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Applied Spectroscopy

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https://www.readbyqxmd.com/read/28198640/novel-applications-of-laser-induced-breakdown-spectroscopy
#1
Amy J Ray Bauer, Steven G Buckley
The goal of this review article is to provide a description of recent and novel laser-induced breakdown spectroscopy (LIBS) applications and developments, especially those discussed during the NASLIBS Conference, held during SciX in Providence, RI, in September 2015. This topic was selected in view of the numerous recent overall review papers that have successfully given a broad view of the current understanding of laser-material interactions and plasma development and have also discussed the wide landscape of analytical applications of LIBS...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28195505/comparative-study-of-elemental-nutrients-in-organic-and-conventional-vegetables-using-laser-induced-breakdown-spectroscopy-libs
#2
Chet R Bhatt, Bader Alfarraj, Charles T Ghany, Fang Y Yueh, Jagdish P Singh
In this study, the laser-induced breakdown spectroscopy (LIBS) technique was used to identify and compare the presence of major nutrient elements in organic and conventional vegetables. Different parts of cauliflowers and broccolis were used as working samples. Laser-induced breakdown spectra from these samples were acquired at optimum values of laser energy, gate delay, and gate width. Both univariate and multivariate analyses were performed for the comparison of these organic and conventional vegetable flowers...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28195502/on-the-immersion-liquid-evaporation-method-based-on-the-dynamic-sweep-of-magnitude-of-the-refractive-index-of-a-binary-liquid-mixture-a-case-study-on-determining-mineral-particle-light-dispersion
#3
Ilpo Niskanen, Jukka Räty, Kai-Erik Peiponen
This is a feasibility study of a modified immersion liquid technique for determining the refractive index of micro-sized particles. The practical challenge of the traditional liquid immersion method is to find or produce a suitable host liquid whose refractive index equals that of a solid particle. Usually, the immersion liquid method uses a set of immersion liquids with different refractive indices or continuously mixes two liquids with different refractive indices, e.g., using a pumping system. Here, the phenomenon of liquid evaporation has been utilized in defining the time-dependent refractive index variation of the host liquid...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28195499/development-of-a-direct-spectrophotometric-and-chemometric-method-for-determining-food-dye-concentrations
#4
Erin Arroz, Michael Jordan, Gerard G Dumancas
An ultraviolet visible (UV-Vis) spectrophotometric and partial least squares (PLS) chemometric method was developed for the simultaneous determination of erythrosine B (red), Brilliant Blue, and tartrazine (yellow) dyes. A training set (n = 64) was generated using a full factorial design and its accuracy was tested in a test set (n = 13) using a Box-Behnken design. The test set garnered a root mean square error (RMSE) of 1.79 × 10(-7) for blue, 4.59 × 10(-7) for red, and 1.13 × 10(-6) for yellow dyes...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28195498/quantitative-imaging-of-ozone-vapor-using-photofragmentation-laser-induced-fluorescence-lif
#5
Kajsa Larsson, Dina Hot, Andreas Ehn, Andreas Lantz, Wubin Weng, Marcus Aldén, Joakim Bood
In the present work, the spectral properties of gaseous ozone (O3) have been investigated aiming to perform quantitative concentration imaging of ozone by using a single laser pulse at 248 nm from a KrF excimer laser. The O3 molecule is first photodissociated by the laser pulse into two fragments, O and O2. Then the same laser pulse electronically excites the O2 fragment, which is vibrationally hot, whereupon fluorescence is emitted. The fluorescence intensity is found to be proportional to the concentration of ozone...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28195496/high-pressure-high-temperature-hp-ht-stability-of-polytetrafluoroethylene-raman-spectroscopic-study-up-to-10%C3%A2-gpa-and-600%C3%A2-%C3%A2
#6
Anna Yu Likhacheva, Artem D Chanyshev, Sergey V Goryainov, Sergey V Rashchenko, Konstantin D Litasov
The increasing demand for use of polymers at extreme conditions makes important the exploration of their behavior in a wide pressure and temperature range, which remains unknown for polytetrafluoroethylene (PTFE), one of the most common materials. An in situ Raman spectroscopic study of PTFE shows that it is stable within the range of 2-6 GPa at 500 ℃ and up to 12 GPa at 400 ℃. At T > 500 ℃ and P > 3.5 GPa, the graphitization of PTFE is observed, but judging from the preservation of liquid run products, PTFE can be used as a material for sample container up to 600 ℃ at this pressure...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28195495/accuracy-enhancement-of-raman-spectroscopy-using-complementary-laser-induced-breakdown-spectroscopy-libs-with-geologically-mixed-samples
#7
Soojin Choi, Dongyoung Kim, Junho Yang, Jack J Yoh
