Environmental Engineering Science

Compressed energy storage (CES) of air, CO2 , or H2 in porous formations is a promising means of energy storage to abate the intermittency of renewable energy production. During operation, gas is injected during times of excess energy production and extracted during excess demands to drive turbines. Storage in saline aquifers using CO2 as a cushion or working gas has numerous advantages over typical air storage in caverns. However, interactions between CO2 and saline aquifers may result in potential operational limitations and have not been considered...

Coprecipitation can be an effective treatment method for the removal of environmentally relevant metals from industrial wastewaters such as produced waters from the oil and gas industry. The precipitation of barite, BaSO4 , through the addition of sulfate removes barium while coprecipitating strontium and other alkaline earth metals even when these are present at concentrations below their solubility limit. Among other analytical methods, X-ray fluorescence (XRF) nanospectroscopy at the Hard X-ray Nanoprobe (HXN) beamline at the National Synchrotron Light Source II (NSLS-II) was used to quantify Sr incorporation into barite...

Dam operations are known to have significant impacts on reservoir hydrodynamics and solute transport processes. The Gardiner Dam, one of the structures that forms the Lake Diefenbaker reservoir located in the Canadian Prairies, is managed for hydropower generation and agricultural irrigation and is known to have widely altering temperature regimes and nutrient circulations. This study applies the hydrodynamic and nutrient CE-QUAL-W2 model to explore how various withdrawal depths (5, 15, 25, 35, 45, and 55 m) influence the concentrations and distribution of nutrients, temperature, and dissolved oxygen (DO) within the Lake Diefenbaker reservoir...

[This corrects the article DOI: 10.1089/ees.2016.0348.].

In recent years, there has been increased recognition of the importance of a nexus approach to optimize food, energy, and water (FEW) security at regional and global scales. Remote communities in the Arctic and Subarctic regions in Alaska provide unique examples of closed and isolated systems, wherein the FEW nexus not only needs to be examined to lend resilience to these vulnerable communities but that could also serve as small-scale test beds for a wider and systematic understanding of the FEW nexus. In this short communication, looking at the FEW nexus in Cordova, Alaska, through an energy lens, we introduce an approach (referred to as the "MicroFEWs approach") that may assist remote communities in Alaska in making informed decisions regarding the use of renewable energy to increase FEW security...

Traditional wastewater management uses end-of-pipe approaches to remove pollutants in wastewater before discharge. Although effective in human health protection for decades, this approach of removal and disposal requires a high investment of energy and materials and overlooks the values of the key nutrients in wastewater such as phosphorus (P). Phosphorus in wastewater comes from the human metabolites of food, resulted from crop uptakes of fertilizer that ultimately derived from phosphate rock (PR). PR, however, could be depleted in this century, which would lead to a global food crisis...

The water-energy nexus (WEN) is dynamic and complicated in megacities, most of which are challenged by water scarcity and the mandate to reduce energy consumption. A salient feature of water and energy services in megacities is that they are supported by a web of regional infrastructure, extending far beyond the geographic boundaries of the cities, resulting in a strong dependence on resources imported from outside. Understanding the WEN of megacities has implications not only for more efficient resource utilization but also for synergistic regional development and corporation...

This study develops general predictive models for the ultraviolet (UV) radiation dose-response behavior of Bacillus subtilis spores to solar UV irradiation that occurs in the environment and broadband UV irradiation used in water disinfection systems. The approach is demonstrated using previously obtained experimental survival rates for B. subtilis spores deposited on dry surfaces as well as in water and exposed to both narrow band UV radiation as well as broadband UV irradiation from solar exposure and disinfectant lamps...

This study investigated the adsorptive removal of fluoride from simulated water pollution using various (hydro)oxide nanomaterials, which have the potential to be used as sorbents for surface water and groundwater remediation. Tested nanomaterials include hematite, magnetite, ferrihydrite, goethite, hematite-alpha, hydroxyapatite (HAP), brucite, and four titanium dioxides (TiO2 -A [anatase], TiO2 -B [rutile], TiO2 -C [rutile], and TiO2 -D [anatase]). Among 11 (hydro)oxide nanomaterials tested in this study, ferrihydrite, HAP, and brucite showed two to five times higher removal of fluoride than other nanomaterials from synthetic fluoride solutions...

