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Ultrasonics Sonochemistry

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https://www.readbyqxmd.com/read/28533126/sonodynamic-therapy-combined-with-novel-anti-cancer-agents-sanguinarine-and-ginger-root-extract-synergistic-increase-in-toxicity-in-the-presence-of-panc-1-cells-in-vitro
#1
Matthew Prescott, James Mitchell, Stella Totti, Judy Lee, Eirini Velliou, Madeleine Bussemaker
The presence of ultrasound-induced cavitation in sonodynamic therapy (SDT) treatments has previously enhanced the activity and delivery of certain sonosensitisers in biological systems. The purpose of this work was to investigate the potential for two novel anti-cancer agents from natural derivatives, sanguinarine and ginger root extract (GRE), as sonosensitisers in an SDT treatment with in vitro PANC-1 cells. Both anti-cancer compounds had a dose-dependent cytotoxicity in the presence of PANC-1 cells. A range of six discreet ultrasound power-frequency configurations were tested and it was found that the cell death caused directly by ultrasound was likely due to the sonomechanical effects of cavitation...
May 13, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28529051/ultrasound-assisted-biogas-production-from-co-digestion-of-wastewater-sludges-and-agricultural-wastes-comparison-with-microwave-pre-treatment
#2
B Aylin Alagöz, Orhan Yenigün, Ayşen Erdinçler
This study investigates the effect of ultrasonication and microwave sludge disintegration/pre-treatment techniques on the anaerobic co-digestion efficiency of wastewater sludges with olive and grape pomaces. The effects of both co-digestion and sludge pre-treatment techniques were evaluated in terms of the organic removal efficiency and the biogas production. The "co-digestion" of wastewater sludge with both types of pomaces was revealed to be a much more efficient way for the biogas production compared to the single (mono) sludge digestion...
May 11, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28501355/sono-photo-fenton-oxidation-of-bisphenol-a-over-a-lafeo3-perovskite-catalyst
#3
Meral Dükkancı
In this study, oxidation of bisphenol-A (IUPAC name - 2,2-(4,4-dihydroxyphenyl, BPA), which is an endocrine disrupting phenolic compound used in the polycarbonate plastic and epoxy resin industry, was investigated using sono-photo-Fenton process under visible light irradiation in the presence of an iron containing perovskite catalyst, LaFeO3. The catalyst prepared by sol-gel method, calcined at 500°C showed a catalytic activity in BPA oxidation using sono-photo-Fenton process with a degradation degree and a chemical oxygen demand (COD) reduction of 21...
May 5, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28622994/ultrasound-assisted-acid-hydrolysis-of-cellulose-to-chemical-building-blocks-application-to-furfural-synthesis
#4
Daniel Santos, Ubiratan F Silva, Fabio A Duarte, Cezar A Bizzi, Erico M M Flores, Paola A Mello
In this work, the use of ultrasound energy for the production of furanic platforms from cellulose was investigated and the synthesis of furfural was demonstrated. Several systems were evaluated, as ultrasound bath, cup horn and probe, in order to investigate microcrystalline cellulose conversion using simply a diluted acid solution and ultrasound. Several acid mixtures were evaluated for hydrolysis, as diluted solutions of HNO3, H2SO4, HCl and H2C2O4. The influence of the following parameters in the ultrasound-assisted acid hydrolysis (UAAH) were studied: sonication temperature (30 to 70°C) and ultrasound amplitude (30 to 70% for a cup horn system) for 4 to 8molL(-1) HNO3 solutions...
April 25, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28438401/a-control-system-for-ultrasound-devices-utilized-for-inactivating-e-coli-in-wastewater
#5
H Ohrdes, I Ille, J Twiefel, J Wallaschek, R Nogueira, K-H Rosenwinkel
Sonochemical processes applied to wastewater treatment have an influence on the behavior of ultrasonic systems. This is especially due to the load characteristic of the sonochemical process itself and the temperature increase caused by internal damping within the converter. Hence, a controlling device is needed to guarantee the operation in resonance and to keep the vibration amplitude constant. This paper presents a digital control system for the operation of weak to strong damped ultrasonic devices and its application for inactivating Escherichia coli in wastewater...
