Zhe Zhang, Heng Wang, Junjuan Shi, Pingshan Wang, Changlin Liu, Ming Wang, Xiaopeng Li
Snowflake, a highly symmetrical hexagram figure, is challenging to be expressed by chemistry/supramolecular chemistry due to the complex structure. Herein, we have constructed super snowflake supramolecules using terpyridine (tpy)-based metal-organic building blocks with <tpy-Ru(II)-tpy> and <tpy-Zn(II)-tpy> connectivities through stepwise strategies in high yield. The structures were characterized by multi-dimensional mass spectrometry and multi-dimensional NMR spectrometry. In order to address the stability/tolerance of our designed super snowflake structures, ligand exchange behaviors between different supramolecules with various arm length were fully investigated by mass spectrometry...
March 2019: Israel Journal of Chemistry