In the United States, approved methods to measure free chlorine concentrations in drinking water systems adding sodium dichloroisocyanurate (dichlor) or trichloroisocyanuric acid (trichlor) as chlorine sources exhibit measurement bias from chlorinated cyanurate presence, leading to overestimated free chlorine concentrations for regulatory compliance. One option to overcome this limitation is to estimate free chlorine concentrations using an established water chemistry model (full model), but the full model has only been determined for 25 °C...

Underground fractures serve as flow conduits, and they may produce unwanted migration of water and other fluids in the subsurface. An example is the migration and leakage of greenhouse gases in the context of geologic carbon sequestration. This study has generated new understanding about how acids erode carbonate fracture surfaces and the positive feedback between reaction and flow. A two-dimensional reactive transport model was developed and used to investigate the extent to which geochemical factors influence fracture permeability and transmissivity evolution in carbonate rocks...

[This retracts the article DOI: 10.1089/ees.2006.23.253.].

Paracetamol and its toxic transformation products have been found in surface water, wastewater, and drinking water. Effective methods to degrade these products must be found to reduce their detrimental effects on microorganisms in aquatic systems and minimize the concern on human health. Thus, this study looked into the electrochemical oxidation of paracetamol and its oxidation products on surface water, and results were compared with those of paracetamol synthetic solution oxidation. Degradation of paracetamol was conducted using a stainless steel electrode cell, a pH of 3, and direct current densities of 5...

The chemical composition of coal ash is highly heterogeneous and dependent on the origin of the source coal, combustion parameters, and type and configuration of air pollution control devices. This heterogeneity results in uncertainty in the evaluation of leaching potential of contaminants from coal ash. The goal of this work was to identify whether a single leaching protocol could roughly group high-leaching potential coal ash from low-leaching potential coal ash, with respect to arsenic (As) and selenium (Se)...

This is Part II of a review covering the wide range of issues associated with all aspects of the use and responsible disposal of foam and plastic wastes containing toxic or potentially toxic flame retardants. We identify basic and applied research needs in the areas of responsible collection, pretreatment, processing, and management of these wastes. In Part II, we explore alternative technologies for the management of halogenated flame retardant (HFR) containing wastes, including chemical, mechanical, and thermal processes for recycling, treatment, and disposal...

Flame retardants (FRs) are added to foams and plastics to comply with flammability standards and test requirements in products for household and industrial uses. When these regulations were implemented, potential health and environmental impacts of FR use were not fully recognized or understood. Extensive research in the past decades reveal that exposure to halogenated FRs, such as those used widely in furniture foam, is associated with and/or causally related to numerous health effects in animals and humans...

Use of biotrickling filter (BTF) for gas phase treatment of volatile trihalomethanes (THMs) stripped from water treatment plants could be an attractive treatment option. The aim of this study is to use laboratory-scale anaerobic BTF to treat gaseous chloroform (recalcitrant to biological transformation) as a model THM and compare results with aerobic BTF. Additional investigations were conducted to determine the microbial diversity present within the BTFs. Chloroform is a hydrophobic volatile THM known to be difficult to biodegrade...

No abstract text is available yet for this article.

Performance of microbial fuel cells (MFCs) was monitored during the influent nutrient change from lactate to glucose/acetate/propionate and then to lactate. Meanwhile, anodic microbial communities were characterized by culture-independent molecular biotechnologies. Results showed MFC performance recovered rapidly when the lactate was replaced by one of its metabolic intermediates acetate, while it needed a longer time to recover if lactate substrate was converted to glucose/propionate or acetate to lactate...

[This corrects the article DOI: 10.1089/ees.2016.0223.].