April 16, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28438402/effects-of-ultrasonic-and-hydrodynamic-cavitation-on-the-treatment-of-cork-wastewater-by-flocculation-and-fenton-processes
#6
Zhilin Wu, Francisco J Yuste-Córdoba, Pedro Cintas, Zhansheng Wu, Luisa Boffa, Stefano Mantegna, Giancarlo Cravotto
This paper reports that ultrasonic (US) and hydrodynamic cavitation (HC) are efficient strategies for the environmental remediation of cork wastewater (CW). It is necessary to remove toxic, inhibitory or refractory organic matter from CW using physical and chemical techniques (pre-treatment) prior to performing conventional biological treatment. After this biological treatment, it is also critical to further decontaminate (post-treatment) in order to meet the discharge limitation. The pre-treatment of diluted CW using Fenton oxidation (FE) alone led to COD and polyphenol (PP) removal values of 30% and 61%, respectively, while HC and US resulted in 83-90% increases in COD reduction and 26-33% increases in PP reduction...
April 13, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28434880/ultrasound-assisted-extraction-of-rare-earth-elements-from-carbonatite-rocks
#7
Lisarb O Diehl, Thais L Gatiboni, Paola A Mello, Edson I Muller, Fabio A Duarte, Erico M M Flores
In view of the increasing demand for rare-earth elements (REE) in many areas of high technology, alternative methods for the extraction of these elements have been developed. In this work, a process based on the use of ultrasound for the extraction of REE from carbonatite (an igneous rock) is proposed to avoid the use of concentrated reagents, high temperature and excessive extraction time. In this pioneer work for REE extraction from carbonatite rocks in a preliminary investigation, ultrasonic baths, cup horn systems or ultrasound probes operating at different frequencies and power were evaluated...
April 12, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28552350/ultrasound-assisted-advanced-oxidation-processes-for-water-decontamination
#8
Nilsun H Ince
The study reflects a part of my experience in sonochemistry and ultrasound-assisted advanced oxidation processes (AOPs) acquired during the last fifteen years with my research team. The data discussed were selected from studies with azo dyes, endocrine disrupting compounds and analgesic/anti-inflammatory pharmaceuticals, which are all classified as "hazardous" or "emerging" contaminants. The research focused on their treatability by ultrasound (US) and AOPs with emphasis on the mineralization of organic carbon...
April 9, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28412092/chaotic-oscillations-of-gas-bubbles-under-dual-frequency-acoustic-excitation
#9
Yuning Zhang, Yuning Zhang
Chaotic oscillation of bubbles in liquids reduces the efficiency of the sonochemical system and should be suppressed in the practical applications. In the present paper, a chaos control method based on the dual-frequency approach is numerically investigated and is proved to be an effective method even for cases with intensive energy input. It was found that the chaos could be successfully suppressed by the application of dual-frequency approach in a wide range of parameter zone (even with high acoustic pressure amplitude)...
April 9, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28434879/sonoluminescence-and-acoustic-emission-spectra-at-different-stages-of-cavitation-zone-development
#10
N V Dezhkunov, A Francescutto, L Serpe, R Canaparo, G Cravotto
The way in which a cavitation zone develops in a focused pulsed ultrasound field is studied in this work. Sonoluminescence (SL), total hydrophone output and cavitation noise spectra have been recorded across a gradual, smooth increase in applied voltage. It is shown that the cavitation zone passes through a number of stages of evolution, according to increasing ultrasound intensity, decreasing pulse period and increasing ultrasound pulse duration. Sonoluminescence is absent in the first phase and the hydrophone output spectra consists of a main line with two or three harmonics whose intensity is much lower than that of the main (fundamental) line...
