty acids (PUFAs) like docosahexaenoic acid, by combining mild glass (zirconia) bead treatment and electroporation. Because the cell wall is a barrier against transfer of exogenous DNA into cells, gentle vortexing of cells with glass beads was performed prior to electroporation for partial cell wall disruption. G418-resistant transformants of thraustochytrid cells (Aurantiochytrium limacinum strain SR21 and thraustochytrid strain 12B) were successfully obtained with good reproducibility...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626143/effect-of-conjugated-linoleic-acid-intake-on-endurance-exercise-performance-and-anti-fatigue-in-student-athletes
#10
Naoko Terasawa, Ken Okamoto, Kenta Nakada, Kazumi Masuda
Conjugated linoleic acids (CLA) intake has been reported to reduce body fat mass or increase lean body mass and to improve exercise outcome by modulating testosterone in humans. These reports have studied mostly overweight subjects; few were athletes. Therefore, in this study, the effect of CLA intake on endurance performance and anti-fatigue in student athletes was investigated. A double-blind, crossover study was conducted with 10 male student athletes. Each subject was administered with either CLA (net 0...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626142/surface-modification-of-pdms-and-plastics-with-zwitterionic-polymers
#11
Mutsuo Tanaka, Shigeru Kurosawa
Surface modification of PDMS, polycarbonate, and acrylic resin was examined using various methacryl polymers bearing sulfobetaine, phosphoryl choline, and oligoethylene glycol units. We have found that zwitterionic polymers are adsorbed on the PDMS surface treated with plasma. The surface of PDMS is stable to keep high hydrophilicity after a month of the modification. On the other hand, one of sulfobetaine polymers showed distinguished adsorption behavior in the case of polycarbonate surface treated with plasma...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626141/dietary-starfish-oil-prevents-hepatic-steatosis-and-hyperlipidemia-in-c57bl-6n-mice-fed-high-fat-diet
#12
Fumiaki Beppu, Haoqi Li, Kazuaki Yoshinaga, Toshiharu Nagai, Akihiko Yoshinda, Atsushi Kubo, Jota Kanda, Naohiro Gotoh
Starfish oil (SO) is characterized by functional lipids, including n-3 polyunsaturated fatty acid (both in the form of triacylglycerol and in the form of phospholipid), and carotenoids, which may exert beneficial effects on metabolic disorders in obesity-associated diseases. In the present study, the effect of SO on dysregulation of lipid metabolism was examined using C57BL/6N mice treated with high-fat (HF) diet. Mice were fed HF, HF with 2% SO, or HF with 5% SO diet for 8 weeks. Weight gain, blood glucose, serum and hepatic lipid contents, and hepatic fatty acid composition were measured...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626140/long-chain-polyunsaturated-fatty-acid-supplementation-improves-mood-in-elderly-japanese-men
#13
Hisanori Tokuda, Toshiaki Sueyasu, Hiroshi Kawashima, Hiroshi Shibata, Yoshihiko Koga
Although several studies have reported the effects of long-chain polyunsaturated fatty acid (LCPUFA) supplementation on the mood in healthy adults, the effects of LCPUFA on elderly individuals remain unclear. Thus, we hypothesized that LCPUFA supplementation improves mood in the elderly. To address this hypothesis, 115 elderly Japanese men aged 55-64 years were assigned and randomly allocated to the LCPUFA or placebo group. Participants received 4 weeks of supplementation with LCPUFAcontaining oil (docosahexaenoic acid (DHA) 300 mg/day, eicosapentaenoic acid (EPA) 100 mg/day, arachidonic acid (ARA) 120 mg/day) or a placebo oil...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626139/synthesis-of-ricinoleic-acid-estolides-by-the-esterification-of-ricinoleic-acids-using-functional-acid-ionic-liquids-as-catalysts
#14
Gaoshang Wang, Shangde Sun
Estolides of ricinoleic acid (RA) have been used as lubricants and pigment dispersant in many industries. In this paper, functional acid ionic liquids (ILs) were firstly used as catalysts to prepare RA estolides by the esterification of RAs in solvent-free system. Different ILs were used as catalysts for the esterification. Effect of reaction variables (IL amount, reaction temperature and reaction time) on the esterification were also investigated and optimized using response surface methodology (RSM). Among all tested ILs, [BSO3HMIM]TS showed the best performance for the esterification...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626138/evaluation-of-sorption-mechanism-of-pb-ii-andni-ii-onto-pea-pisum-sativum-peels
#15
Atta Ul Haq, Muhammad Saeed, Salma Anjum, Tanveer Hussain Bokhari, Muhammad Usman, Saiqa Tubbsum
