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Chemosphere

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https://www.readbyqxmd.com/read/28437745/comparative-study-of-the-effects-of-gadolinium-chloride-and-gadolinium-based-magnetic-resonance-imaging-contrast-agent-on-freshwater-mussel-dreissena-plymorpha
#1
Houda Hanana, Patrice Turcotte, Chantale André, Christian Gagnon, François Gagné
Gadolinium (Gd), a metal of the lanthanide series used in various industrial and medical purposes is released into the aquatic environment. However, there are few aquatic toxicological studies addressing environmental effects of Gd which remains unknown in aquatic animals. Therefore, this study aimed to compare the effects of GdCl3 and a gadolinium-based MRI contrast agent (Omniscan), in zebra mussels after 28 days through a multibiomarker approach. Data revealed that after GdCl3 exposure, the mRNA level of metallothionein (MT) was modulated, those of cytochrome c oxidase (CO1) and superoxide dismutase (SOD) were increased, while gene expressions of catalase (CAT) and glutathione-S-transferase (GST) were downregulated...
April 21, 2017: Chemosphere
https://www.readbyqxmd.com/read/28437743/eco-pharmacovigilance-of-non-steroidal-anti-inflammatory-drugs-necessity-and-opportunities
#2
REVIEW
Bing-Shu He, Jun Wang, Juan Liu, Xia-Min Hu
Eco-pharmacovigilance (EPV) is a practical and powerful approach to minimize the potential risks posed by pharmaceutical residues in environment. However, it is impracticable to practise rigorous and unitary EPV process for all the existing and new pharmaceuticals. Here, we focused on non-steroidal anti-inflammatory drugs (NSAIDs), and discussed the necessity and potential opportunities of practising EPV of NSAIDs. We found that the consumption of NSAIDs is huge and ubiquitous across the globe. NSAIDs were worldwidely reported as one of the most dominant and frequently detected groups in environmental matrices including wastewater, surface water, suspended solids, sediments, groundwater, even drinking water...
April 21, 2017: Chemosphere
https://www.readbyqxmd.com/read/28437742/biological-treatment-of-model-dyes-and-textile-wastewaters
#3
Alicia Paz, Julia Carballo, María José Pérez, José Manuel Domínguez
Previous works conducted in our laboratory, reveled that Bacillus aryabhattai DC100 produce ligninolytic enzymes such as laccases and/or peroxidases, opening new applications in different bioprocesses, including the treatment of disposal residues such as dyestuffs from textile processing industries. This work described the degradation of three commercial model dyes Coomassie Brilliant Blue G-250 (CBB), Indigo Carmine (IC) and Remazol Brilliant Blue R (RBBR) under different culture media and operational conditions...
April 18, 2017: Chemosphere
https://www.readbyqxmd.com/read/28431390/sulfonamides-photoassisted-oxidation-treatments-catalyzed-by-ilmenite
#4
P García-Muñoz, G Pliego, J A Zazo, A Bahamonde, J A Casas
This work assesses the feasibility of several advanced oxidation processes (CWPO Catalytic Wet Peroxide Oxidation), Photocatalysis and their combination (CWPO-Photoassisted process) for sulfonamide antibiotic degradation. Raw ilmenite was used as catalyst in both processes, because of the presence of iron and titanium in its structure. Despite both treatments allowed reaching a total starting antibiotic depletion working at pH0 = 3 and T0 = 30 °C within 30 min reaction time, significant differences were observed in terms of mineralization...
April 18, 2017: Chemosphere
https://www.readbyqxmd.com/read/28437744/fe-%C3%A2-ions-enhanced-catalytic-properties-of-bio-2co3-nanowires-and-mechanism-study-for-complete-degradation-of-xanthate
#5
Yujiao Guo, Kuixin Cui, Mingyi Hu, Shengming Jin
The wire-like Fe(3+)-doped (BiO)2CO3 photocatalyst was synthesized by a hydrothermal method. The photocatalytic property of Fe(3+)-doped (BiO)2CO3 nanowires was evaluated through degradation of sodium isopropyl xanthate under UV-visible light irradiation. The as-prepared Fe(3+)-doped (BiO)2CO3 nanowires were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), UV-visible diffuse reflectance spectroscopy (UV-vis DRS), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) in detail...