April 6, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28433504/intensification-of-ultrasonic-assisted-crude-oil-demulsification-based-on-acoustic-field-distribution-data
#11
Matheus F Pedrotti, Michele S P Enders, Leticia S F Pereira, Marcia F Mesko, Erico M M Flores, Cezar A Bizzi
Water removal is an essential step during crude oil production due to several problems such as increased transportation costs and high corrosion rate due to dissolved salts. Indirect low frequency ultrasonic energy (US), using baths, has been recently proposed as an effective alternative for crude oil demulsification. However, the reactor position during sonication and its influence on the demulsification efficiency for crude oil has not been evaluated. In this sense, the aim of this study was to develop an automated system based on an open source hardware for mapping the acoustic field distribution in an US bath operating at 35kHz using a hydrophone...
April 2, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28389057/acoustic-wave-propagation-in-bubbly-flow-with-gas-vapor-or-their-mixtures
#12
Yuning Zhang, Zhongyu Guo, Yuhang Gao, Xiaoze Du
Presence of bubbles in liquids could significantly alter the acoustic waves in terms of wave speed and attenuation. In the present paper, acoustic wave propagation in bubbly flows with gas, vapor and gas/vapor mixtures is theoretically investigated in a wide range of parameters (including frequency, bubble radius, void fraction, and vapor mass fraction). Our finding reveals two types of wave propagation behavior depending on the vapor mass fraction. Furthermore, the minimum wave speed (required for the closure of cavitation modelling in the sonochemical reactor design) is analyzed and the influences of paramount parameters on it are quantitatively discussed...
March 29, 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633862/ultrasound-assisted-methods-for-enhanced-extraction-of-phycobiliproteins-from-marine-macro-algae-gelidium-pusillum-rhodophyta
#13
Rochak Mittal, Hrishikesh A Tavanandi, Vaibhav A Mantri, K S M S Raghavarao
Extraction of phycobiliproteins (R-phycoerythrin, R-PE and R-phycocyanin, R-PC) from macro-algae is difficult due to the presence of large polysaccharides (agar, cellulose etc.) present in the cell wall which offer major hindrance for cell disruption. The present study is aimed at developing most suitable methodology for the primary extraction of R-PE and R-PC from marine macro-algae, Gelidium pusillum(Stackhouse) Le Jolis. Such extraction of phycobiliproteins by using ultrasonication and other conventional methods such as maceration, maceration in presence of liquid nitrogen, homogenization, and freezing and thawing (alone and in combinations) is reported for the first time...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633861/optimization-of-magnetic-field-assisted-ultrasonication-for-the-disintegration-of-waste-activated-sludge-using-box-behnken-design-with-response-surface-methodology
#14
Su Guan, Feng Deng, Si-Qi Huang, Shu-Yang Liu, Le-Xian Ai, Pu-Ying She
This study investigated for the first time the feasibility of using a magnetic field for sludge disintegration. Approximately 41.01% disintegration degree (DD) was reached after 30min at 180mT magnetic field intensity upon separate magnetic field treatment. Protein and polysaccharide contents significantly increased. This test was optimized using a Box-Behnken design (BBD) with response surface methodology (RSM) to fit the multiple equation of the DD. The maximum DD was 43.75% and the protein and polysaccharide contents increased to 56...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633860/influencing-factors-and-kinetics-analysis-on-the-leaching-of-iron-from-boron-carbide-waste-scrap-with-ultrasound-assisted-method
#15
REVIEW
Xin Li, Pengfei Xing, Xinghong Du, Shuaibo Gao, Chen Chen
In this paper, the ultrasound-assisted leaching of iron from boron carbide waste-scrap was investigated and the optimization of different influencing factors had also been performed. The factors investigated were acid concentration, liquid-solid ratio, leaching temperature, ultrasonic power and frequency. The leaching of iron with conventional method at various temperatures was also performed. The results show the maximum iron leaching ratios are 87.4%, 94.5% for 80min-leaching with conventional method and 50min-leaching with ultrasound assistance, respectively...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633859/stability-of-cavitation-structures-in-a-thin-liquid-layer