The present study was carried out to know the sorption mechanism of Pb (II) and Ni (II) in aqueous solution using pea peels under the influence of sorbent dose, pH, temperature, initial metal ion concentration and contact time. SEM and FTIR were used for characterization of pea peels. The study showed that solution pH affects sorption process and the optimum pH for Pb (II) was 6.0 while for that of Ni (II) was 7.0. Pseudo-second order kinetic model was found to be the most suitable one to explain the kinetic data not only due to high value of R(2) (>0...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626137/novel-palm-fatty-acid-functionalized-magnetite-nanoparticles-for-magnetic-solid-phase-extraction-of-trace-polycyclic-aromatic-hydrocarbons-from-environmental-samples
#16
Siti Khalijah Mahmad Rozi, Hamid Rashidi Nodeh, Muhammad Afzal Kamboh, Ninie Suhana Abdul Manan, Sharifah Mohamad
A novel adsorbent, palm fatty acid coated magnetic Fe3O4 nanoparticles (MNP-FA) was successfully synthesized with immobilization of the palm fatty acid onto the surface of MNPs. The successful synthesis of MNP-FA was further confirmed by X-Ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and Energy dispersive X-Ray spectroscopy (EDX) analyses and water contact angle (WCA) measurement. This newly synthesized MNP-FA was applied as magnetic solid phase extraction (MSPE) adsorbent for the enrichment of polycyclic aromatic hydrocarbons (PAHs), namely fluoranthene (FLT), pyrene (Pyr), chrysene (Cry) and benzo(a)pyrene (BaP) from environmental samples prior to High Performance Liquid Chromatography- Diode Array Detector (HPLC-DAD) analysis...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626136/effect-of-hydroxyl-groups-on-solubilization-states-of-alkandiols-in-dtab-micelles-application-of-a-differential-conductivity-technique
#17
Hideo Kawamura, Yuuto Takeda, Takuro Tagawa, Hajime Katuura, Masaki Shiomi
The partition coefficients, Kx, of 1,2-alkanediols and α,ω-alkanediols between dodecyltrimethylammonium bromide (DTAB) micelles and water, and the change of the degree of counterion dissociation, dα/dXa(m), on DTAB micelles associated with solubilization of the alkanediols are determined by a differential conductivity technique. The standard Gibbs energy change of transfer per methylene group, ΔG(0)(CH2), is estimated from a dependence of logarithmic value of the Kx on the carbon number of alkyl chain in the alkanediols...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626135/adsorption-of-the-three-phase-emulsion-on-various-solid-surfaces
#18
Yasutaka Enomoto, Yoko Imai, Kazuo Tajima
The present study investigates the adsorption of the three-phase emulsion on various solid/water interfaces. Vesicles can be used as emulsifiers in the three-phase emulsions and act as an independent phase unlike the surfactant used in conventional emulsions; therefore, it is expected that the three-phase emulsion formed by the adhesion of vesicles to the oil/water interface will adsorb on various solid/water interfaces. The cationic three-phase emulsion was prepared to encourage emulsion adsorption on negatively charged solid substrates in water...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626134/synthesis-and-detection-by-hplc-of-3-oxohexadecanoyl-coa-for-the-study-of-peroxisomal-bifunctional-proteins
#19
Shirou Tsuchida, Ayumu Tenma, Naoya Hamaue, Tsuyoshi Murai, Teruki Yoshimura, Takashi Aoki, Takao Kurosawa
3-oxohexadecanoyl-CoA was synthesized for the study of D-bifunctional protein (EC 4. 2. 1. 107, EC 4. 2. 1. 119, EC 1. 1. 1. n12) and L-bifunctional protein (EC 4. 2. 1. 17, EC 5. 3. 3. 8, EC 1. 1. 1. 35). First, tetradecanal was subjected to the Reformatsky reaction with ethyl bromoacetate, and the product was then converted into ethyl 3-oxohexadecanoate. After acetalization of the 3-oxo ester with ethylene glycol, 3,3-ethlenedioxyhexadecanoic acid was obtained by alkaline hydrolysis. The acid was condensed with coenzyme A (CoA) by the mixed anhydride method, and the resulting CoA ester was deprotected with 4 M HCl to obtain 3-oxohexadecanoyl-CoA...
June 13, 2017: Journal of Oleo Science
https://www.readbyqxmd.com/read/28626133/simple-synthesis-hydrogenated-castor-oil-fatty-amide-wax-and-its-coating-characterization
#20
Xiuzhu Yu, Ning Wang, Rui Zhang, Zhong Zhao
A simple method for incorporating amine groups in hydrogenated castor oil (HCO) to produce wax for beeswax or carnauba wax substitution in packaging and coating was developed. From the conversion rate of the products, HCO was reacted with ethanolamine at 150°C for 5 h, and the molar ratio of HCO and ethanolamine was 1:4. The hardness of the final product was seven times higher than that of beeswax, the cohesiveness of the final product was 1.3 times higher than that of beeswax and approximately one half of that of carnauba wax, and the melting point of the final product is 98°C...
June 13, 2017: Journal of Oleo Science
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