Quantitative Raman analysis was carried out with geologically mixed samples that have various matrices. In order to compensate the matrix effect in Raman shift, laser-induced breakdown spectroscopy (LIBS) analysis was performed. Raman spectroscopy revealed the geological materials contained in the mixed samples. However, the analysis of a mixture containing different matrices was inaccurate due to the weak signal of the Raman shift, interference, and the strong matrix effect. On the other hand, the LIBS quantitative analysis of atomic carbon and calcium in mixed samples showed high accuracy...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28145749/a-novel-optical-diagnostic-for-in-situ-measurements-of-lithium-polysulfides-in-battery-electrolytes
#8
Najmus Saqib, Cody J Silva, C Mark Maupin, Jason M Porter
An optical diagnostic technique to determine the order and concentration of lithium polysulfides in lithium-sulfur (Li-S) battery electrolytes has been developed. One of the major challenges of lithium-sulfur batteries is the problem of polysulfide shuttling between the electrodes, which leads to self-discharge and loss of active material. Here we present an optical diagnostic for quantitative in situ measurements of lithium polysulfides using attenuated total reflection Fourier transform infrared (FT-IR) spectroscopy...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28145744/a-simple-device-for-lens-to-sample-distance-adjustment-in-laser-induced-breakdown-spectroscopy-libs
#9
Juliana Cortez, Benedito B Farias Filho, Laiane M Fontes, Celio Pasquini, Ivo M Raimundo, Maria Fernanda Pimentel, Flávia de Souza Lins Borba
A simple device based on two commercial laser pointers is described to assist in the analysis of samples that present uneven surfaces and/or irregular shapes using laser-induced breakdown spectroscopy (LIBS). The device allows for easy positioning of the sample surface at a reproducible distance from the focusing lens that conveys the laser pulse to generate the micro-plasma in a LIBS system, with reproducibility better than ±0.2 mm. In this way, fluctuations in the fluence (J cm(-2)) are minimized and the LIBS analytical signals can be obtained with a better precision even when samples with irregular surfaces are probed...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28145742/quartz-enhanced-photoacoustic-spectroscopy-qepas-detection-of-the-%C3%AE-7-band-of-ethylene-at-low-pressure-with-co2-interference-analysis
#10
Zhen Wang, Jian Geng, Wei Ren
Ethylene (C2H4) was detected using quartz-enhanced photoacoustic spectroscopy (QEPAS) at 10.5 µm with a continuous wave, distributed-feedback quantum cascade laser as the light source. The QEPAS sensor was operated at low pressures (≤200 torr) to eliminate the cross-talk spectral interference between C2H4 and CO2, a major interfering species in practical applications. The sensor was calibrated to show a good linear response to C2H4 concentration and the Allan deviation analysis demonstrated a minimum detection limit of 8 ppb at an integration time of 90 s...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28145737/terahertz-imaging-of-the-distribution-of-crystallinity-and-crystalline-orientation-in-a-poly-%C3%A9-caprolactone-film
#11
Chihiro Funaki, Takuya Toyouchi, Hiromichi Hoshina, Yukihiro Ozaki, Harumi Sato
The distribution of crystallinity and the crystalline orientation of a poly(ɛ-caprolactone) (PCL) film have been studied using terahertz (THz) imaging. Terahertz images were developed by using the intensity ratio of the two spectral peaks at 1.42 and 2.03 THz that are assigned to the crystalline modes parallel and perpendicular to the c-axis (I⊥/I ||) of the PCL film. The obtained THz images show that the distribution of crystallinity and crystalline orientation vary considerably between the different regions in the PCL film, even though this inhomogeneity is not visible in the corresponding optical image...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28107035/determination-of-the-zinc-concentration-in-human-fingernails-using-laser-induced-breakdown-spectroscopy
#12
Vlora A Riberdy, Christopher J Frederickson, Steven J Rehse
The absolute concentration of Zn in human fingernail clippings was determined ex vivo using 1064 nm laser-induced breakdown spectroscopy and confirmed by speciated isotope dilution mass spectrometry. A nail testing protocol that sampled across the nail (perpendicular to the direction of growth) was developed and validated by scanning electron microscopy energy-dispersive X-ray spectrometry. Using this protocol, a partial least squares (PLS) regression model predicted the Zn concentration in the fingernails of five people to within an average of 7 ppm...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28107034/automated-measurement-of-magnesium-calcium-ratios-in-gastropod-shells-using-laser-induced-breakdown-spectroscopy-for-paleoclimatic-applications
#13
Adolfo Cobo, Asier García-Escárzaga, Igor Gutiérrez-Zugasti, Jesús Setién, Manuel R González-Morales, José Miguel López-Higuera
The chemical composition of mollusk shells offers information about environmental conditions present during the lifespan of the organism. Shells found in geological deposits and in many archeological sites can help to reconstruct past climatic conditions. For example, a correlation has been found between seawater temperature and the amount of some substituent elements (e.g., magnesium, strontium) in the biogenerated calcium carbonate matrix of the shell, although it is very species-specific. Here we propose the use laser-induced breakdown spectroscopy (LIBS) to estimate Mg/Ca ratios in modern specimens of the common limpet Patella vulgata...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28107025/least-squares-moving-window-spectral-analysis