#16
Pengfei Wu, Lixin Bai, Weijun Lin, Jiuchun Yan
The inception and evolution of acoustic cavitation structures in thin liquid layers under different conditions and perturbations are investigated experimentally with high speed photography. The stability and characterization of cavitation structures are quantified by image analysis methods. It is found that cavitation structures (shape of bubble cloud and number of bubbles) are stable under unaltered experimental conditions, and the cavitation bubble cloud will return to the original structure and remain stable even in the face of large perturbations...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633858/effects-of-processing-parameters-in-the-sonic-assisted-water-extraction-sawe-of-6-gingerol
#17
Syaripah Zaimah Syed Jaapar, Noor Azian Morad, Yoshio Iwai, Mariam Firdhaus Mad Nordin
The use of water in subcritical conditions for extraction has several drawbacks. These include the safety features, higher production costs and possible degradation of the bioactive compounds. To overcome these problems, sonic energy and an entrainer were used as external interventions to decrease the polarity of water at milder operating conditions. The effect of low (28kHz) and high (800kHz) frequencies of sonication in the extraction of the main ginger bioactive compound (6-gingerol) were compared. Six parameters were studied: mean particle size (MPS, mm), time of extraction, applied power, sample to solvent ratio (w/v), temperature of extraction, and the percentage of entrainer...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633857/state-of-the-art-on-ultrasonic-oil-production-technique-for-eor-in-china
#18
Zhenjun Wang, Congbo Yin
Ultrasonic oil production technique for enhanced oil recovery (EOR) attracts more attention due to its high adaptability, simple operation, low cost and zero pollution to the oil reservoir. In this paper, recent new downhole tools used for enhanced oil recovery developed in China are summarized. Furthermore, research advance on some key problems that affect the widespread application of ultrasonic oil production technique in China are also summarized in view of what are the primary factors that influence crude oil paraffin inhibition and viscosity reduction, whether ultrasonic excitation is better than chemical agent for any plugs removal and whether ultrasound-chemical combination plug removal technology has the best plugs removal effect...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633856/using-of-sonochemically-prepared-sbsi-for-electrospun-nanofibers
#19
M Nowak, T Tański, P Szperlich, W Matysiak, M Kępińska, D Stróż, Ł Bober, B Toroń
A novel polymeric, polyacrylonitrile (PAN) nanofibers containing ferroelectric and semiconducting antimony sulfoiodide (SbSI) have been made by electrospinning. SbSI nanowires, used as the filler, have been prepared sonochemically from antimony sulphide (Sb2S3) and antimony tri-iodide (SbI3) for the first time. Nanocrystalline SbSI has been fabricated in ethanol under ultrasonic irradiation (20kHz, 565W/cm(2)) at 323K within 2h. The products have been characterized by using techniques such as powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, high-resolution transmission electron microscopy, selected area electron diffraction and optical diffuse reflection as well as transmission spectroscopy...
September 2017: Ultrasonics Sonochemistry
https://www.readbyqxmd.com/read/28633855/nanocomposites-synthesis-characterization-and-its-application-to-removal-azo-dyes-using-ultrasonic-assisted-method-modeling-and-optimization
#20
Sima Porhemmat, Mehrorang Ghaedi, Ali Reza Rezvani, Mohammad Hossein Ahmadi Azqhandi, Ali Akbar Bazrafshan
S-doped and Cu- and Co-doped TiO2 was synthesized by a sol-gel method and characterized by FE-SEM, XRD, EDX and FTIR. The Co/Cu/S-TiO2 nanocomposite loaded on the activated carbon as new nanoadsorbent was used for simultaneous removal of methylene blue (MB) and sunset yellow (SY) from aqueous solution by ultrasonic-assisted adsorption method. In this work, central composite design (CCD) and adaptive neuro-fuzzy inference system (ANFIS) as a support tool for examining data and making prediction are used to recognize and predict the removal percentage in MB and SY dye solution of different concentrations...
September 2017: Ultrasonics Sonochemistry
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