April 17, 2017: Chemosphere
https://www.readbyqxmd.com/read/28432880/immobilization-of-cu-zn-cd-and-pb-in-mine-drainage-stream-sediment-using-chinese-loess
#6
Fei Zang, Shengli Wang, Zhongren Nan, Jianmin Ma, Yepu Li, Qian Zhang, Yazhou Chen
The in situ immobilization of metal-contaminated sediment, using various amendments, has attracted great attention owing to their cost-effectiveness. The present study investigated the effectiveness of Chinese loess on Cu, Zn, Cd and Pb stabilization by decreasing their bioavailability in contaminated sediment. The loess was mixed with the sediment in doses of 0, 0.5, 1, 2, 5, 10 and 20 kg. Approximately 70 d after loess application, the effectiveness was evaluated using the Tessier sequential extraction procedure and single extractants, including ethylenediaminetetraacetic acid disodium salt (EDTA-2Na), diethylenetriaminepentaacetic acid (DTPA), calcium chloride (CaCl2) and hydrochloric acid (HCl)...
April 17, 2017: Chemosphere
https://www.readbyqxmd.com/read/28431388/retention-and-transport-of-graphene-oxide-in-water-saturated-limestone-media
#7
Shunan Dong, Yuanyuan Sun, Bin Gao, Xiaoqing Shi, Hongxia Xu, Jianfeng Wu, Jichun Wu
In this work, column experiments were conducted to investigate the transport characteristics of graphene oxide (GO) nanoparticles in limestone media under various electrolytes, solution pH, and humic acid (HA) concentration conditions. In the limestone media, GO exhibited relatively low mobility with the mass recovery rate lower than 65.2%, even when solution ionic strength was low. The presence of HA enhanced its mobility. In addition, the presence of S(2-), a divalent anion, also promoted GO transport in limestone media compared to Cl(-) under similar ionic strength conditions through neutralizing more positive charge and thus diminishing the cation bridging...
April 17, 2017: Chemosphere
https://www.readbyqxmd.com/read/28426941/behavioral-deficits-and-neural-damage-of-caenorhabditis-elegans-induced-by-three-rare-earth-elements
#8
Tiantian Xu, Manke Zhang, Jiani Hu, Zihan Li, Taipu Wu, Jianing Bao, Siyu Wu, Lili Lei, Defu He
Rare earth elements (REEs) are widely used in industry, agriculture, medicine and daily life in recent years. However, environmental and health risks of REEs are still poorly understood. In this study, neurotoxicity of trichloride neodymium, praseodymium and scandium were evaluated using nematode Caenorhabditis elegans as the assay system. Median lethal concentrations (48 h) were 99.9, 157.2 and 106.4 mg/L for NdCl3, PrCl3 and ScCl3, respectively. Sublethal dose (10-30 mg/L) of these trichloride salts significantly inhibited body length of nematodes...
April 17, 2017: Chemosphere
https://www.readbyqxmd.com/read/28437740/stabilization-of-metal-loid-s-in-two-contaminated-agricultural-soils-comparing-biochar-to-its-non-pyrolysed-source-material
#9
Lukáš Trakal, Irene Raya-Moreno, Kerry Mitchell, Luke Beesley
Two metal(loid) contaminated agricultural soils were amended with grape stalk (wine production by-product)-derived biochar as well as its pre-pyrolysed origin material, to investigate their geochemical impacts on As, Cr, Cu and Zn. Detailed physico-chemical evaluation combined with a column leaching test determined the retention of metal(loid)s from soil solution by each amendments. A pot experiment measured metal(loid)s in soil pore water and their uptake to ryegrass when the amendments were mixed into soils at 1 and 5% (w/w)...
April 15, 2017: Chemosphere
https://www.readbyqxmd.com/read/28432879/seasonal-variation-and-health-risk-assessment-of-organochlorine-compounds-in-urban-soils-of-novi-sad-serbia
#10
Biljana D Škrbić, Vesna Marinković, Igor Antić, Anita Petrović Gegić
The aim of this paper was to determine spatial and seasonal variation of 6 indicator polychlorinated biphenyls (PCBs) and 18 organochlorine pesticides (OCPs) in urban soils of Novi Sad, Serbia. Sixty surface soil samples were collected during both winter and summer season, from different types of locations: schools, recreational areas, residential and industrial zones. Samples were treated using the method of accelerated solvent extraction, which allows simultaneous extraction and clean up of PCBs and OCPs...