#14
Young Jong Lee
Least squares regression is proposed as a moving-windows method for analysis of a series of spectra acquired as a function of external perturbation. The least squares moving-window (LSMW) method can be considered an extended form of the Savitzky-Golay differentiation for nonuniform perturbation spacing. LSMW is characterized in terms of moving-window size, perturbation spacing type, and intensity noise. Simulation results from LSMW are compared with results from other numerical differentiation methods, such as single-interval differentiation, autocorrelation moving-window, and perturbation correlation moving-window methods...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28106475/characterization-of-developmental-immature-fiber-im-mutant-and-texas-marker-1-tm-1-cotton-fibers-using-attenuated-total-reflection-fourier-transform-infrared-atr-ft-ir-spectroscopy
#15
Yongliang Liu, Hee-Jin Kim
The immature fiber ( im) mutant is one type of cotton fiber mutant with unique characteristics of non-fluffy cotton bolls. Compared to its near-isogenic wild type Texas Marker-1 (TM-1), im fiber has a thin secondary cell wall and is less mature. In this work, we applied the previously proposed principal component analysis (PCA) and simple algorithms to analyze the attenuated total reflection Fourier transform infrared (ATR FT-IR) spectra of developmental im and TM-1 fibers. The results from these approaches could not effectively and consistently indicate the inherent difference between TM-1 and im fibers at the same developmental stage...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28106472/sample-preparation-for-repeated-measurements-on-a-single-liquid-droplet-using-laser-induced-breakdown-spectroscopy
#16
Violeta Lazic, Roberta Fantoni, Antonio Palucci, Massimiliano Ciaffi
We studied changes in laser-induced breakdown spectroscopy (LIBS) signal intensity with the thickness of a liquid layer placed on a solid substrate, where an easily evaporating methanol sample was used. For a certain optimal liquid film thickness we obtained a manifold increase of the LIBS signal from methanol. Progressive liquid film thinning leads to a reduction and a successive disappearance of laser-induced splashes; the latter condition drastically reduces the sample consumption and allows measurements to be repeated many times on a single liquid droplet...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28103053/mercury-amalgam-diffusion-in-human-teeth-probed-using-femtosecond-libs
#17
Liciane Toledo Bello, Patricia Aparecida da Ana, Dário Santos, Francisco José Krug, Denise Maria Zezell, Nilson Dias Vieira, Ricardo Elgul Samad
In this work the diffusion of mercury and other elements from amalgam tooth restorations through the surrounding dental tissue (dentin) was evaluated using femtosecond laser-induced breakdown spectroscopy (fs-LIBS). To achieve this, seven deciduous and eight permanent extracted human molar teeth with occlusal amalgam restorations were half-sectioned and analyzed using pulses from a femtosecond laser. The measurements were performed from the amalgam restoration along the amalgam/dentin interface to the apical direction...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28103051/standoff-laser-induced-breakdown-spectroscopy-libs-using-a-miniature-wide-field-of-view-spatial-heterodyne-spectrometer-with-sub-microsteradian-collection-optics
#18
Patrick D Barnett, Nirmal Lamsal, S Michael Angel
A spatial heterodyne spectrometer (SHS) is described for standoff laser-induced breakdown spectroscopy (LIBS) measurements. The spatial heterodyne LIBS spectrometer (SHLS) is a diffraction grating based interferometer with no moving parts that offers a very large field of view, high light throughput, and high spectral resolution in a small package. The field of view of the SHLS spectrometer is shown to be ∼1° in standoff LIBS measurements. In the SHLS system described here, the collection aperture was defined by the 10 mm diffraction gratings in the SHS and standoff LIBS measurements were made up to 20 m with no additional collection optics, corresponding to a collection solid angle of 0...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28092172/analysis-of-indium-tin-oxide-film-using-argon-fluroide-arf-laser-excited-atomic-fluorescence-of-ablated-plumes
#19
Sut Kam Ho, Dario Machado Garcia
A two-pulse laser-excited atomic fluorescence (LEAF) technique at 193 nm wavelength was applied to the analysis of indium tin oxide (ITO) layer on polyethylene terephthalate (PET) film. Fluorescence emissions from analytes were induced from plumes generated by first laser pulse. Using this approach, non-selective LEAF can be accomplished for simultaneous multi-element analysis and it overcomes the handicap of strict requirement for laser excitation wavelength. In this study, experimental conditions including laser fluences, times for gating and time delay between pulses were optimized to reveal high sensitivity with minimal sample destruction and penetration...
January 1, 2017: Applied Spectroscopy
https://www.readbyqxmd.com/read/28092163/corrigendum-to-simultaneous-orthogonal-drug-detection-using-fully-integrated-gas-chromatography-with-fourier-transform-infrared-detection-and-mass-spectrometric-detection
#20
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No abstract text is available yet for this article.
January 1, 2017: Applied Spectroscopy
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