April 15, 2017: Chemosphere
https://www.readbyqxmd.com/read/28419957/arsenic-in-groundwater-of-the-kolkata-municipal-corporation-kmc-india-critical-review-and-modes-of-mitigation
#11
Dipankar Chakraborti, Bhaskar Das, Mohammad Mahmudur Rahman, Bishwajit Nayak, Arup Pal, Mrinal K Sengupta, Sad Ahamed, Md Amir Hossain, Uttam K Chowdhury, Bhajan Kumar Biswas, Khitish Chandra Saha, R N Dutta
This study represents the first comprehensive report of groundwater arsenic contamination status in the Kolkata Municipal Corporation (KMC). During the past 23 years, 4210 groundwater samples were analysed from all 141 wards in the KMC: 14.2% and 5.2% samples had arsenic >10 μg/l and >50 μg/l, respectively, representing 77 and 37 wards. The study shows that the number of arsenic contaminated samples (and wards) in the southern part of the KMC exceeds that of other parts of the city. The daily intake of arsenic from drinking water was estimated as 0...
April 15, 2017: Chemosphere
https://www.readbyqxmd.com/read/28419900/dimethylarsenate-dma-exposure-influences-germination-rates-arsenic-uptake-and-arsenic-species-formation-in-wheat
#12
Elliott G Duncan, William A Maher, Simon D Foster, Frank Krikowa, Cathryn A O'Sullivan, Margaret M Roper
The contamination of cereals with arsenic (As) is a global health and agronomic concern. This study compared the physiological response, As uptake and As speciation in the grains and above ground tissues of 20 wheat cultivars exposed to 5 mg As kg(-1) soil as either arsenate (As(V)) or dimethylarsenate (DMA) under glasshouse conditions. Germination rates for the majority of cultivars exceeded 80% for the majority of cultivars when exposed to As(V), but fell significantly to 20-40% when exposed to DMA. For a number of cultivars, grain yields were 20-50% lower when plants were exposed to DMA compared to As(V)...
April 15, 2017: Chemosphere
https://www.readbyqxmd.com/read/28419899/the-long-term-tsunami-impact-evolution-of-iron-speciation-and-major-elements-concentration-in-tsunami-deposits-from-thailand
#13
Lidia Kozak, Przemyslaw Niedzielski
The article describes the unique studies of the chemical composition changes of new geological object (tsunami deposits in south Thailand - Andaman Sea Coast) during four years (2005-2008) from the beginning of formation of it (deposition of tsunami transported material, 26 December 2004). The chemical composition of the acid leachable fraction of the tsunami deposits has been studied in the scope of concentration macrocompounds - concentration of calcium, magnesium, iron, manganese and iron speciation - the occurrence of Fe(II), Fe(III) and non-ionic iron species described as complexed iron (Fe complex)...
April 15, 2017: Chemosphere
https://www.readbyqxmd.com/read/28433929/pollution-characteristics-and-human-health-risks-of-potentially-eco-toxic-elements-ptes-in-road-dust-from-metropolitan-area-of-hefei-china
#14
Muhammad Ubaid Ali, Guijian Liu, Balal Yousaf, Qumber Abbas, Habib Ullah, Mehr Ahmed Mujtaba Munir, Biao Fu
This study aims to investigate the pollution characteristics of road dust and their associated health risks of potentially toxic elements (PTEs) to humans using array-based risk assessment models described by United States Environmental Protection Agency (USEPA) in a metropolitan area of Hefei, China. Geoaccumulation index (Igeo) was used to describe pollution characteristics of roadside dust in urban, periurban and industrial areas. Results indicate that industrial roadside dust was contaminated with Fe, Ni, Cu, Ti, V, Pb, Ba, Sb, Cr, Sn, Pb, As and Ga showing Igeo value (log2 (x)) between Igeo class 3 to 4...
April 14, 2017: Chemosphere
https://www.readbyqxmd.com/read/28432892/arsenic-chromium-molybdenum-and-selenium-geochemical-fractions-and-potential-mobilization-in-riverine-soil-profiles-originating-from-germany-and-egypt
#15
Sabry M Shaheen, Eilhann E Kwon, Jayanta K Biswas, Filip M G Tack, Yong Sik Ok, Jörg Rinklebe
The fractionation and potential mobilization of As, Cr, Mo, and Se in four floodplain soil profiles collected along the Nile (Egypt) and Wupper (Germany) Rivers were assessed using the BCR sequential extraction procedure. The concentrations of total and the geochemical fractions (acid soluble (F1), reducible (F2), oxidizable (F3), and residual (F4) fraction) of the elements were determined. The Wupper soils had the highest total concentrations (mg kg(-1)) of As (378) and Cr (2,797) while the Nile soils contained the highest total Mo (12) and Se (42)...
April 14, 2017: Chemosphere
https://www.readbyqxmd.com/read/28432890/characterization-of-spectral-responses-of-dissolved-organic-matter-dom-for-atrazine-binding-during-the-sorption-process-onto-black-soil
#16
Yifan Wang, Xinyuan Zhang, Xing Zhang, Qingjuan Meng, Fengjie Gao, Ying Zhang
This study was aim to investigate the interaction between soil-derived dissolved organic matter (DOM) and atrazine as a kind of pesticides during the sorption process onto black soil. According to the experimental data, the adsorption capacity of Soil + DOM, Soil and DOM were 41.80, 31.45 and 9.35 mg kg(-1), separately, which indicated that DOM significantly enhanced the adsorption efficiency of atrazine by soil. Data implied that the pseudo-second-order kinetic equation could well explain the adsorption process...
April 14, 2017: Chemosphere
https://www.readbyqxmd.com/read/28431387/cypermethrin-toxication-leads-to-histopathological-lesions-and-induces-inflammation-and-apoptosis-in-common-carp-cyprinus-carpio-l
#17
Harun Arslan, Selçuk Özdemir, Serdar Altun
Cypermethrin (Cyp), a known neurotoxic pesticide, is widely used in agricultural applications. In the present study, the aim was to determine the histopathological effects of Cyp toxication and evaluate the activation of inducible nitric oxide synthetase (iNOS) and 8-hydroxy-2-deoxyguanosine (8-OHdG) using an immunofluorescence assay. Thereafter, we identified the expressions of caspase 3, capsase 8, iNOS, and metallothionein 1 (MT1) genes in common carp using quantitative reverse transcription polymerase chain reaction (qRT-PCR)...
April 14, 2017: Chemosphere
https://www.readbyqxmd.com/read/28431384/sediment-and-salinity-effects-on-the-bioaccumulation-of-sulfamethoxazole-in-zebrafish-danio-rerio
#18
Y Chen, J L Zhou, L Cheng, Y Y Zheng, J Xu
The dynamic distribution of a widely used antibiotic sulfamethoxazole between water, sediment and aquatic organisms (zebrafish) was studied in microcosms. Sulfamethoxazole concentrations in water were gradually reduced, while in sediment and zebrafish gradually increased, suggesting active adsorption and bioaccumulation processes occurring. The presence of sediment particles and their interactions with water reduced the bioaccumulation of sulfamethoxazole in zebrafish by 13-28%. The sediment of smaller particle size with more organic carbon content and higher surface area, adsorbed sulfamethoxazole more extensively and decreased its bioaccumulation most significantly...
April 14, 2017: Chemosphere
https://www.readbyqxmd.com/read/28427037/monitoring-of-styrene-oligomers-as-indicators-of-polystyrene-plastic-pollution-in-the-north-west-pacific-ocean
#19
Bum Gun Kwon, Keiji Amamiya, Hideto Sato, Seon-Yong Chung, Yoichi Kodera, Seung-Kyu Kim, Eung Jae Lee, Katsuhiko Saido
Styrene oligomers (SOs) as global contaminants are an environmental concern. However, little is known on the distribution of SOs in the ocean. Here, we show the distribution of anthropogenic SOs generated from discarded polystyrene (PS) plastic monitored from the coastal ocean surface waters (horizontal distribution) and deep seawaters (vertical distribution) in the North-West Pacific Ocean. SOs concentrations in surface seawater and deep seawater ranged from 0.17 to 4.26 μg L(-1) (total mean: 1.48 ± 1...
April 14, 2017: Chemosphere
https://www.readbyqxmd.com/read/28426942/polychlorinated-biphenyl-and-polybrominated-diphenyl-ether-profiles-in-serum-from-cattle-sheep-and-goats-across-california
#20
S Sethi, X Chen, P H Kass, B Puschner
It has been previously been shown by our lab and others that persistent organic pollutants, such as polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs), are contaminants in milk produced for human consumption. To further this research we determined the concentration of 21 PCB and 14 PBDE congeners in livestock serum, mainly bovine, across California. Congeners were extracted from serum using solid phase extraction (SPE), cleaned up by silica cartridge and quantified using gas chromatography-triple quadruple mass spectrometry...
April 14, 2017: Chemosphere
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